• 제목/요약/키워드: non-phosphorous

검색결과 92건 처리시간 0.02초

파이로포스포릭 락톤 변성 폴리에스터를 함유한 폴리우레탄 도료의 물성 및 난연 효과 (Physical Properties and Flame-Retardant Effects of Polyurethane Coatings Containing Pyrophosphoric Lactone Modified Polyesters)

  • 정동진;김성래;박형진;박홍수;김승진
    • 폴리머
    • /
    • 제27권3호
    • /
    • pp.169-175
    • /
    • 2003
  • 무독성의 반응형 난연 도료를 제조할 목적으로 모체수지 1개의 구조단위 속에 2개의 인산기를 보유한 파이로포스포릭 락톤 변성 폴리에스터 (PATT)를 합성하고, PATT에 이소시아네이트인 toluene diisocyanate-isocyanurate를 상온경화시켜 2성분계 폴리우레탄 난연 도료(PIPUC)를 제조하였다. PIPUC로서 도막제작 후 비난연 도료와의 도막물성을 비교한 결과 난연 성분 도입에 따른 난연 도료의 물성이 저하되지 않음을 알았다. 난연성 시험 중 45$^{\circ}$ Meckel burner 법에서는 탄화길이가 3.1~4.4 cm를, LOI법에서는 LOI 27~30%를 각각 나타냄으로써 양호한 난연 효과를 보여주었고, SEM에 의한 표면 도막을 관찰한 결과 도막의 결함이나 상분리 현상이 생기지 않음을 관찰하였다.

피로포스포릭 락톤 변성폴리에스테르를 함유한 폴리우레탄 난연도료의 물성 및 난연효과 (Physical Properties and Flame Retardant Effects of Polyurethane Coatings Containing Pyrophosphoric Lactone Modified Polyesters)

  • 정충호;최용호;박홍수
    • 한국응용과학기술학회지
    • /
    • 제17권3호
    • /
    • pp.203-211
    • /
    • 2000
  • Pyrophosphoric lactone modified polyester(PATT) that contains two phosphorous functional groups in one unit base resin structure was synthesized to prepare a non-toxic reactive flame retardant coatings. Then the PATT was cured at room temperature with isocyanate, Desmodur IL, to get a two-component polyurethane flame retardant coatings(PIPUC). Comparing the physical properties of the films of PIPUC with the film of non-flame retardant coatings, there was no degradation observed in physical properties by the introduction of a flame-retarding component into the resin. We found that the char lengths measured by $45^{\circ}$Meckel burner method were $3.1{\sim}4.4cm$ and LOI values recorded $27{\sim}30%$. These results indicate that the coatings prepared in this study is good flame retardant one. The surface structure of coatings investigated with SEM does not show any defects and phase separation.

농경지로부터의 오염물질 유출부하특성 - 전Kjeldahl 질소 및 전인을 중심으로 (Characteristics of Pollutant Loading into Streams from Flooded Paddies -On The Special Reference to Total Kjeldahl Nitorgen and Total phosphorous-)

  • 홍성구;권순국
    • 한국농공학회지
    • /
    • 제31권3호
    • /
    • pp.93-102
    • /
    • 1989
  • With an objective to provide basic information for the management and the prediction of eutrophication in lentic water Systems, total amount of Kjeldahl nitrogen(T-N) and phosphorous(T-P) from irrigated water and drained water from flooded paddies were investigated during the rice growing period of 1988. A 29.3 ha paddies near Jungnam-myun, HwaSung-gun, Gyungi Province, Korea was instrumented for measuring runoff and sampling irrigated water and drained water from paddies. The following conclusions may be drawn from the result of this study. 1.During 115 days of investigation, T-N load for paddies was 362.6kg and T-P 63.44kg.These would be converted to 12.4kg T-N/ha and 2.17kg T-P/ha, respectively. 2.The T-N and T-P loadings in different periods showed a significant difference. The 25% of T-N loading was drained soon after fertilization period and 60% was drained during the rainy season from July 5 to July 24. 3.Annual loadings from paddies could be calculated to 30kg T-N/ha/year and 52kg T-P/ha/year considering non-measurement periods. 4.After the rainy season, the nutrient loads from drained water showed much less than those from irrigated water, and it may be suggested that the paddies would act as a stabilization pond. 5.The average concentrations of nutrients at 0.9km downstream from investigated paddies were 2.02(T-N) mg/l and 0.52(T-P) mg/I, which were 1.82(T-N) mg/l and 0.056(T-P)mg/l lower than those of drained water from paddies.

  • PDF

온실멜론의 양액재배에 있어서 영양진단법 확립을 위한 즙액분석 (A Study of Sap Analysis for the Establishment of Nutrient Diagnosis Method)

  • 장홍기;정순주
    • 생물환경조절학회지
    • /
    • 제6권4호
    • /
    • pp.310-316
    • /
    • 1997
  • 본 연구는 온실멜론의 양액재배에서 영양진단에 기초한 배양액관리를 하기 위해 유효한 수단으로 이용할 수 있고 신속하고 간편하며 정확한 즙액분석 방법(질산태질소의 정량방법, 인산정량방법, 즙액추출법, 추출비율, 마쇄시간 및 샘플채취 부위 등)들에 관한 비교검토를 하였다. 'Earl's Favorite 춘계를 1993년 1월 11일에 파종하여 본엽 3∼4매의 묘를 정식하여 비순환 방식으로 재배했다. 즙액분석법은 결핍이나 과잉증상이 외관적으로 나타나기 전에 신속하고 간이한 즙액분석법에 의해 물체의 영양상태를 진단하여 대응이 가능하다고 판단되었다. 즙액분석시 질산태질소의 분석에는 자외부 흡광도법, 인산분석에는 바나드몰리브덴산법이 추천되었고, 추출비율은 1:4로, 엽병의 마쇄시간은 60초, 그리고 채취부위는 일정부위로 하는 것이 바람직하다고 판단되었다. 그러나 샘플채취시간에 대해서는 채취시간에 따른 차이가 크기 때문에 앞으로 보다 상세한 검토가 요청되었다.

  • PDF

Influence of Soil and Forage Minerals on Buffalo (Bubalus bubalis) Parturient Haemoglobinuria

  • Akhtar, M.Z.;Khan, A.;Sarwar, M.;Javaid, A.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제20권3호
    • /
    • pp.393-398
    • /
    • 2007
  • The present study was carried out to investigate the serum minerals profile in buffaloes (Bubalus bubalis) suffering from parturient haemoglobinuria (PHU) along with minerals profile of soils and fodders from the disease prone areas and their interrelationships. Serum samples were collected from 60 each of healthy and PHU affected buffaloes randomly selected from field cases. Serum samples were collected from each animal. Fifty composite soil samples were collected where PHU was prevalent. Fifty samples of fodders including leaves and stems being fed to the diseased buffaloes were collected. The difference in the levels of calcium and potassium between upper and lower soil surface of disease prone areas under study were statistically non-significant. The mean values of phosphorous, copper, iron, selenium and molybdenum in upper soil surface were significantly (p<0.05) higher than in lower soil surface. None of the fodders offered to the diseased animals met the dietary requirements of phosphorus and copper whereas none of the fodders was deficient in potassium, iron and selenium rather were having excess of potassium, iron and selenium. The concentration of calcium was adequate in lucerne, berseem, sarson and sorghum, while maize, sugarcane and wheat straw did not meet the required levels for dairy animals. Molybdenum contents in all fodders were adequate to meet the dietary requirements of the dairy buffaloes. Serum phosphorus, copper and selenium were significantly (p<0.001) lower whereas potassium, iron and molybdenum in buffaloes suffering from PHU were significantly (p<0.001) higher than in healthy buffaloes. It was concluded that phosphorous deficient soils play a major role by transferring this deficiency to plants and ultimately reaching to animals where hypophosphataemia is a consistent finding.

SWAT 모델을 이용한 외남천 유역의 토사 및 총인 유출량 분석 (Assessment of sediment and total phosphorous loads using SWAT in Oenam watershed, Hwasun, Jeollanam-do)

  • 이태수
    • 한국지역지리학회지
    • /
    • 제22권1호
    • /
    • pp.240-250
    • /
    • 2016
  • 본 연구에서는 섬진강의 지류이자 주암호로 유입되는 외남천 유역의 수량 및 수질을 분석하기 위하여 2012년부터 2013년까지 2년 간 수량과 수질 모니터링을 실시하였다. 수질은 부유토사와 총인에 대해 분석하였으며 기존 연구를 참조하여 수량 및 오염물질의 분석, 오염원과 토지이용과의 관계를 규명하고자 하였다. 유출량은 일반적으로 강수량의 크기에 따라 비슷한 패턴으로 반응하였으나 기상데이터(광주광역시)와의 지리적 차이 때문에 일부 차이를 보이기도 하였다. 측정된 데이터를 기반으로 SWAT(Soil and Water Assessment Tool) 모델을 이용하여 유역을 모의하였다. 2012년 데이터를 이용하여 모델을 보정하고 2013년 데이터를 이용하여 모델 검정을 실시하였다. 모델 보정 결과 수량 및 총인의 실측값과 예측값의 결정계수($R^2$)는 각각 0.6644와 0.5176으로 나타났고 모델 검정 결과에서는 다소 높은 0.7529와 0.7057을 보였다. 소유역별 토사유출량과 총인유출량을 분석하여 유역 관리에 있어 가장 중점을 두어야 할 지역을 선정하였다. 토지이용별 총인 배출량은 전체 유역면적의 5%를 차지하는 밭이 총인배출량의 53.6%를 차지하였고 그 다음으로 주거지 및 축산지역이 23.5%를 차지하였다.

  • PDF

저수태 한우와 번식장애 한우의 혈액화학치 및 호르몬 분석 (Analysis of Blood Chemical Values and Hormone of Repeat Breeder and Reproductive Disorder in Hanwoo)

  • 양부근;김종복;정희태;박춘근;김정익;황환섭;김현철
    • 한국가축번식학회지
    • /
    • 제23권2호
    • /
    • pp.175-180
    • /
    • 1999
  • 본 실험은 한우 번식장애우와 저수태우의 혈액 성분 및 성선호르몬(estrogen과 progesterone)의 농도를 비교 분석하여 번식우의 기초적인 생리지표를 확립시키는데 있다. 본 실험의 결과를 요약하면 다음과 같다. 1. 저수태 한우와 번식장애우 혈중 albumin, BUN, Ca, cholesterol, creatine, glucose, phosphorous, total protein 및 triglyceride 함량은 3.28$\pm$0.05 와 3.27$\pm$0.04 g/㎗, 11.07$\pm$0.61와 12.69$\pm$0.88 mg/㎗, 9.98$\pm$0.10와 9.56$\pm$0.11mg/㎗, 105.75$\pm$3.57와 126.78$\pm$5.66 mg/㎗, 1.62$\pm$0.05와 1.65$\pm$0.09 mg/㎗, 67.46$\pm$3.07와 76.97$\pm$3.76 mg/㎗, 6.13$\pm$0.36 와 6.11$\pm$0.26 mg/㎗, 5.82$\pm$0.08와 6.18$\pm$0.08 g/㎗ 및 12.82$\pm$1.46와 15.19$\pm$1.61 mg/㎗으로 나타났다. 2. 혈청의 중요한 성분중 하나인 요소태 질소, 칼슘 및 인의 함량이 번식 장애우와 저수태우의 경우 정상우보다 다소 높은 경향을 나타냈으며, 특히 콜레스테롤의 함량이 번식 장애우와 저수태우의 경우 정상우의 약 2배정도 현저히 높은 성적을 나타냈다. 3. 발정주기중 혈액내 progesterone 수준은 임신우와 비임신우에서 수정후 18일까지는 비슷한 수준(6.55$\pm$0.17, 5.46$\pm$0.18 ng/$m\ell$)을 보였으나 그 후 임신우에서는 점차 증가하였고 비임신우에서는 발정일 (0.18$\pm$0.03 ng/$m\ell$)에 급감하였다. 4. 번식 장애우와 저수태우의 혈중 estrogen과 progesterone 함량은 각각 57.42$\pm$5.03, 56.76$\pm$8.73 pg/$m\ell$과 6.26$\pm$0.83 ng/$m\ell$, 9.41$\pm$1.85 ng/$m\ell$으로서, 혈중 progesterone 농도가 정상우의 황체기 수준으로 유지되어 발정발현과 수태가 억제되는 것으로 나타났다.

  • PDF

High Flame Retardancy and High-strength of Polymer Composites with Synergistically Reinforced MOSw and EG

  • Kim, Chowon;Lee, Jinwoo;Yoon, Hyejeong;Suhr, Jonghwan
    • Composites Research
    • /
    • 제35권5호
    • /
    • pp.359-364
    • /
    • 2022
  • Polymers are inherently vulnerable to flame, which limits their application to various high-tech industries. In addition, environmental regulations restrict the use of halogen-based flame retardants which has best flame-retardant effect. There are inorganic flame retardants and phosphorous flame retardants as representative non-halogen-based flame retardants. However, high content of flame retardants is required to impart high flame retardancy of the polymers, and this leads to a decrease in mechanical properties. In this research, a new approach for inorganic flame retardant-based polymer composites with high mechanical properties and flame retardancy was suggested. Inorganic flame retardants called as magnesium oxysulfate whisker (MOSw) were used in this research. MOSw can extinguish fire by releasing water and non-combustible gases when exposed to flame. In addition, they have reinforcing effect when added into the polymer with its high aspect ratio. Expandable graphite (EG) was used as a flame-retardant supplement by helping to form a more dense char layer. Through this research, it is expected that it can be applied to various industries requiring flame retardancy such as automobile, and architecture by replacing halogen-based flame polymer composites.

비만과 대사증후군 동반 여부에 따른 한국 성인 여성의 영양소 섭취 상태 평가 (Assessment for Nutrient Intakes in Korean Women according to Obesity and Metabolic Syndrome)

  • 정혜경;강주희;신민정
    • 대한지역사회영양학회지
    • /
    • 제15권5호
    • /
    • pp.694-703
    • /
    • 2010
  • Recent studies have reported that a subset of obese individuals who were metabolically healthy but obese had more favorable clinical outcomes than obese subjects with metabolic disturbances. The purpose of this study was to evaluate the distribution and agreement of obesity subtypes according to body mass index (BMI) and metabolic syndrome (MS). Furthermore, we examined the differences of nutrient intake among the groups. Data was analyzed for 1,095 female subjects older than 40 years using Korean National Health and Nutrition Survey in 2008. The degree of obesity was classified by two methods, using BMI (obese ${\geq}\;25\;kg/m^2$, not obese < $25\;kg/m^2$) and MS (meet ${\geq}\;3$ criteria among 5 index: waist circumference, triglyceride, glucose, HDL-cholesterol and blood pressure). Subjects were divided into 4 groups according to $2{\times}2$ cross table: non-obese without MS, non-obese with MS, obese without MS and obese with MS. Nutrient intakes were compared among 4 groups. The results showed that the proportions of non-obese without MS, non-obese with MS, obese without MS and obese with MS were 47.6%, 13.6%, 16.6%, and 22.2% of total subjects, respectively. The agreement (kappa value) of two methods was 0.354 (fair) in total subjects, 0.365 (fair) in 40-60 year old subjects and 0.304 (fair) in ${\geq}\;61$ year old subjects. In ${\geq}\;61$ years old subjects, intakes of percentage energy from carbohydrate, percentage of energy from fat, calcium, phosphorous, sodium, vitamin A, carotene, thiamine, riboflavin and niacin were significantly different among the groups. In contrast, the subjects of 40-60 years old, no differences in nutrient intakes were observed. In conclusion, there were differences in nutrient intakes among the groups subdivided by obesity and MS, especially in elderly female subjects. Individualized dietary guideline for subtype of obesity will be needed to treat metabolic disturbance of obesity.

개별교육프로그램이 역할불이행 혈액투석환자의 투석관련 지식, 이행 및 생리적 지표에 미치는 효과 (Effects of an Individualized Educational Program on Knowledge, Compliance and Physiologic Parameters in Non-Compliant Hemodialysis Patients)

  • 이수진;박향숙;한진희;김해진;서민원;최은아;임은영;최미란;최선숙;박광옥;김경옥
    • 임상간호연구
    • /
    • 제15권3호
    • /
    • pp.5-16
    • /
    • 2009
  • Purpose: This study was done to provide effective nursing interventions using an individualized educational program designed to contribute to the knowledge, compliance and physiologic parameters (serum potassium, phosphorus and interdialytic weight gain) of non-compliant hemodialysis patients. Methods: There were 22 participants in the experimental group and 19 in the control group. Nurses with rapport with patients provided education to non-compliant hemodialysis patients for 20 minutes three times a week for six weeks. This education program consisted of individual consulting, telephones conversations regarding hemodialysis, and requests for patient support from patients' families and colleagues. Results: Hypothesis 1; "Knowledge about hemodialysis in the experimental group will be higher than the control. group" was not supported. Hypothesis 2; "Compliance will be higher in the experimental group than in the control group", and Hypothesis 3; "Physiologic parameters of experimental group will improve" were supported as serum potassium and interdialytic weight gain decreased, but results were not consistent for phosphorous. Conclusion: This program for non-compliant patients increased compliance and improved physiologic parameters. Therefore, this educational program should be effective as a nursing intervention.