• Title/Summary/Keyword: non-linear boundary

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Effect of Sb/Bi Ratio on Sintering and Grain Boundary Properties of ZnO-Bi2O3-Sb2O3-Mn3O4-Co3O4 Varistor (Sb/Bi비가 ZnO-Bi2O3-Sb2O3-Mn3O4-Co3O4 바리스터의 소결과 입계 특성에 미치는 영향)

  • Hong, Youn-Woo;Lee, Young-Jin;Kim, Sei-Ki;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.878-885
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    • 2012
  • In this study we aims to examine the co-doping effects of 1/3 mol% $Mn_3O_4+Co_3O_4$ (1:1) on the reaction, microstructure, and electrical properties such as the bulk defects and grain boundary properties of $ZnO-Bi_2O_3-Sb_2O_3$ (ZBS; Sb/Bi=0.5, 1.0, and 2.0) varistors. The sintering and electrical properties of Mn,Co-doped ZBS, ZBS(MCo) varistors were controlled by Sb/Bi ratio. Pyrochlore ($Zn_2Bi_3Sb_3O_{14}$) was decomposed and promoted densification at lower temperature on heating in Sb/Bi=1.0 by Mn rather than Co. Pyrochlore on cooling was reproduced in all systems however, spinel (${\alpha}$- or ${\beta}$-polymorph) did not formed in Sb/Bi=0.5. More homogeneous microstructure was obtained in $Sb/Bi{\geq}1.0$ In ZBS(MCo), the varistor characteristics were improved drastically (non-linear coefficient, ${\alpha}$=30~49), and seemed to form $Zn_i^{..}$(0.17 eV) and $V_o^{\bullet}$(0.33 eV) as dominant defects. From impedance and modulus spectroscopy (IS & MS), the grain boundaries have divided into two types, i.e. the one is tentatively assign to $ZnO/Bi_2O_3(Mn,Co)/ZnO$ (0.47 eV) and the other ZnO/ZnO (0.80~0.89 eV) homojunctions.

Preliminary Study on the Development of a Platform for the Optimization of Beach Stabilization Measures Against Beach Erosion III - Centering on the Effects of Random Waves Occurring During the Unit Observation Period, and Infra-Gravity Waves of Bound Mode, and Boundary Layer Streaming on the Sediment Transport (해역별 최적 해빈 안정화 공법 선정 Platform 개발을 위한 기초연구 III - 단위 관측 기간에 발생하는 불규칙 파랑과 구속모드의 외중력파, 경계층 Streaming이 횡단표사에 미치는 영향을 중심으로)

  • Chang, Pyong Sang;Cho, Yong Jun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.31 no.6
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    • pp.434-449
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    • 2019
  • In this study, we develop a new cross-shore sediment module which takes the effect of infra-gravity waves of bound mode, and boundary layer streaming on the sediment transport into account besides the well-known asymmetry and under-tow. In doing so, the effect of individual random waves occurring during the unit observation period of 1 hr on sediment transport is also fully taken into account. To demonstrate how the individual random waves would affect the sediment transport, we numerically simulate the non-linear shoaling process of random wavers over the beach of uniform slope. Numerical results show that with the consistent frequency Boussinesq Eq. the application of which is lately extended to surf zone, we could simulate the saw-tooth profile observed without exception over the surf zone, infra-gravity waves of bound mode, and boundary-layer streaming accurately enough. It is also shown that when yearly highest random waves are modeled by the equivalent nonlinear uniform waves, the maximum cross-shore transport rate well exceeds the one where the randomness is fully taken into account as much as three times. Besides, in order to optimize the free parameter K involved in the long-shore sediment module, we carry out the numerical simulation to trace the yearly shoreline change of Mang-Bang beach from 2017.4.26 to 2018.4.20 as well, and proceeds to optimize the K by comparing the traced shoreline change with the measured one. Numerical results show that the optimized K for Mang-Bang beach would be 0.17. With K = 0.17, via yearly grand circulation process comprising severe erosion by consecutively occurring yearly highest waves at the end of October, and gradual recovery over the winter and spring by swell, the advance of shore-line at the northern and southern ends of Mang-Bang beach by 18 m, and the retreat of shore-line by 2.4 m at the middle of Mang-Bang beach can be successfully duplicated in the numerical simulation.

Thermal Bridge and Heat Transfer Analysis for Each Part in Residential Building According to Construction of Wood-based Finishing Material (목질 마감재 구성에 따른 주거용 건축물 부위별 열교 및 전열성능 분석)

  • Seo, Jungki;Jeong, Su-Gwang;Kim, Sumin
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.3
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    • pp.343-359
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    • 2017
  • Many researches and policies have been carried out for saving energy in buildings. However, there are a few studies of thermal characteristics of wood-based materials that have been widely used as structural materials and finishing materials in buildings. In this study, thermal bridging areas were found to investigate thermal performance of residential building using non wood-based materials and wood-based materials. And heat transfer analysis of 16 case studies according to composition of structural materials and finishing materials was conducted. Also in this experiment, Physibel Trisco was used as the heat transfer analysis simulation tool, which conforms to the calculation method of ISO 10211. Analytical modeling was also carried out according to the ISO 10211, and the boundary temperature conditions were set at room temperature $20^{\circ}C$ and outdoor temperature $-11.3^{\circ}C$ (Seoul standard) according to the energy saving design standard in South Korea. Applied structures are classified according to the cases of concrete structure with non wood-based finishing materials, concrete structure with wood-based finishing materials and wood structure. Analyzed building elements were divided into a wall, a roof, an interlayer floor and a bottom floor. As a result, it can be confirmed that the thermal bridge of the concrete structure and wood structure were caused by the geometrical and material causes. In addition, the structural thermal bridge was caused in the discontinuity of the insulation in the concrete structure. Also it was confirmed that the linear heat transfer coefficient of the wall decreases when the wood-based materials are applied to the concrete structure.

Sintering and Electrical Properties According to Sb/Bi Ratio(I) : ZnO-Bi2O3-Sb2O3-Mn3O4-Cr2O3 Varistor (Sb/Bi비에 따른 5원계 바리스터의 소결거동 및 전기적 특성(I) : ZnO-Bi2O3-Sb2O3-Mn3O4-Cr2O3)

  • Hong, Youn-Woo;Lee, Young-Jin;Kim, Sei-Ki;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.675-681
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    • 2012
  • We aimed to examine the co-doping effects of 1/6 mol% $Mn_3O_4$ and 1/4 mol% $Cr_2O_3$ (Mn:Cr = 1:1) on the reaction, microstructure, and electrical properties, such as the bulk defects and grain boundary properties, of ZnO-$Bi_2O_3-Sb_2O_3$ (ZBS; Sb/Bi = 0.5, 1.0, and 2.0) varistors. The sintering and electrical properties of Mn,Cr-doped ZBS, ZBS(MnCr) varistors were controlled using the Sb/Bi ratio. Pyrochlore ($Zn_2Bi_3Sb_3O_{14}$), ${\alpha}$-spinel ($Zn_7Sb_2O_{12}$), and ${\delta}-Bi_2O_3$ (also ${\beta}-Bi_2O_3$ at Sb/Bi ${\leq}$ 1.0) were detected for all of the systems. Mn and Cr are involved in the development of each phase. Pyrochlore was decomposed and promoted densification at lower temperature on heating in Sb/Bi = 1.0 system by Mn rather than Cr doping. A more homogeneous microstructure was obtained in all systems affected by ${\alpha}$-spinel. In ZBS(MnCr), the varistor characteristics were improved dramatically (non-linear coefficient, ${\alpha}$ = 40~78), and seemed to form ${V_o}^{\cdot}$(0.33 eV) as a dominant defect. From impedance and modulus spectroscopy, the grain boundaries can be seen to have divided into two types, i.e. one is tentatively assigned to ZnO/$Bi_2O_3$ (Mn,Cr)/ZnO (0.64~1.1 eV) and the other is assigned to the ZnO/ZnO (1.0~1.3 eV) homojunction.

Geostatistical Interpretation of Sparsely Obtained Seismic Data Combined with Satellite Gravity Data (탄성파 자료의 해양분지 구조 해석 결과 향상을 위한 인공위성 중력자료의 지구통계학적 해석)

  • Park, Gye-Soon;Oh, Seok-Hoon;Lee, Heui-Soon;Kwon, Byung-Doo;Yoo, Hai-Soo
    • Geophysics and Geophysical Exploration
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    • v.10 no.4
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    • pp.252-258
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    • 2007
  • We have studied the feasibility of geostatistics approach to enhancing analysis of sparsely obtained seismic data by combining with satellite gravity data. The shallow depth and numerous fishing nets in The Yellow Sea, west of Korea, makes it difficult to do seismic surveys in this area. Therefore, we have attempted to use geostatistics to integrate the seismic data along with gravity data. To evaluate the feasibility of this approach, we have extracted only a few seismic profile data from previous surveys in the Yellow Sea and performed integrated analysis combining with the results from gravity data under the assumption that seismic velocity and density have a high physical correlation. First, we analyzed the correlation between extracted seismic profiles and depths obtained from gravity inversion. Next, we transferred the gravity depth to travel time using non-linear indicator transform and analyze residual values by kriging with varying local means. Finally, the reconstructed time structure map was compared with the original seismic section given in the previous study. Our geostatistical approach demonstrates relatively satisfactory results and especially, in the boundary area where seismic lines are sparse, gives us more in-depth information than previously available.

Kinetic Behavior of Immobilized Tyrosinase on Carbon in a Simulated Packed-Bed Reactor (충전층에서 탄소에 고정시킨 Tyrosinase의 반응속도에 관한 연구)

  • Shin, Sun Kyoung;Kim, Kyeo-Keun
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.66-74
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    • 1997
  • Influence of the axial dispersion on immobilized enzyme catalytic bed was investigated in order to examine the kinetic behavior of the biocatalysis. The enzyme employed in this study was the tyrosinase(EC 1.14.18.1) immobilized on carbon support : this system requires two substrates of phenol and oxygen. This enzyme has potential application for phenol degradation in waste water. A simulated reactor was a packed-bed reactor of 2.54cm in diameter and 10cm long, loaded with the immobilized carbon particle with an average diameter of $550{\mu}m$. A phenol feed in the strength of 55.5mM(5220ppm) was used to observe the behavior of the immobilized enzyme column at three different dissolved oxygen levels of 0.08445mM(2.7ppm), 0.1689mM(5.4ppm) and 0.3378mM(9.5ppm) with the flow rates in the range of 60(1mL/s) to 180mL/min(3mL/s). Examination of the Biot number and Damkolher numbers of the immobilized system enables us to eliminate the contribution of external mass transfer to set of differential equations derived from the dispersion model. Solution of the equation was finally obtained numerically with the application of the Danckwert boundary conditions and the assumed zero-and first order rates on the non-linear two substrate enzyme kinetics. Higher conversion of phenol was observed at the low flow rates and at the higher oxygen concentration. Comparison of axial dispersion and plug flow model showed that no detectable difference was observed in the column outlet conversion between the axial and the plug flow models which was in complete agreement with the previous studies.

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Free Vibration Analysis of Circular Arches Considering Effects of Midsurface Extension and Rotatory Inertia Using the Method of Differential Quadrature (미분구적법을 이용 중면신장 및 회전관성의 영향을 고려한 원형아치의 고유진동해석)

  • Kang, Ki-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.9-17
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    • 2021
  • Curved beams are increasingly used in buildings, vehicles, ships, and aircraft, which has resulted in considerable effort being directed toward developing an accurate method for analyzing the dynamic behavior of such structures. The stability behavior of elastic circular arches has been the subject of a large number of investigations. One of the efficient procedures for the solution of ordinary differential equations or partial differential equations is the differential quadrature method DQM. This method has been applied to a large number of cases to overcome the difficulties of the complex computer algorithms, as well as excessive use of storage due to conditions of non-linear geometries, loadings, or material properties. This study uses DQM to analyze the in-plane vibration of the circular arches considering the effects of midsurface extension and rotatory inertia. Fundamental frequency parameters are calculated for the member with various parameter ratios, boundary conditions, and opening angles. The solutions from DQM are compared with exact solutions or other numerical solutions for cases in which they are available and given to analyze the effects of midsurface extension and rotatory inertia on the frequency parameters of the circular arches.

Modelling Gas Production Induced Seismicity Using 2D Hydro-Mechanical Coupled Particle Flow Code: Case Study of Seismicity in the Natural Gas Field in Groningen Netherlands (2차원 수리-역학적 연계 입자유동코드를 사용한 가스생산 유발지진 모델링: 네덜란드 그로닝엔 천연가스전에서의 지진 사례 연구)

  • Jeoung Seok Yoon;Anne Strader;Jian Zhou;Onno Dijkstra;Ramon Secanell;Ki-Bok Min
    • Tunnel and Underground Space
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    • v.33 no.1
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    • pp.57-69
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    • 2023
  • In this study, we simulated induced seismicity in the Groningen natural gas reservoir using 2D hydro-mechanical coupled discrete element modelling (DEM). The code used is PFC2D (Particle Flow Code 2D), a commercial software developed by Itasca, and in order to apply to this study we further developed 1)initialization of inhomogeneous reservoir pressure distribution, 2)a non-linear pressure-time history boundary condition, 3)local stress field monitoring logic. We generated a 2D reservoir model with a size of 40 × 50 km2 and a complex fault system, and simulated years of pressure depletion with a time range between 1960 and 2020. We simulated fault system failure induced by pressure depletion and reproduced the spatiotemporal distribution of induced seismicity and assessed its failure mechanism. Also, we estimated the ground subsidence distribution and confirmed its similarity to the field measurements in the Groningen region. Through this study, we confirm the feasibility of the presented 2D hydro-mechanical coupled DEM in simulating the deformation of a complex fault system by hydro-mechanical coupled processes.

Regional Topographic Characteristics of Sand Ridge in Korean Coastal Waters on the Analysis of Multibeam Echo Sounder Data (다중빔음향측심 자료분석에 의한 한국 연안 사퇴의 해역별 지형 특성)

  • BAEK, SEUNG-GYUN;SEO, YOUNG-KYO;JUNG, JA-HUN;LEE, YOUNG-YUN;LEE, EUN-IL;BYUN, DO-SEONG;LEE, HWA-YOUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.27 no.1
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    • pp.33-47
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    • 2022
  • In this study, distribution of submarine sand ridges in the coastal waters of Korea was surveyed using multibeam echo sounder data, and the topographic characteristics of each region were identified. For this purpose, the DEM (Digital Elevation Model) data was generated using depth data obtained from the Yellow Sea and the South Sea by Korea Hydrographic and Oceanographic Agency, and then applied the TPI (Topographic Position Index) technique to precisely extract the boundary of the sand ridges. As a result, a total of 200 sand ridges distributed in the coastal waters were identified, and the characteristics of each region of the sedimentary sediments were analyzed by performing statistical analysis on the scale (width, length, perimeter, area, height) and shape (width/length ratio, height/width ratio, linear·branch type, exposure·non-exposure type). The results of this study are expected to be used not only for coastal navigational safety, but also for marine naming support, marine aggregate resource identification, and fisheries resource management.

Fundamental Frequency Extraction of Stay Cable based on Energy Equation (에너지방정식에 기초한 사장 케이블 기본진동수 추출)

  • Kim, Hyeon Kyeom;Hwang, Jae Woong;Lee, Myeong Jae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1A
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    • pp.125-133
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    • 2008
  • According to longer and longer span, dynamic instability of stay cable should be prevented. Dynamic instability occurs mainly symmetric 1st mode and antisymmetric 1st mode in stay cable. Especially symmetric 1st mode has a lot of influence on sag. Therefore fundamental frequency of stay cable is different from that of taut sting. Irvine, Triantafyllou, Ahn etc. analyzed dynamic behavior of taut cable with sag through analytical technical and their researches give important results for large bounds of Irvine parameter. But each research shows mutually different values out of characteristic (cross-over or mode-coupled) point and each solution of frequency equations of all researchers can be very difficultly found because of their very high non-linearity. Presented study focuses on fundamental frequency of stay cable. Generalized mechanical energy with symmetric 1st mode vibration shape satisfied boundary conditions is evolved by Rayleigh-Ritz method. It is possible to give linear analytic solution within characteristic point. Error by this approach shows only below 3% at characteristic point against existing researches. And taut cable don't exceed characteristic point. I.e. high accuracy, easy solving techniques, and a little bit limitations. Therefore presented study can be announced that it is good study ergonomically.