• Title/Summary/Keyword: nitrogen flow rate

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Pyrolysis Reaction for the Treatment of Hazardous Halogenated Hydrocarbon Waste (유해 할로겐화 탄화수소 폐기물 처리를 위한 열분해 반응)

  • 조완근
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.399-407
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    • 1997
  • The pyrolysis reactions of atomic hydrogen with chloroform were studied In a 4 cm 1.6. tubular flow reactor with low flow velocity 1518 cm/sec and a 2.6 cm 1.4. tubular flow reactor with high flow velocity (1227 cm/sec). The hydrogen atom concentration was measured by chemiluminescence titration with nitrogen dioxide, and the chloroform concentrations were determined using a gas chromatography. The chloroform conversion efficiency depended on both the chloroform flow rate and linear flow velocity, but 416 not depend on the flow rate of hydrogen atom. A computer model was employed to estimate a rate constant for the initial reaction of atomic hydrogen with chloroform. The model consisted of a scheme for chloroform-hydrogen atom reaction, Runge-Kutta 4th-order method for Integration of first-order differential equations describing the time dependence of the concentrations of various chemical species, and Rosenbrock method for optimization to match model and experimental results. The scheme for chloroform-hydrogen atom reaction Included 22 elementary reactions. The rate constant estimated using the data obtained from the 2.6 cm 1.4. reactor was to be 8.1 $\times$ $10^{-14}$ $cm^3$/molecule-sec and 3.8 $\times$ $10^{-15}$ cms/molecule-sec, and the deviations of computer model from experimental results were 9% and 12% , for the each reaction time of 0.028 sec and 0.072 sec, respectively.

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Simple and Flexible Temperature Control System for Space Environment Test

  • Lee, Sang-Hoon;Cho, Hyok-Jin;Seo, Hee-Jun;Moon, Guee-Won;Choi, Seok-Weon
    • Bulletin of the Korean Space Science Society
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    • 2008.10a
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    • pp.29.1-29.1
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    • 2008
  • The temperature control system which is using liquid and gaseous nitrogen has been known as the most economical system to simulate space temperature condition due to relatively not expansive price of the liquid nitrogen (less than 0.2 USD per liter). And, among these systems, the closed loop system which circulates compressed nitrogen gas come from sprayed liquid nitrogen by blower and makes a target temperature with heat from an electrical heater and flow rate of liquid nitrogen is prevail all over the world. But, this complete closed loop system requires expansive equipments such as blower, heater, and liquid nitrogen injector, and special maintenance on the system. Therefore, KARI is developing efficient and simple open loop system which utilizes liquid and gaseous nitrogen with eliminating a special blower and other expansive units. In this study, this open loop system with more efficiency and flexibility will be designed and introduced.

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Simultaneous N-P Removal of Wastewater with Flow Variation by Anaerobic-Aerobic Activated Sludge Process(I) (혐기-호기 활성슬러지법에 의한 유량변동이 있는 폐수의 N-P 동시 제거에 관한 연구(I))

  • 이민규;서근학
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.509-516
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    • 1995
  • The treatment performances of anaerobic-aerobic activated sludge process were investigated under various operation conditions. The treatment system proposed in this study gave a relatively stable performance against hourly change of the flow rate and showed a satisfactory removal of nitrogen and phosphorus compounds under experimental conditions. The recycle ratio of mixed liquor from aerobic to anaerobic region and peak coefficient primarily controlled the extent of nitrogen removal. The recycle ratio had the optimum values which were determined by the microbial activities of nitrification and denitrification. The behavior of the treatment unit could be simulated by using the kinetic equations and reactor models which considered the treatment units as complete mixing tanks.

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Simultaneous N-P Removal of Wastewater with Flow Variation by Anaerobic-Aerobic Activated Sludge Process(I) (혐기-호기 활성슬러지법에 의한 유량변동이 있는 폐수의 N-P 동시 제거에 관한 연구(I))

  • Lee, Min-Gyu;Suh, Kuen-Hack
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.123-123
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    • 1995
  • The treatment performances of anaerobic-aerobic activated sludge process were investigated under various operation conditions. The treatment system proposed in this study gave a relatively stable performance against hourly change of the flow rate and showed a satisfactory removal of nitrogen and phosphorus compounds under experimental conditions. The recycle ratio of mixed liquor from aerobic to anaerobic region and peak coefficient primarily controlled the extent of nitrogen removal. The recycle ratio had the optimum values which were determined by the microbial activities of nitrification and denitrification. The behavior of the treatment unit could be simulated by using the kinetic equations and reactor models which considered the treatment units as complete mixing tanks.

Adsorption Properties of Ca-exchanged Clinoptilolite under Low-temperature (Ca 이온교환 Clinoptilolite의 저온 흡착 특성)

  • Song Taek-Yong;Lee Young-Chul;Baek Young-Soon;Kim Jong-Nam
    • Journal of the Korean Institute of Gas
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    • v.8 no.4 s.25
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    • pp.36-41
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    • 2004
  • The breakthrough curve was obtained to evaluate separation efficiency of clinoptilolite as an methane/nitrogen separation adsorbent. The Ca-exchanged clinoptilolite showed improved separation efficiency. The nitrogen adsorption capacity of Ca-clinoptilolite was increased with decreasing temperature. The temperature was decreased from 293K to 253K(feed gas flow rate : 670ml/min, pressure : 333kPa). The adsorption capacity is increased with increasing pressure. The pressure was increased from 333kPa to 700kPa(feed gas flow rate : 670ml/min, temperature : 253K, 293K).

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Optimization of Atmospheric Cold Plasma Treatment with Different Gases for Reduction of Escherichia coli in Wheat Flour

  • Lee, Jeongmin;Park, Seul-Ki;Korber, Darren;Baik, Oon-Doo
    • Journal of Microbiology and Biotechnology
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    • v.32 no.6
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    • pp.768-775
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    • 2022
  • In this study we aimed to derive the response surface models for Escherichia coli reduction in wheat flour using atmospheric cold plasma (ACP) with three types of gas. The jet-type atmospheric cold plasma wand system was used with a 30 W power supply, and three gases (argon, air, and nitrogen) were applied as the treatment gas. The operating parameters for process optimization considered were wheat flour mass (g), treatment time (min), and gas flow rate (L/min). The wheat flour samples were artificially contaminated with E. coli at a concentration of 9.25 ± 0.74 log CFU/g. ACP treatments with argon, air, and nitrogen resulted in 2.66, 4.21, and 5.55 log CFU/g reduction of E. coli, respectively, in wheat flour under optimized conditions. The optimized conditions to reduce E. coli were 0.5 g of the flour mass, 15 min of treatment time, and 0.20 L/min of nitrogen gas flow rate, and the predicted highest reduction level from modeling was 5.63 log CFU/g.

The Effect of N2 Dilution on the Flame Stabilization in a Non-Premixed Turbulent H2 Jet with Coaxial Air (질소 희석이 수소 난류확산화염의 화염안정성에 미치는 영향)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.7
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    • pp.477-485
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    • 2009
  • The study of nitrogen dilution effect on the flame stability was experimentally investigated in a non-premixed turbulent lifted hydrogen jet with coaxial air. Hydrogen gas was used as a fuel and coaxial air was used to make flame liftoff. Each of hydrogen and air were injected through axisymetric inner and outer nozzles ($d_F=3.65\;mm$ and $d_A=14.1\;mm$). And both fuel jet and coaxial air velocity were fixed as $u_F=200\;m/s$ and $u_A=16\;m/s$, while the mole fraction of nitrogen diluents gas was varied from 0.0 to 0.2 with 0.1 step. For the analysis of flame structure and the flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF laser diagnostics had been performed. The stabilization point was selected in the most upstream region of the flame base and defined as the point where the turbulent flame propagation velocity was equal to the axial component of local flow velocity. We found that the turbulent flame propagation velocity increased with the decrease of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity and axial strain rate, even though nitrogen diluents mole fraction was changed.

Experimental investigation on No-Vent Fill (NVF) process using liquid Nitrogen

  • Kim, Youngcheol;Seo, Mansu;Yoo, Donggyu;Jeong, Sangkwon
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.4
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    • pp.71-77
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    • 2014
  • For a long-term space mission, filling process of cryogenic liquid propellant is operated on a space vehicle in space. A vent process during transfer and filling of cryogenic propellant is needed to maintain the fuel tank pressure at a safe level due to its volatile characteristic. It is possible that both liquid and vapor phases of the cryogenic propellant are released simultaneously to outer space when the vent process occurs under low gravity environment. As a result, the existing filling process with venting not only accompanies wasting liquid propellant, but also consumes extra fuel to compensate for the unexpected momentum originated from the vent process. No-Vent Fill (NVF) method, a filling procedure without a venting process of cryogenic liquid propellant, is an attractive technology to perform a long-term space mission. In this paper, the preliminary experimental results of the NVF process are described. The experimental set-up consists of a 9-liter cryogenic liquid receiver tank and a supply tank. Liquid nitrogen ($LN_2$) is used to simulate the behavior of cryogenic propellant. The whole situation in the receiver tank during NVF is monitored. The major experimental parameter in the experiment is the mass flow rate of the liquid nitrogen. The experimental results demonstrate that as the mass flow rate is increased, NVF process is conducted successfully. The quality and the inlet temperature of the injected $LN_2$ are affected by the mass flow rate. These parameters determine success of NVF.

Size Control of Bismuth Nanoparticles by Changes in Carrier-Gas Flow Rate and Chamber Pressure of Gas Condensation Apparatus (가스응축장치 캐리어가스 공급속도 및 압력변화를 통한 비스무스 나노분말 입도제어)

  • Lee, Gyoung-Ja;Kim, Chang-Kyu;Lee, Min-Ku;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.17 no.5
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    • pp.379-384
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    • 2010
  • In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 $m^2g^{-1}$ of specific surface area and 45.6 nm of average particles diameter.

Performance improvement of countercurrent-flow membrane gas absorption in a hollow fiber gas-liquid membrane contactor

  • Ho, Chii-Dong;Sung, Yun-Jen;Chen, Wei-Ting;Tsai, Feng-Chi
    • Membrane and Water Treatment
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    • v.8 no.1
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    • pp.35-50
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    • 2017
  • The theoretical membrane gas absorption module treatments in a hollow fiber gas-liquid membrane contactor using Happel's free surface model were obtained under countercurrent-flow operations. The analytical solutions were obtained using the separated variable method with an orthogonal expansion technique extended in power series. The $CO_2$ concentration in the liquid absorbent, total absorption rate and absorption efficiency were calculated theoretically and experimentally with the liquid absorbent flow rate, gas feed flow rate and initial $CO_2$ concentration in the gas feed as parameters. The improvements in device performance under countercurrent-flow operations to increase the absorption efficiency in a carbon dioxide and nitrogen gas feed mixture using a pure water liquid absorbent were achieved and compared with those in the concurrent-flow operation. Both good qualitative and quantitative agreements were achieved between the experimental results and theoretical predictions for countercurrent flow in a hollow fiber gas-liquid membrane contactor with accuracy of $6.62{\times}10^{-2}{\leq}E{\leq}8.98{\times}10^{-2}$.