• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.2
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• pp.127-135
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• 1997

Experiments have been conducted to investigate emission characteristics of compressed natural gas fueled vehicle(CNGV) by the FTP 75 mode test. Its purification technologies were also investigated. It was found that CNGV was operated on the rich A/F condition by comparison with gasoline vehicle. The Pd catalyst was higher in methane purification performance than Pt and Pd/Pt/Rh catalysts. Up to 60% portion of the accumulative HC emissions(that contains above 80% methane) form CNGV occurs during the first phase of the FTP 75 mode. CO that is exhausted at rich conditions of the air-fuel ratio more than lean conditions should be used for the catalytic reduction of NOX, because the methane is not the effective reduction for NOX in the CNGV with 3-way catalyst system.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.3
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• pp.373-382
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• 2013

In this study, a biological odor treatment system was proposed to remove odor(foul smell) materials causing several problems in the closed sewage treatment plant. This odor treatment system was composed of a two-step biofilter system in one reactor. The two-step biofilter reactor was constructed with natural purification layer in upper part and artificial purification layer in lower part. The reed grasses of water purification plants were planted in the surface area and mixed porous ceramic media were filled with the lower part of biofilter reactor. By using the above experimental apparatus, the ammonia gas removal efficiency was attained to 98.3 % and the hydrogen sulfide gas removal efficiency was appeared more than 97.7 % which shows more effective than the conventional odor removal process.

• Journal of the Korean Institute of Gas
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• v.23 no.2
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• pp.61-67
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• 2019

Korea is natural gas importer which imports a lot quantities which 20% of the volume of US exports in 2018. Biogas which can satisfy gas demand and respond effectively to climate change, will be an alternative. However, only 20% of biogas production is sold, which is also not efficient and difficult to use. The purpose of this study develops an optimal purification system for supplying biogas as city gas. We develope an optimal system by analyzing biogas for system selection, finding cases for system design, developing scenario, and developing a cost - benefit tool.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.172-172
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• 2011

Anaerobic digestion(AD) has successfully been used for many applications that have conclusively demonstrated its ability to recycle biogenic wastes. AD has been successfully applied in industrial waste water treatment, stabilsation of sewage sludge, landfill management and recycling of biowaste and agricultural wastes as manure, energy crops. During AD, i.e. organic materials are decomposed by anaerobic forming bacteria and fina1ly converted to excellent fertilizer and biogas which is primarily composed of methane(CH4) and carbon dioxide(CO2) with smaller amounts of hydrogen sulfide(H2S) and ammonia(NH3), trace gases such as hydrogen(H2), nitrogen(N2), carbon monoxide(CO), oxygen(O2) and contain dust particles and siloxanes. The production and utilisation of biogas has several environmental advantages such as i)a renewable energy source, ii)reduction the release of methane to the atomsphere, iii)use as a substitute for fossil fuels. In utilisation of biogas, most of biogas produced from small scale plant e.g. farm-scale AD plant are used to provide as energy source for cooking and lighting, in most of the industrialised countries for energy recovery, environmental and safety reasons are used in combined heat and power(CHP) engines or as a supplement to natural. In particular, biogas to use as vehicle fuel or for grid injection there different biogas treatment steps are necessary, it is important to have a high energy content in biogas with biogas purification and upgrading. The energy content of biogas is in direct proportion to the methane content and by removing trace gases and carbon dioxide in the purification and upgrading process the energy content of biogas in increased. The process of purification and upgrading biogas generates new possibilities for its use since it can then replace natural gas, which is used extensively in many countries, However, those technologies add to the costs of biogas production. It is important to have an optimized purification and upgrading process in terms of low energy consumption and high efficiency giving high methane content in the upgraded gas. A number of technologies for purification and upgrading of biogas have been developed to use as a vehicle fuel or grid injection during the passed twenty years, and several technologies exist today and they are continually being improved. The biomethane which is produced from the purification and the upgrading process of biogas has gained increased attention due to rising oil and natural gas prices and increasing targets for renewable fuel quotes in many countries. New plants are continually being built and the number of biomethane plants was around 100 in 2009.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.290-298
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• 2021

A purification process was performed for the application of natural graphite as an anode material. The influence of the structural change and impurity content of graphite according to the process on the anode electrochemical characteristics was investigated. Natural graphite was chemically/physically purified by acid-treatment which used different amounts of solution of ammonium fluoride/sulfuric acid in the same ratio and thermal treatment used different temperatures (800~2500 ℃). Acid-treatment had limitation to remove impurities, and identified that all impurity contents was removed except some traces of atom such as Si by after progressed thermal-treatment until 2500 ℃. The anode materials characteristic of graphite treated by purification process was improved, and changes in the structure and impurity contents affected dominantly the capacity, rate property and initial Coulombic efficiency. Consequently, the complex purification process improved the graphite structure and also the performance of lithium ion battery by controlling the excessive formation of solid electrolyte interphase and expanding Li⁺ insertion space originated from the effective removal of impurities.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.1
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• pp.92-100
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• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Journal of Hydrogen and New Energy
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• v.27 no.6
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• pp.628-635
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• 2016

Natural gas reformed hydrogen is used as a fuel of fuel cell vehicle, PSA process is used for the purification of reformed hydrogen. In this study, the performance of CO adsorbent in PSA process was evaluated. Zeolite adsorbents used in the commercial PSA process is used. The physical and chemical properties of adsorbents were characterized using BET apparatus, XRD, and FE-SEM. The breakthrough apparatus modified from GC was used for the CO breakthrough experiment, the quantitative analysis of CO adsorption capacity was performed using CO breakthrough curve. Zeolite 10X and 13X showed superior CO adsorption capacity than activated alumina. The CO adsorption capacity of zeolite 10X is more than twice of zeolite 13X even the BET surface area is low. It seems that the presence of $Ca^{2+}$ cation in zeolite 10X is beneficial to the adsorption of CO.

• Membrane Journal
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• v.20 no.4
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• pp.267-277
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• 2010

Gas separation membranes have been developed for decades in various areas to replace the conventional processes. Membrane processes for gas separation have many advantages of energy saving, compact size, and easy scale-up. Nowadays, gas separation processes is widely spreaded in nitrogen generating system, hydrogen generating system, membrane dryer, on board inert gas generating system, natural gas purification, biogas purification and fuel cells. Carbon dioxide separation process using membrane would be a strong candidate of carbon dioxide capturing process. In order to broaden the scope of application of gas separation membranes, development of new materials which can overcome the borderline of Robeson's plot should be necessary, so that many researchers and companies are trying to develop the new materials like polymers containing cardo and spiro group and PIMs (polymers for intrinsic microporosity).

• New & Renewable Energy
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• v.6 no.2
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• pp.27-32
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• 2010

Low Calorific Gas Turbine (LCGT) has been developed as a next generation power system using landfill gas (LFG) and biogas made from various organic wastes, food Waste, waste water and Livestock biogas. Low calorific fuel purification by pretreatment system and carbon dioxide fixation by green house system are very important design target for the optimum applications of LCGT. Main troubles of Low Calorific Gas Turbine system was derived from the impurities such as hydro sulfide, siloxane, water contained in biogas. Even if the quality of the bio fuel is not better than natural gas, LCGT may take low quality gas fuel and environmental friendly power system. The mechanical characterisitics of LCGT system is a high energy efficiency (>70%), wide range of output power (30 kW - 30 MW class) and very clean emission from power system (low NOx). A green house has been designed for four different carbon dioxide concentration from ambient air to 2000 ppm by utilizing the exhaust gas and hot water from LCGT system. LCGT is expected to contribute achieving the target of Renewable Portfolio Standards (RPS).

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.291-298
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• 2023

This research evaluates the sustainability of gasifying livestock manure to produce fuel gas from an economic and carbon emission perspective. The entire process, including gasification, fuel gas purification, and pipeline installation to transport the produced fuel gas to the demanding industrial complex, is analyzed for realistic feasibility. The study is conducted using an ASPEN PLUS simulation with experimental data. The results of the economic and CO₂ life cycle assessments confirm that the fuel gas produced from livestock manure is competitive with natural gas despite having a lower calorific value. When used as a fuel with a high hydrogen content, the fuel gas emits less CO₂ per calorific value, making it more environmentally friendly. A scenario analysis is also performed to determine the expected economics, with price competitiveness being influenced by several factors. Although a significant decrease in natural gas prices could reduce the price competitiveness of the proposed process, it can still be supported by government policies. The cash flow analysis also confirms the economic viability of the process.