• Journal of Korean Society on Water Environment
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• v.32 no.6
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• pp.628-648
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• 2016

Increased attention has been paid to the presence of veterinary antibiotics in various environmental matrices due to their toxicological behavior in the ecosystem and development of antibiotic-resistant strains of pathogenic bacteria. In the this review, 37 target antimicrobials were selected based on annual sales of antibiotics for livestock in South Korea 2014. Also, extraction and clean-up methods for the determination of the antibiotic residues in liquid samples including water, milk, and honey were comprehensively reviewed in the literature. Solid-phase extraction (SPE) was commonly used as a pre-treatment method for the samples. Most of the analytes were extracted in acidic conditions (2.5~4.0) except for aminoglycosides, which were extracted in neutral conditions (7.0~8.0). ${\beta}-Lactams$ showed the highest recoveries in neutral pH due to their degradation characteristics in acidic media. Starta-X, Oasis HLB, and Oasis MCX were frequently applied as an SPE cartridge and Oasis HLB showed the highest recoveries for the majority of antibiotic classes. The homogenized honey and milk were extracted by mixing with acids for deproteinization. Solids and other interfering substances in the extract were eliminated by centrifugation followed by membrane filtration or SPE before injection into HPLC.

• Journal of Korean Society on Water Environment
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• v.32 no.6
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• pp.649-669
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• 2016

This study explored the analytical conditions for 21 veterinary antibiotics which have been popularly sold in South Korea in 2014 but have not yet been targeted in EPA method 1694. Most of the selected antibiotics were separated by a reverse-phase C18 column with a combination of (buffered) water and organic polar solvent, which was commonly methanol and acetonitrile in the gradient elution mode. Volatile additives such as formic acid, ammonium acetate and ammonium formate were usually added to the mobile phases to minimize asymmetrical and tailing of antibiotics' peaks and to increase their ionization in mass spectrometry. The analytical methods of aminoglycoside antibiotics were distinct from those of the other antibiotics in terms of adoption of ion-pair chromatography (IPC) and hydrophilic interaction liquid chromatography (HILIC) capable of retaining and separating extremely polar compounds due to their hydrophilicity. Trifluoroacetic acid or heptafluorobutyric acid was frequently added to the mobile phase as an ion-pair reagent for the IPC. Tandem mass spectrometry was numerously applied to the detection of antibiotics using positive electrospray ionization (ESI) and the selected reaction monitoring (SRM) mode. All reviewed analytical methods had been/were validated by evaluating recovery, limits of detection and quantification, decision limit or detection capability of the methods.

• Journal of Korean Society on Water Environment
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• v.31 no.6
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• pp.732-738
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• 2015

Water quality in four major river basin in Korea was managed with Total Maximum Daily Load (TMDL) System. The unit watershed in TMDL system has been evaluated with Target Water Quality (TWQ) assessment using average water quality, without considering its volume of water quantity. As results, although unit watershed are obtained its TWQ, its allocated loads were not satisfied and vice versa. To solve these problems, a number of TWQ assessments with using Load Duration Curve (LDC) have been studied at other watersheds. The purpose of this study was to evaluate achievement of TWQ with Flow Duration Curve (FDC) and Load Duration Curve(LDC) at 26 unit watersheds in Han river basin. The results showed that achievement rates in TWQ assessment with current method and with LDC were 50~56 % and 69~73%, respectively. Because of increasing about 20% of achievement rates with using LDC, the number of exceeded unit watershed at Han river Basin was decreased about 4~6 unit watersheds.

• Journal of Korean Society of Water and Wastewater
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• v.35 no.3
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• pp.187-196
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• 2021

When evaluating the extent of the impact of water pollutants on the surrounding area, we would like to present the target level (proposal) of the quality of the environment, which is the standard for evaluation. We propose the environmental quality target level for substances that need to be applied domestically by investigating overseas cases operating the integrated environmental management system and the implications of domestic environmental pollutant management. The appropriateness of the environmental quality target level reviewed in this study was determined using data from the water quality measuring network, and future improvement measures were proposed. We review the available methodologies for setting quality objectives for the environment. It proposed the environmental quality target level for 21 substances that have domestic water pollutant emission standards and do not have environmental standards, and proposed future improvement measures. If it is necessary to add quality target-level items of the environment in the future, it is believed that expansion will be possible based on the methodology presented in this study.

• Journal of Korean Society on Water Environment
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• v.29 no.4
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• pp.531-539
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• 2013

In order to apply a water quality indicator as a certain target pollutant, the indicator should have the representability of an index for the management of Total Maximum Daily Loads (TMDLs). Scientific groundwork and treatment technologies also should be provided for the application of the indicator. This study analyzed the applicability of major water quality indicators for target pollutants. The results showed that four water quality indicators of TOC, T-N, SS & T-Coli can be considered as target pollutants besides existing BOD and T-P. These indicators can be applied with the preparations such as essential basic data, pollution load estimation framework as well as legal criteria setting when the need is raised. As the importance of TOC, which is considered as a replacement of BOD, is emphasized, technical and institutional terms are being prepared in order to determine TOC as another target pollutant in the near future. It could be considered to combine TOC with BOD for the time being during the $3^{rd}$ stage of TMDLs in view of the present conditions for the management of TOC. TOC can be the most effective index for the organic matter and help to be managed more systematically in the waterbodies where rivers and lakes are mutually connected.

• Journal of fish pathology
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• v.34 no.2
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• pp.225-231
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• 2021

In biofloc culture for olive flounder, Paralichthys olivaceus, the possibility of antibiotics treatment was investigated against edwardsiellosis. After inducing edwardsiellosis by immersion in Edwardsiella tarda 1.2 × 10⁵/mL suspension, the survival trends on various biofloc water management and some physiological changes were observed. For biofloc water management, six types of water treatments were carried out, which were no exchange without antibiotics as negative control, the exchange to stored biofloc water, the exchange to stored biofloc water with 20% flow-through, the exchange to fresh biofloc water, half fresh biofloc water and half sea water, and the complete flow-through. There was no significant physicochemical change on water qualities in any type. The exchange to fresh biofloc water was shown the highest survival ratio as 72.3%, and in case of stored biofloc water with 20% flow-through, the survival ratio was also significantly high as 62%. Plasma glucose, cholesterol, total protein, calcium, and magnesium were analyzed as physiological index. Mostly, there was no significant change, but plasma cholesterol showed an initial decrease in low survival group, and an initial increase with high survival group. Consequently, antibiotic treatment against a bacterial disease during biofloc culture is possible as long as the biofloc water management follow along properly.

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.235-235
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• 2017

• KCID journal
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• v.17 no.2
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• pp.95-104
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• 2010

Water quality data for 10 years (2000~2009) from about 826 reservoirs that are operated as a agricultural water quality survey network were analyzed in order to seek water quality management plan based on physical and chemical characteristics of agricultural reservoirs. The 95% reservoirs that exceed agricultural water quality standard of Chl-a (35mg/ $m^3$) had effective water depth shallower than 5m. The reason was that the reservoirs had more inflows of nutrient salts from the watershed, bigger surface water area of weak structure to algae occurrence. As the reservoirs of effective water depth shallower than 5m cover 49% of benefited area for irrigation, it is critical for agricultural water quality management of the reservoirs. The water quality of reservoir with shallower than 5m effective water depth was worse than reservoir with deeper than 5m effective water depth. Therefore, it is desirable that effective water depth of reservoirs make more than 5m for water quality management by building the bank higher and dredging the bottom of reservoirs.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.676-681
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• 2008

The evaluation of the effluent water quality of sewage treatment plant is one of the most important factor in calculating total maximum daily loads (TMDLs). Current method to calculate 95% upper limit of effluent water quality of sewage treatment plant assuming normal distribution of data needs to be implemented in case of non-normal distribution. We have investigated the applicability of percentile ranking method as a non-parametric statistical analysis in case of non-normal distribution of data.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.767-772
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• 2008

Studies regarding the application of the impervious cover rate as a watershed management index have increased in number due to concerns over watershed management. The impervious cover rate is suggested as an index that can manage not only water quality but also water volume and the water ecosystem. This study intends to prove its applicability through the interconnection of the impervious cover rate and the water environment in Korea. Analysis of a selected watershed with reference to impervious cover rates showed that a watershed with an impervious cover rate of over 30% had a direct runoff in excess of 60% of precipitation, while a watershed with an impervious cover rate of 7% had a direct runoff of 39%. Watersheds with higher impervious cover rates were also found to have higher BOD, though different watersheds showed slightly different aspects in connection with BOD. Monitoring of benthic macroinvertebrates showed that species inhabiting clean water appear more frequently in areas with lower impervious cover rates than areas with higher impervious cover rates, and in mainstream areas, relatively larger numbers of species appeared in areas with lower impervious cover rates. This suggests that impervious cover rates can be appropriately used as an index for watershed management, as it effectively represents changes to the water environment.