• Title/Summary/Keyword: nano structure

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Preparation of Core-Shell Structured BaTiO3 Powder Via Coating of Cr2O3 and Mn2O3 (Cr2O3 및 Mn2O3의 코팅에 의한 Core-Shell 구조의 BaTiO3 분말 제조)

  • Kwon, Byung-Soo;Lee, Hye-Un;Jang, Jung-Yoon;Lee, Sang-Kil;Chung, In Jae;Cho, Young-Sang;Park, Tae-Jin;Choi, Guang-Jin
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.99-105
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    • 2008
  • Core-shell structured $BaTiO_3$ powders were produced via nano-coating of $Cr_2O_3$ and $Mn_2O_3$ to barium titanate powder system for MLCCs. From preliminary experiments, the optimal solution reaction condition employing using $KMnO_4$, $K_2Cr_2O_4$ and sulfur was established. Not only powders of $Cr_2O_3$ and $Mn_2O_3$ were synthesized but also their coating on $BaTiO_3$ powders were peformed under the same reaction condition. The coating was carried out in two ways, one-step and two-step, and its results were characterized for comparison. Conclusively speaking, two oxide additives were coated onto the $BaTiO_3$ powder surface with high quality and excellent reaction yield even under mild condition, which indicates that the contents as well as the properties of additive shell layer can be precisely controlled with rather ease.

Luminescence Characteristic of CNT Element in ZnS:(Cu, Al) Thin Film Fabricated by a Screen Printing Method (스크린 프린팅 방법으로 제작한 ZnS:(Cu, AL) 박막의 CNT 불순물 첨가에 의한 광학적 특성에 관한 연구)

  • Shon, Pong-Kyun;Shin, Jun-Ha;Bea, Jae-Min;Lee, Jae-Bum;Kim, Jong-Su;Lee, Sang-Nam
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.1
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    • pp.23-33
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    • 2011
  • This experimental focus to characterize luminescence properties related to CNT (Carbon Nano Tube) element dispersedly implanted in ZnS-based phosphor thin film panel fabricated by a screen printing method. More specifically FE-SEM measurements, L-V(Luminescence vs. Voltage) and photo luminescence were carried out to determine an optimum value of CNT concentration and film thickness for the thin film structure of CNT-ZnS:(Cu, Al) by the screen printing method. We confirmed that an optimum value of CNT concentration in the ZnS:(Cu, Al) film panel is about 0.75 wt% resulting that the electric conductivity is 1.6 times higher than that of pure CNT sample and showing that the luminescence intensity is increasing until the optimum concentration. Clearly, CNT is presenting in the luminescence process providing a pathway for the creation of hot electron and a channel for the electron-hole recombination but overly inserted CNT may hinder to produce the hot electron for making an avalanching process. In case of the overly doped CNT 1.0 wt% in the ZnS-based phosphor, the luminescence intensity is decreasing although the electric conductivity is exponentially increasing. Based on these results, we realized that hot electron occurred by the external electric field or exciton arose by the external photon source are reduced dramatically over the critical value of CNT concentration because CNT element provide various isolated residues in the composites of ZnS based phosphor rather than pathway or channel for the D-A(Donnor to Acceptor) pair transition or the radiative recombination of electron-hole.

Optical System Design of Compact Head-Up Display(HUD) using Micro Display (마이크로 디스플레이를 이용한 소형 헤드업 디스플레이 광학계 설계)

  • Han, Dong-Jin;Kim, Hyun-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.9
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    • pp.6227-6235
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    • 2015
  • The HUD has recently been downsized due to the development of micro display and LED technology as a see through information display device, gradually expands the application areas. In this paper, using a DLP micro display device designed a compact head-up display(HUD) optical system for biocular observation of the image exhibition area 5 inches. It was analyzed for each design element of the optical system in order to design a compacted HUD. DLP, projection optical system and concave image combiner were discussed the design approach and the characteristics. Through a connection structure analysis of each optical system, detailed design specifications were set up and designed the optical system in detail. Put a folded configuration in the form of a white diffuse reflector between the projection lens and concave image combiner was designed to be independent, respectively. Distance of the projected image is adjustable up to approximately 2m ~ infinity and observation distance is 1m. Resolution could be recognized by 1 ~ 2pixels in HD($1,280{\times}720pixels$) class, various characters and symbols could be read. In addition, color navigation map, daytime video camera and thermal imaging cameras can be displayed.

Effects of SIS Sponge and Bone Marrow-Derived Stem Cells on the Osteogenic Differentiation for Tissue Engineered Bone (SIS 스폰지와 골수유래줄기세포를 이용한 조직공학적 골분화 유도)

  • Park Ki Suk;Jin Chae Moon;Yun Sun Jung;Hong Keum Duck;Kim Soon Hee;Kim Moon Suk;Rhee John M.;Khang Gilson;Lee Hai Bang
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.501-507
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    • 2005
  • Small intestinal submucosa (SIS) had been widely used as a biomaterial without immune rejection responses. SIS sponges prepared by crosslinking with 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC). SIS powders dissolved in $3\%(v/v)$ acetic acid aqueous solution for 48hrs and freeze-dried. EDC solution ($H_2O$ : ethanol = 5 : 95) as a crosslink agent was used in concentration of 100mM. In vitro, rat-BMSCs seeded in SIS sponges and induced the osteogenesis for 28 days. We have characterized the osteogenic potential of rat-BMSCs in SIS sponges by alkaline phosphatase activity(ALP), n assay, SEM and RT-PCR for osteogenic phenotype. In SEM, all morphology of SIS sponges was regular and showed interconnected pore structure. By RT-PCR analysis, we observed type I collagen expression. These results demonstrate osteogenic differentiation of rat-BMSCs. In conclusion, we confirmed that the morphology of surface, cross-section, and side of SIS sponges were highly porous with good interconnections between each pores, which can support the surface of cell growth, proliferation, and differentiation. This result indicates that SIS sponge is useful for osteogenesis of BMSCs.

Synthesis of ceria by combination of spray pyrolysis, postheat, and ball-milling and its characterization (분무열분해, 후소성 및 볼밀링을 조합한 방법을 이용한 세리아의 합성 및 특성연구)

  • Kim, Hyun-Ik;Kim, Sang Pil;Song, Jae-Kyung;Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1057-1072
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    • 2018
  • In this study, micro-sized $CeO_2$ particles were synthesized by spray pyrolysis, and EG(ethylene glycol) and CA(citric acid) as organic additives were added to obtain hollow and porous particle during spray pyrolysis, and characteristics of obtained ceria were investigated according to the amount of added organic additives. Spray pyrolysis, postheat and ball-milling were combined to give 6 paths. $CeO_2$ nano-sized particle was obtained by the path which has sequence of Spray Pyrolysis with 0.5 M of EG and CA${\rightarrow}$Post-heat${\rightarrow}$Ball-milling${\rightarrow}$Post-heat among 6 paths. The average particle size(24 nm with standard deviation of 3.8 nm) of $CeO_2$ nano-sized particle by TEM analysis is close to the primary particle size(20 nm) which was calculated by Debye-Scherrer equation. To investigate the morphological characteristics and structure of the synthesized nanoparticle powders, SEM(Scanning Electron Microscopy), XRD(X-Ray Diffractometer) and TEM(Transmission Electron Microscopy) were used.

A Study on the Application of GOCI to Analyzing Phytoplankton Community Distribution in the East Sea (동해에서 식물플랑크톤 군집 분포 분석을 위한 GOCI 활용 연구)

  • Choi, Jong-kuk;Noh, Jae Hoon;Brewin, Robert J.W.;Sun, Xuerong;Lee, Charity M.
    • Korean Journal of Remote Sensing
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    • v.36 no.6_1
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    • pp.1339-1348
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    • 2020
  • Phytoplankton controls marine ecosystems in terms of nutrients, photosynthetic rate, carbon cycle, etc. and the degree of its influence on the marine environment depends on their physical size. Many studies have been attempted to identify marine phytoplankton size classes using the remote sensing techniques. One of successful approach was the three-component model which estimates the chlorophyll concentrations of three phytoplankton size classes (micro-phytoplankton; >20 ㎛, nano-; 2-20 ㎛ and pico-; <2 ㎛) as a function of total chlorophyll. Here, we examined the applicability of Geostationary Ocean Colour Imager (GOCI) to the mapping of the phytoplankton size class distribution in the East Sea. A fit of the three-component model to a biomarker pigment dataset collected in the study area for some years including a large harmful algal bloom period has been carried out to derive size-fractioned chlorophyll concentration (CHL). The tuned three-component model was applied to the hourly GOCI images to identify the fractions of each phytoplankton size class for the entire CHL. Then, we investigated the distribution of phytoplankton community in terms of the size structure in the East Sea during the harmful Cochlodinium polykrikoides blooms in the summer of 2013.

Career map and course map recommendation system for employment (취업준비를 위한 career map and course map 추천 시스템)

  • Kwon, Wonhyun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2022.10a
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    • pp.276-279
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    • 2022
  • The 4th industrial revolution refers to the transition to a knowledge society in which the production speed of knowledge is fast and the proportion of the knowledge industry is greatly increased. The reorganization of the industrial structure and the change of occupations and jobs due to new technologies are bringing about changes in education, and the development of digital technology has made education that is borderless, individual and dynamic, becoming the new standard of education. With these changes, interest in nano-degrees on new technologies or micro-degrees focused on core courses rather than regular course degrees is increasing. As a representative example, Udacity in the United States has opened and operated online nanodegree courses related to jobs, and collaborates with major companies to develop and educate core training courses necessary for companies, thereby efficiently supporting companies in securing talent. With the revitalization of online vocational and job training, an environment has been prepared in which individuals can set goals for vocational competency development and continue their portfolio-based sustainable learning. However, for effective vocational education, automated and personalized educational content design should be preceded. To this end, in this paper, we propose a personalized career and course map recommendation system in the era of online learning

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The Effect of Employee's Entrepreneurship Level (Capacity, Attitude, CEO Support) on Entrepreneurial Culture, Structure and Operation Systems of Corporate: Focused on Design Corporate in Korea (조직 구성원의 기업가정신 수준(역량, 태도, CEO 지원)이 기업의 기업가적 문화와 구조, 운영체계에 미치는 영향: 국내 디자인기업을 중심으로)

  • Kim, Sun Joo;Choi, Seung Wook
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.11 no.4
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    • pp.103-116
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    • 2016
  • In uncertain future and the rapidly changing environment, it is necessary for companies to do innovative management activity. With business strategy that creates value and vision, The major industrialized countries ensure development of venture & start-up business and business competition by creating various added value through design. Thereby, Companies use design to increase enterprise value, a lots of interests and supports are focused in design industry which pioneer new market with new product and services. Therefore, Companies need more innovative and creative activities, and leads creative companies through developing entrepreneurship. Now, Companies should improve successful entrepreneurship, developing effective process in the organizational level beyond individual level. This research conducts empirical analysis from the individual and organizational perspective of corporate entrepreneurship. This study of design corporate 351 employees in design corporate is surveyed. This research finding is that design corporate employees' entrepreneurial capacity, entrepreneurial attitude and CEO support have meaningful effects on culture and structure. However, The analysis result indicates that this employees' entrepreneurial capacity, entrepreneurial attitude and CEO support have no effects on operation systems, so it is necessary to build the operation systems for activation of corporate entrepreneurship. This study puts emphasis on the needs to raise the level of corporate entrepreneurship and requires ways to improve entrepreneurship for sustainable growth. Also, This study suggests practical implications that it is important to systematic operation systems to actively utilize infrastructure, so it occurs in employees' entrepreneurship not only on the individual level, but also on the organizational level.

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Effect of Salinity Change on Biological Structure between Primary Producers and Herbivores in Water Column (해수층의 염분 변화가 일차생산자와 상위소비자의 크기구조에 미치는 영향)

  • SIN, YONGSIK;SOH, HOYOUNG;HYUN, BONGKIL
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.2
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    • pp.113-123
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    • 2005
  • Samples were collected to investigate the effect of salinity change on biological interaction between primary producers and herbivores in water column of the Youngsan estuary (Mokpo Harbor) at 8 stations from October 2003 to September 2004. The highest river freshwater inputs were introduced into the estuary from the Youngsan dike during summer (June and July 2004). Ranges of salinity were between 6 and 28.9 psu when the gates of dike were open whereas the ranges were between 24.4 and 30.3 psu when the gates were closed. Algal bloom occurred in February and July when the gates were not open at the upper region of the Youngsan estuary and the bloom was dominated $(70\%)$ by large cells of phytoplankton $(micro-sized;>20{\mu}m).\;Nano-sized (2-20{\mu}m)$ and pico-sized phytoplankton $(<2{\mu}m)$ were dominant in October, November 2003, June, August and September 2004 when the gates were open suggesting that size structure was affected by river discharge from the dike. Micro-and meso-zooplankton (herbivores) displayed the similar pattern to that of phytoplankton. The biomass of zooplankton was higher when the gates were closed than when the gates open and also the biomass was higher at the upper region of the harbor system. This results suggest that freshwater inputs affect size structure and biomass of phytoplankton by changing salinity, nutrient inputs, turbidity or light level In water column resulting in the change of the interaction between primary producters and herbivores in the Youngsan estuary.

Synthesis and Crystal Structure of Ag4Br4 Nanoclusters in the Sodalite Cavities of Fully K+-Exchanged Zeolite A (LTA)

  • Lim, Woo-Taik;Choi, Sik-Young;Kim, Bok-Jo;Kim, Chang-Min;Lee, In-Su;Kim, Seok-Han;Heo, Nam-Ho
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1090-1096
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    • 2005
  • $Ag_4Br_4$ nanoclusters have been synthesized in about 75% of the sodalite cavities of fully $K^+$-exchanged zeolite A (LTA). An additional KBr molecule is retained in each large cavity as part of a near square-planar $K_4Br^{3+}$ cation. A single crystal of $Ag_{12}$-A, prepared by the dynamic ion-exchange of $Na_{12}$-A with aqueous 0.05 M $AgNO_3$ and washed with $CH_3OH$, was placed in a stream of flowing 0.05 M KBr in $CH_3OH$ for two days. The crystal structure of the product ($K_9(K_4Br)Si_{12}Al_{12}O_{48}{\cdot}0.75Ag_4Br_4$, a = 12.186(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm m. It was refined with all measured reflections to the final error index $R_1$ = 0.080 for the 99 reflections for which $F_o\;{\gt}\;4_{\sigma}\;(F_o)$. The thirteen $K^+$ ions per unit cell are found at three crystallographically distinct positions: eight $K^+$ ions in the large cavity fill the six-ring site, three $K^+$ ions fill the eight-rings, and two $K^+$ ions are opposite four-rings in the large cavity. One bromide ion per unit cell lies opposite a four-ring in the large cavity, held there by two eight-ring and two six-ring $K^+$ ions ($K_4Br^{3+}$). Three $Ag^+$ and three $Br^-$ions per unit cell are found on 3-fold axes in the sodalite unit, indicating the formation of nano-sized $Ag_4Br_4$ clusters (interpenetrating tetrahedra; symmetry $T_d$; diameter ca. 7.9 $\AA$) in 75% of the sodalite units. Each cluster (Ag-Br = 2.93(3) $\AA$) is held in place by the coordination of its four $Ag^+$ ions to the zeolite framework (each $Ag^+$ cation is 2.52(3) $\AA$ from three six-ring oxygens) and by the coordination of its four $Br^-$ ions to $K^+$ ions through six-rings (Br-K = 3.00(4) $\AA$).