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http://dx.doi.org/10.12925/jkocs.2018.35.4.1057

Synthesis of ceria by combination of spray pyrolysis, postheat, and ball-milling and its characterization  

Kim, Hyun-Ik (Department of Chemical & Biological Engineering, Hanbat National University)
Kim, Sang Pil (Hannam University, Industry-Academic Cooperation Foundation)
Song, Jae-Kyung (Konkuk University, Industry-Academic Cooperation Foundation)
Kim, Sang Hern (Department of Chemical & Biological Engineering, Hanbat National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.35, no.4, 2018 , pp. 1057-1072 More about this Journal
Abstract
In this study, micro-sized $CeO_2$ particles were synthesized by spray pyrolysis, and EG(ethylene glycol) and CA(citric acid) as organic additives were added to obtain hollow and porous particle during spray pyrolysis, and characteristics of obtained ceria were investigated according to the amount of added organic additives. Spray pyrolysis, postheat and ball-milling were combined to give 6 paths. $CeO_2$ nano-sized particle was obtained by the path which has sequence of Spray Pyrolysis with 0.5 M of EG and CA${\rightarrow}$Post-heat${\rightarrow}$Ball-milling${\rightarrow}$Post-heat among 6 paths. The average particle size(24 nm with standard deviation of 3.8 nm) of $CeO_2$ nano-sized particle by TEM analysis is close to the primary particle size(20 nm) which was calculated by Debye-Scherrer equation. To investigate the morphological characteristics and structure of the synthesized nanoparticle powders, SEM(Scanning Electron Microscopy), XRD(X-Ray Diffractometer) and TEM(Transmission Electron Microscopy) were used.
Keywords
Ceria nanoparticle; Spray Pyrolysis; Postheat; Ball-milling; Organic Additive;
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1 T. Itoh, T. Uchida, N. Izu, I. Matsubara, W. Shin, "Effect of core-shell ceria/poly(vinylpyrrolidone)(PVP) nanoparticles incorporated in polymer films and their optical properties", J. Mater., Vol. 6, pp. 2119-2129, (2013).   DOI
2 J. F. de Lima, R. F. Martins, O. A. Serra, "Transparent UV-absorbers thin films of zinc oxide: ceria system synthesized via sol-gel process", J. Opt. Mater., Vol. 35, pp. 56-60, (2012).   DOI
3 C. Y. Chen, K. H. Chang, "Temperature independent resistive oxygen sensor prepared using zirconia-doped ceria powders", J. Sens. Actuators B: Chem., Vol. 162, pp. 68-75, (2012).   DOI
4 G. Vilee, B. Bridier, J. Wichert, J. P. Ramiirez, "Ceria in hydrogenation catalysis: high selectivity in the conversion of alkynes to olefins", Angew. Chem, Int. Ed., Vol. 51, pp. 8620-8623, (2012).   DOI
5 A. Alijani, A. Irankhah, "Effect of nickel addition on ceria-supported platinum catalysts for medium-temperature shift reaction in fuel processors", J. Chem. Eng. Technol., Vol. 36, No.4, pp. 552-558, (2013).   DOI
6 C. Laberty-Robert, J. W. Long, E. M. Lucas, K. A. Pettigrew, R. M. Stroud, M. S. Doescher, and D. R. Rolison, "Sol-Gel-Derived Ceria Nanoarchitectures: Synthesis, Characterization, and Electrical Properties", Chem. Mater., Vol. 18, pp. 50-58, (2006).   DOI
7 E. A. Trusova, A. A. Khrushcheva, K. V. Vokhmintcev, "Sol-gel synthesis and phase composition of ultrafine ceria-doped zirconia powders for functional ceramics", Journal of the European Ceramic Society, Vol. 32, No. 9, pp. 1977-1981, (2012).   DOI
8 M. Rumruangwong, S. Wongkasemjit, "Synthesis of ceria-zirconia mixed oxide from cerium and zirconium glycolates via sol-gel process and its reduction property", Applied Organometallic Chemistry, Vol. 20, No. 10, pp. 615-625, (2006).   DOI
9 B. Li, X. Wei, W. Pan, "Synthesis of doped ceria-zirconia core-shell nanocomposites via sol-gel process", Journal of Power Sources, Vol. 193, No. 2, pp. 598-601, (2009).   DOI
10 Z. Liu, D. Ding, M. Liu, X. Ding, D. Chen, X. Li, C. Xia, M. Liu, High-performance, "Ceria-based solid oxide fuel cells fabricated at low temperatures", J. Power Sour., Vol. 241, pp. 454-459, (2013).   DOI
11 Jong-Young Kim, Ung-Soo Kim, Woo-Seok Cho, "Synthesis of Ceria Nanosphere by Ultrasonic Spray Pyrolysis", Journal of the Korean Ceramic Society, Vol. 46, No.3, pp. 249-252, (2009).   DOI
12 C. M. Halmenschlager, R. Neagu, L. Rose, C. F. Malfatti, C. P. Bergmann, "Influence of the process parameters on the spray pyrolysis technique, on the synthesis of gadolinium doped-ceria thin film", Materials Research Bulletin, Vol. 48, No. 2, pp. 207-213, (2013).   DOI
13 Shao-Ju Shih, Ying-Ying Wu, Chin-Yi Chen, Chin-Yang Yu, "Controlled Morphological Structure of Ceria Nanoparticles Prepared by Spray Pyrolysis", Procedia Engineering, Vol. 36, pp. 186-194, (2012).   DOI
14 D.-H. Kim, H.-G. Kang, S.-K. Kim, U. Paik, J.-G. Park, "Effect of Calcination Process on Synthesis of Ceria Particles, and Its Influence on Shallow Trench Isolation Chemical Mechanical Planarization Performance", Japanese Journal of Applied Physics, Vol. 45, No.6, pp. 4893-4897, (2006).   DOI
15 B. Matovic, J. Dukic, B. Babic, D. Bucevac, Z. Dohcevic-Mitrovic, M. Radovic, S. Boskovic, "Synthesis, calcination and characterization of Nanosized ceria powders by self-propagating room temperature method", Ceramics International, Vol. 39, No. 5, pp. 5007-5012, (2013).   DOI
16 T. Taniguchi, Ken-ichi Katsumata, S. Omata, K. Okada, and N. Matsushita, "Tuning Growth Modes of Ceria-Based Nanocubes by a Hydrothermal Method", Cryst. Growth Des., Vol. 11, pp. 3754-3760, (2011)   DOI
17 M. Lundberg, B. Skarman, F. Cesar, L. R. Wallenberg, "Mesoporous thin films of high-surface-area crystalline cerium dioxide", Microporous and Mesoporous Materials, Vol. 54, pp. 97-103, (2002).   DOI
18 F. Heidari, A. Irankhahn, "Effect of surfactants and digestion time on nano crystalline cerium oxide characteristics synthesized by differential precipitation", Ceramics International, Vol. 40, pp. 12655-12660, (2014).   DOI
19 J. J. Ketzial and A. S. Nesaraj, "Synthesis of CeO2 nanoparticles by chemical precipitation and the effect of a surfactant on the distribution of particle sizes", Journal of Ceramic Processing Research, Vol. 12, No. 1, pp. 74-79, (2011).
20 H. Li, G. Lu, Q. Dai, Y. Wang, Y. Guo, and Y. Guo, "Hierarchical Organization and Catalytic Activity of High-Surface-Area Mesoporous Ceria Microspheres Prepared Via Hydrothermal Routes", Applied Materials and Interfaces, Vol. 2, No. 3, pp. 838-846, (2010).   DOI
21 Jin-Seok Lee, Sung-Churl Choi, "Crystallization behavior of nano-ceria powders by hydrothermal synthesis using a mixture of $H_2O_2$ and $NH_4OH$ Materials", Material Letters, Vol. 58, pp. 390-393, (2004).   DOI
22 Huey-Ing Chen, Hung-Yi Chang, "Synthesis of nanocrystalline cerium oxide particles by the precipitation method", Ceramics International, Vol. 31, pp. 795-802, (2005).   DOI