• Title/Summary/Keyword: n-doped

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The microstructure evolution and the efficiency of DSSC Counter Electrode with MWCNT addition (카본나노튜브 분산도에 따른 DSSC 상대전극 미세구조와 효율 변화)

  • Yu, Byung-Kwan;Han, Jeung-Jo;Noh, Yun-Young;Jang, Hyun-Chul;Sok, Jung-Hyun;Song, Oh-Sung
    • Proceedings of the KAIS Fall Conference
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    • 2011.05b
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    • pp.836-839
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    • 2011
  • 염료감응형 태양전지의 상대전극으로 MWCNT(multi-walled carbon nanotube)의 농도 (0.01~0.06g)를 달리하여 FTO(fluorine-doped tin oxide) glass에 분산시켜 상대전극을 만들었다. 그리고 glass/FTO/$TiO_2$/Dye(N719)/electrolyte(C6DMII,GSCN)/MWCNT/FTO/glass 구조를 가진 0.45$cm^2$급 DSSC(dye-sensitized solar cells) 소자를 만들었다. 소자의 미세구조, 분산정도, 광특성은 각각 광학현미경, SEM, source measure unit (Keithley model 2400) 장비를 이용하여 확인하였다. MWCNT 농도 증가와 FTO의 거친 표면형상에 따라 비선형적으로 MWCNT 분산면적이 증가하였고, MWCNT 농도 0.06g일 때 FTO 표면에 전체적으로 MWCNT가 완전히 분산됨을 확인하였다. 소자의 광변환 효율은 MWCNT 분산면적에 비례하는 효율을 보였고, MWCNT 분산농도인 0.06g 일 때 4.49%의 광변환 효율을 얻을 수 있었다.

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Alanysis of the Optical Properties of p-type ZnO Thin Films Doped by P based on Ampouele-tube Method (Ampoule-tube 법으로 Phosphorus를 도핑한 P형 ZnO 박막의 광학적 특성 분석)

  • Yoo, In-Sung;Oh, Sang-Hyun;So, Soon-Jin;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.145-146
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    • 2006
  • The most Important research topic in the development of ZnO LED and LD is the production of p-type ZnO thin film that has minimal stress with outstanding stoichiometric ratio. In this study, Phosphorus diffused into the undoped ZnO thin films using the ampoule-tube method for the production of p-type znO thin films. The undoped ZnO thin films were deposited by RF magnetron sputtering system on $GaAs_{0.6}P_{0.4}$/GaP and Si wafers. 4N Phosphorus (P) was diffused into the undoped ZnO thin films in ampoule-tube which was performed and $630^{\circ}C$ during 3hr. We found the diffusion condition of the conductive ZnO films which had p-type properties with the highest mobility of above 532 $cm^2$/Vs compared with other studies PL spectra measured at 10K for the purpose of analyzing optical properties of p-type ZnO thin film showed strong PL intensity in the UV emission band around 365nm ~ 415nm and 365nm ~ 385nm.

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An InGaAs/InAlAs multi-quantum well (MQW) avalanche photodiode (APD) with a spacer layer showing low dark current and high speed (고속 광통신 시스템을 위한 다중양자우물구조의 애벌런치 광다이오드의 설계 및 제작)

  • ;;D.L.Sivco;A.Y.Cho;J.M.M.Rios
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.440-444
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    • 1996
  • In this paper, we report an InGaAs/InAlAs multi-quantum well (MQW) avalanche photodiode (APD) showing a performance suitable for 10 Gbps lightwave communications. In designing the device, emphasis is given on the effect of indiffusion of Be dopant from the highly doped field layer into the MQW multiplication region. It is found that a small amount of diffusion can alter the dark current and gain characteristics of the device significantly. A spacer used to restrain such indiffusion is shown effective in reducing dark current (500 nA at a gain of 10) while maintaining a high bandwidth (10 GHz at a gain of 10) devices grown by molecular beam epitaxy.

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Studies on MMIC oscillator using HBT for X-band (X-band용 MMIC 오실레이터 설계연구)

  • Chae, Yeon-Sik;An, Dan;Rhee, Jin-Koo
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.387-390
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    • 1998
  • In this paper, HBT's with lower phase noise and passive elements, such as resistors, capacitors and inductors, for resonance and impedance matching networks are designed, fabricated, tested, and carefully analysed, respectively, and then, they are integrated for the design and fabrication of functional X-band oscillators with lower phase noise. Epi-wafers for HBT's with the structure of graded $Al_{x}$G $a_{1-x}$ As emitter and C-doped base layer of 700.angs. thick were used to specially emphasize the improvement of $f_{T}$ and $f_{max}$, and the lowering of phase noise, in design aspects. At the test frequencies of 12GHz, capacitances of MIM capacitors, spiral inductor, and resistances are 0.5~10pF, 0.4~11.06nH, and 20~1,380.ohm., respectively. The emitter size of HBY's for the X-band MMIC oscillators is 3*10u $m^{2}$, and find chip size is 0.9*0.9m $m^{2}$..EX>.

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Novel Application of Platinum Ink for Counter Electrode Preparation in Dye Sensitized Solar Cells

  • Kim, Sang Hern;Park, Chang Woo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.831-836
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    • 2013
  • Platinized counter electrode is common in most of the dye sensitized solar cell (DSSC) researches because of its high catalytic activity and corrosion stability against iodine in the electrolyte. Platinum (Pt) film coating on fluorine doped tin oxide (FTO) glass surface by using alcoholic solution of hexachloroplatinic acid ($H_2PtCl_6$), paste containing Pt precursors or sputtering are widely used techniques. This paper presents a novel application of Pt ink containing nanoparticles for making platinized counter electrode for DSSC. The characteristics of Pt films coated on FTO glass surface by different chemical methods were compared along with the performance parameters of the DSSCs made by using the films as counter electrodes. The samples coated with Pt inks were sintered at $300^{\circ}C$ for 30 minutes whereas Pt-film and Pt-paste were sintered at $400^{\circ}C$ for 30 minutes. The Pt ink diluted in n-hexane was found to a promising candidate for the preparation of platinized counter electrode. The ink may also be applicable for DSSC on flexible substrates after optimization its sintering temperature.

Synthesis and Luminescent Characteristics of $BaGa_{2}S_{4}:Eu^{2+}$ Phosphor by Solid-state Method

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • Journal of Information Display
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    • v.7 no.4
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    • pp.13-16
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    • 2006
  • II-$III_{2}-(S,Se)_{4}$ structured of phosphor have been used at various fields because they have high luminescent efficiency and broad emission band. Among these phosphors, europium doped $BaGa_{2}S_{4}$ was prepared by solid-state method. We investigated the possibility of applying [ ] due to emissive property of UV region. Also, general sulfide phosphors were synthesized by using injurious $H_{2}S$ $CS_{2}$ gas. However, this study prepared $BaGa_{2}S_{4}:Eu^{2+}$ phosphor is addition to excess sulfur under 5% $H_{2}$/95% $N_{2}$ reduction atmosphere. So, this process could involved large scale synthesis because of non-harmfulness and simple process. The photo-luminescence efficiency of the prepared $BaGa_{2}S_{4}:Eu^{2+}$ phosphor increased by 20% compared with commercial $BaGa_{2}S_{4}:Eu^{2+}$ phosphor. From this, we could conclude that the prepared $BaGa_{2}S_{4}:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

Effect of the Frit of the 2nd Firing Oxide in $SrTiO_3$-Based GBLC on the Dielectric Properties ($SrTiO_3$계 Grain Boundary Layer Capacitor에서 2차 열처리 산화물의 Frit화가 유전적 성질에 미치는 영향)

  • 유재근;최성철;이응상
    • Journal of the Korean Ceramic Society
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    • v.28 no.4
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    • pp.261-268
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    • 1991
  • The dielectric properties and microstructure of SrTiO3-based grain boundary layer (GBL) capacitor were investigated, and SrTiO3 GBL capacitor was made by penetrating the Frit (PbO-Bi2O3-B2O3 system). The Nb2O5-doped SrTiO3 ceramics were fired for 4-hours, at 145$0^{\circ}C$ in H2-N2 atomsphere to get semiconductive ceramics. The grain size of SrTiO3 sintered at reduction atmosphere had increased as the amount of Nb2O5 increases and then decreased as the amount of Nb2O5 exceeded 0.2 mole%. Insulating reagents which contained PbO-Bi2O3-B2O3 system frit and oxide mixture were printed on the each semiconductive ceramics and fired at varying temperature and for different holding time. The optimum dielectric properties could be obtained by second heat treatment at 110$0^{\circ}C$ for 1 hour, when frit paste was printed. A SrTiO3-based GBLC had the apparent permitivity of about 3.2$\times$104, the dielectric loss of 0.01~0.02 and the stable temperature coefficient of capacitance. The influence of frit paste on dielectric properties was similiar to that of oxide paste but the stability of temperature property of capacitance was improved.

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Synthesis and Luminescent Characteristics of $BaGa_2S_4:Eu^{2+}$ Phosphor by Solid-state Method

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1096-1099
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    • 2006
  • $II-III_2-(S,Se)_4$ structured of phosphor have been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, europium doped $BaGa_2S_4$ was prepared by solid-state method and we try to look into an application possibility due to an emissive property of UV region. Also, general sulfide phosphors were synthesized by using injurious $H_2S\;CS_2$ gas. However, this study prepared $BaGa_2S_4:Eu^{2+}$ phosphor is addition to excess sulfur under 5% $H_2/95%\;N_2$ reduction atmosphere. So, this process could large scale synthesis because of non-harmfulness and simple process. The photo-luminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could apply to green phosphor for white LED of three wavelengths.

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Hybrid Insulator Organic Thin Film Transistors With Improved Mobility Characteristics

  • Park, Chang-Bum;Jin, Sung-Hun;Park, Byung-Gook;Lee, Jong-Duk
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1291-1293
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    • 2005
  • Hybrid insulator pentacene thin film transistors (TFTs) were fabricated with thermally grown oxide and cross-linked polyvinylalcohol (PVA) including surface treatment by dilute ploymethylmethacrylate (PMMA) layers on $n^+$ doped silicon wafer. Through the optimization of $SiO_2$ layer thickness in hybrid insulator structure, carrier mobility was increased to above 35 times than that of the TFT only with the gate insulator of $SiO_2$ at the same transverse electric field. The carrier mobility of 1.80 $cm^2$/V-s, subthreshold swing of 1.81 V/decade, and $I_{on}$/ $I_{off}$ current ratio > 1.10 × $10^5$ were obtained at low bias (less than -30 V) condition. The result is one of the best reported performances of pentacne TFTs with hybrid insulator including cross-linked PVA material at low voltage operation.

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The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor (녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결)

  • Park, Young-Jo;Lee, Sung-Hoon;Jang, Wook-Kyung;Yoon, Chang-Bun;Yoon, Chul-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.