• Title/Summary/Keyword: n:2-격자

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The ionization energy and lattice parameters of Co- and Ce-doped cubic zirconia (YSZ) single crystal (Co와 Ce를 첨가한 큐빅지르코니아(YSZ) 단결정의 이온화에너지 및 격자상수)

  • Seok, Jeong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.4
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    • pp.159-163
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    • 2010
  • Co-(0.5 mol%) and Ce-(0~0.3 mol%) doped cubic zirconia ($ZrO_2:Y_2O_3$=64:36 mol%) single crystals grown by a skull melting method were heat-treated in $N_2$ at $1200^{\circ}C$ for 3 hrs. The brown-colored as-grown single crystals were changed into either green or blue color after the heat treatment. Before and after the heat treatment, the YSZ (yttriastabilized zirconia) single crystals were cut for wafer form (${\phi}7mm{\times}t2mm$) and round brilliant cut ($\phi$ 12 mm). The optical and structural properties were examined by UV-VIS spectrophotometer and X-ray diffraction. Absorption by $Ce^{3+}(^2F_{5/2},\;_{7/2}(4f){\rightarrow}^2T_g(5d^1)),\;Co^{2+}(^4A_2(^4F){\rightarrow}^4T_1(^4F)$ or $^4T_1(^4P))$ and $Co^{3+}$, change of ionization energy and lattice parameter were confirmed.

Fabrication of Nano-photonic Crystals with Lattice Constant of 460-nm by Inductively-coupled Plasma Etching Process (유도결합형 플라즈마 식각공정을 통해 제작된 460 nm 격자를 갖는 나노 광결정 특성)

  • Choi, Jae-Ho;Kim, Keun-Joo
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.2 s.15
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    • pp.1-5
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    • 2006
  • The GaN thin film on the 8 periods InGaN/GaN multi-quantum well structure was grown on the sapphire substrate using metal-organic chemical vapor deposition. The nano-scaled triangular-lattice holes with the diameter of 150 nm were patterned on a polymethylmethacrylate blocking film using an electron beam nano-lithography system. The thin slab and two-dimensional photonic crystals with the thickness of 28 nm were fabricated on the GaN layer for the blue light diffraction sources. The photonic crystal with the lattice parameter of 460 nm enhances spectral intensity of photoluminescence indicating that the photonic crystals provides the source of nano-diffraction for the blue light of the 450-nm wavelength.

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Superconducting Properties and Tunneling Spectroscopy of Bi2Sr2Ca(Cu1-xNix)2O8+δ Film by LPE Method (LPE법으로 성장시킨 Bi2Sr2Ca(Cu1-xNix)2O8+δ 막(film)의 초전도특성 및 터널링 분광)

  • 이민수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.455-459
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    • 2003
  • Tunneling spectra of B $i_2$S $r_2$Ca(C $u_{1-x}$ N $i_{x}$ )$_2$ $O_{8+}$$\delta$/ film by LPE method have been measured using break junctions. The energy gap 2$\Delta$ and 2$\Delta$/ $k_{B}$ $T_{c}$ $^{zero}$ increased with increase of ft. We obtained the energy gap Parameter 2$\Delta$(4.2 K) = 54.4~64 meV, and corresponding1y $\Delta$/ $k_{B}$ $T_{c}$ $^{zero}$=7.36~10.14, larger than the BCS value. The lattice constant c and critical temperature $T_{c}$ $^{zero}$ decrease with increase of $\chi$$_{L}$.

A study on the synthesis and formation behavior of nanostructrued TiN films by metal doping (금속원소 도핑에 따른 초고경도 나노구조 TiN 박막의 합성 및 형성 거동에 관한 연구)

  • 명현식;한전건
    • Journal of the Korean Vacuum Society
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    • v.12 no.3
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    • pp.193-199
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    • 2003
  • Ti-Cu-N and Ti-Ag-N nanocomposite films with various copper and silver contents were synthesized by arc ion plating and magnetron sputtering hybrid system. The structure and mechanical properties of these films were found to be dependant on the copper and silver concentration. The maximum hardness of Ti-Cu-N and Ti-Ag-N films showed approximately 40 ㎬ below 2 at%Me. The role of soft metallic phase in Ti-Me-N nanosturctured films containing one hard and one soft phase is also discussed.

Tunable $CO_2$ Laser for FIR Laser Pumping (원적외선 레이저 펌핑용 가변파장 $CO_2$ 레이저)

  • 진윤식;정기형;이헌주
    • Korean Journal of Optics and Photonics
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    • v.1 no.2
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    • pp.155-161
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    • 1990
  • A Continous wave tunable $CO_2$ laser which is the slow axial flow type was construccted for the optical pumping of methyl alcohol ($CH_3OH$) laser. The reflective grating of 100 grooveslmm and 10.6$\mu\textrm{m}$ blaze wavelength was used to select wavelength. We have investigated continous outpu: power characteristics, and then have compared tuned output power profile with the gain curve of $CO_2$ laser. The optimum condition for maxium power was found at the gas mixing ratio 1 : 3 : 10 for $CO_2: N_2$ and He. under this condition the flow rate, pressure of lasing gas and discharge current are 9.5 llmin. 14 torr, and 55 mA respectively. The maxium output power was 55 Wlm. Output power of single wavelength operation was measured on 60 individual rotation vibration transitions in the P and K branches of the 9.5$\mu\textrm{m}$ band and 10.4$\mu\textrm{m}$ band in $CO_2$. The output power profile obtained from each band is well consistent with the gain curve of $CO_2$ laser and maxium tuned output power was 20 watt.

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The development of a mesh generation program using contour line data (등고선 데이터를 이용한 산악지형 유동해석 격자생성 프로그램 개발 및 그 응용)

  • Chin S. M.;Won C. S.;Hur N.
    • Journal of computational fluids engineering
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    • v.9 no.4
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    • pp.7-12
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    • 2004
  • In the present study a semi-automatic mesh generation program has been developed by using DXF file containing contour line data. The program consists of DXF file reader and mapping algorithm. Pre-generated 2-D planar mesh points are to be mapped one by one onto triangular surface whose three vertices are three nearest contour points surrounding the mapping point. The present program has been successfully tested for mesh generations for the road tunnel ventilation analysis and analysis of lava movement in mountain area.

EFFECTS OF COMPUTATIONAL GRIDS ON NUMERICAL SIMULATION OF TRANSONIC TURBINE CASCADE FLOWFIELDS (천음속 터빈 익렬유동의 수치해석에서의 계산격자점 영향)

  • Chung H.T.;Jung H.N.
    • Journal of computational fluids engineering
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    • v.10 no.2
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    • pp.15-20
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    • 2005
  • Numerical investigations have been performed to examine the effects of the computational grids on the prediction of the flow characteristics inside the turbine cascades. Three kinds of grid system based on H-type grid are applied to the high-turning transonic turbine rotor blades and comparisons with the experimental data and the numerical results of each grid structure have been done. In addition, the grid sensitivity on the estimation of the blade performances has been investigated.

Enhanced cathode luminescence in $In_xGa_{1-x}N/In_yGa_{1-y}N$ green light emitting diode structure using two-dimensional photonic crystal (2차원 광자 결정을 이용한 $In_xGa_{1-x}N/In_yGa_{1-y}N$ 녹색 발광 다이오드의 음극선 발광 효율 증대)

  • Choi, E.S.;Nguyen, H.P.T.;Doan, H.M.;Kim, S.;Lim, H.;Lee, J.J.
    • Proceedings of the KIEE Conference
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    • 2007.11a
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    • pp.132-133
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    • 2007
  • $In_xGa_{1-x}N/In_yGa_{1-y}N$ 다중 양자우물 녹색 발광 다이오드에 2차원 광자 결정을 이용하여 음극선 발광의 향상을 관찰 하였다. 정사각형 배열의 2차원 광자 결정의 주기와 격자 상수는 200/500 nm 이고 전자빔 리소그래피로 광자결정 패턴을 제작한 후, 플라즈마 건식 식각법으로 패턴을 구현하였다. 식각 시간의 차이를 둔 구현된 패턴의 홀 깊이는, 각각 ${\sim}69nm,\;{\sim}99nm,\;{\sim}173nm$ 이었다. 전계 방사 주사 현미경 측정 결과, 형성된 홀은 끝이 잘린 역전된 원뿔 모양으로 식각 되었다. 식각 된 홀의 깊이에 따라 광자 결정이 있는 부분이 없는 부분보다 최대 ${\sim}30$배 많은 광자가 검출 됨을 확인하였다.

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Brief Review on the preparation of N-doped TiO2 and Its Application to Photocatalysis (질소 도핑 티타니아의 제조와 광촉매 활용의 연구동향)

  • Oh, Kyeongseok;Hwang, Duck Kun
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.331-337
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    • 2019
  • Titania has become the most applicable material for photocatalytic application. Nevertheless, titania has the weak point in its wide band gap energy that is mainly activated by UV irradiation. There have been vast research challenges in order to make the wide band gap energy of titania narrow that could be activated in the presence of visible light. Various modifications of titania surface were popular because titania needs to change its surface to respond in visible light. Among the methodological approaches, N-doping to titania can be the alternative candidate because it is facile process and eco-friendly. The activated electron from valence band in N-doped $TiO_2$ migrates to conduction band in the presence of visible light irradiation, which shows photocatalytic activity as well. In this study, focused on the evaluation of nitrogen state after N-doping through brief review. Arguments are still existed in nitrogen states and their different effects on photocatalytic activity. In particular, two nitrogen states are generally reported; substitutional and interstitial states. The research articles regarding N-doped $TiO_2$ are continuously appearing because the potential application of water split in visible light is still fascinate. The future of N-doped $TiO_2$ is also presented by referrals based on various literature.

Preparation of $N-TiO_2$ Photocatalysts and Activity Test ($N-TiO_2$ 광촉매의 제조와 광촉매 활성 검토)

  • Kang, Young-Gu;Shin, Ki-Seok;Ahn, Sung-Hwan;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.466-472
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    • 2012
  • Visible-light-responding photocatalysts, $N-TiO_2$, were prepared by nitrogen doping onto $TiO_2$. The crystalline structure and morphology, doping state of the prepared photocatalysts were characterized by XRD, FE-SEM, and XPS. The activity of the prepared photocatalysts was examined by the decomposition of methyleneblue. The prepared catalysts were anatase type and the crystallinity was increased with pH. The particle sizes of the prepared catalysts were 5.42, 5.99, 7.58 nm at pH 2.2, 4.7, 9.0, respectively. The particle sizes of the prepared catalysts were slightly increased with pH. The activity of the photocatalysts was directly proportional to the crystallinity of the catalysts. $N-TiO_2$ prepared by nitrogen doping onto $TiO_2$ showed activity under visible light. The doped nitrogen was located not in the lattice but on the surface.