• Title/Summary/Keyword: molar ratios

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Phamaceutical Studies on the Drug (III) -Enhancement of Dissolution and Stability of Sulfamethoxazole by ${\beta}-Cyclodextrin$ Complexation- (약물의 약제학적 연구(제 3보) -${\beta}-$시클로덱스트린과의 복합체 형성에 의한 설파메톡사졸의 용출 및 안정성 향상-)

  • Lee, Hyeon-Jong;Kim, Soo-Uck;Seo, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.18 no.4
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    • pp.181-186
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    • 1988
  • Inclusion complex of sulfamethoxazole with ${\beta}-cyclodextrin$ was prepared by freeze-drying method in molar ratios of 1:1, 1:1.25, 1:1.5 and 1:1.75, and the complex formation was identified by ultraviolet and infrared spectroscopies, powder X-ray diffractometry and differential scanning calorimetry. Dissolution rate and solid state stability of the complex were investigated in comparison with those of sulfamethoxazole powder and the physical mixture of sulfamethoxazole with ${\beta}-cyclodextrin$. As a result, the dissolution rate and the stability of solid complexes in various relative humidity conditions increased more remarkably than those of sulfamethoxazole powder and physical mixture. But the difference according to molar ratio of the complex was not recognized.

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Nitric Oxide Detection of Fe(DTC)3-hybrizided CdSe Quantum Dots Via Fluorescence Energy Transfer

  • Chang-Yeoul, Kim
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.453-458
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    • 2022
  • We successfully synthesize water-dispersible CTAB-capped CdSe@ZnS quantum dots with the crystal size of the CdSe quantum dots controlled from green to orange colors. The quenching effect of Fe(DTC)3 is very efficient to turn off the emission light of quantum dots at four molar ratios of the CdSe quantum dots, that is, the effective covering the surface of quantum dots with Fe(DTC)3. However, the reaction with Fe(DTC)3 for more than 24 h is required to completely realize the quenching effect. The highly quenched quantum dots efficiently detect nitric oxide at nano-molar concentration of 110nM of NO with 34% of recovery of emission light intensity. We suggest that Fe(DTC)3-hybridized CdSe@ZnS quantum dots are an excellent fluorescence resonance energy transfer probe for the detection of nitric oxide in biological systems.

Effects of Ca/Si Molar Ratio on the Interatomic Distance of Synthetic Calcium Silicate Hydrate (C-S-H) at Elevated Temperature (고온 가열시 Ca/Si 몰비율에 따른 합성 칼슘 실리케이트 수화물(C-S-H)의 구성 원자간 거리 변화)

  • Im, Su-Min;Bae, Sung Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.144-145
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    • 2021
  • Calcium silicate hydrate(C-S-H) is the principal binding phase that controls the strength and thermal stability of concrete. However, the effects of high temperature on the lattice structure and interatomic structure of C-S-H remains poorly understood due to its nanocrystallinity. This study aims to elucidate the change in interatomic distance of synthetic C-S-H with different Ca/Si molar ratios after exposure to high temperature via high energy X-ray scattering experiment which is a powerful analytical tool for amorphous materials.

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Early Hydration of Tricalcium Silicate(II) (Tricalcium Silicate의 초기수화반응(II))

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.2
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    • pp.133-138
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    • 1987
  • The behavior of CaO and SiO2 in the reaction produced which produced in the early hydration of C3S was studied by XRD and thermal analyzer. Polymerization of hydrated siltcates was also studied by TMS method. TMS derivatives were separated by gaschromatography. Cao/SiO2 molar ratios of the produced CSH gel under the air atmosphere were higher than that in the CO2. Dimerization rate of hydrated silicates was very fast in the early hydration stage. Trimer began to appear later than dimer and its increasing rate was very low. The amount of dimer and trimer formed under the CO2 atmosphere was less than that in the air.

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The decreased molar ratio of phytate:zinc improved zinc nutriture in South Koreans for the past 30 years (1969-1998)

  • Do, Mi-Sook;Lomeda, Ria-Ann R.;Cho, Young-Eun;Kwun, In-Sook
    • Nutrition Research and Practice
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    • v.1 no.4
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    • pp.356-362
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    • 2007
  • For the assessment of representative and longitudinal Zn nutriture in South Koreans, Zn, phytate and Ca intakes were determined using four consecutive years of food consumption data taken from Korean National Nutrition Survey Report (KNNSR) every 10 years during 1969-1998. The nutrient intake data are presented for large city and rural areas. Zn intake of South Koreans in both large city and rural areas was low during 1969-1988 having values between 4.5-5.6 mg/d, after then increased to 7.4 (91% Estimated Average Requirements for Koreans, EAR = 8.1 mg/d) and 6.7 mg/d (74% EAR) in 1998 in large city and rural areas, respectively. In 1968, Zn intake was unexpectedly higher in rural areas due to higher grain consumption, but since then until 1988 Zn intake was decreased and increased back in 1998. Food sources for Zn have shifted from plants to a variety of animal products. Phytate intake of South Koreans during 1969-1978 was high mainly due to the consumption of grains and soy products which are major phytate sources, but decreased in 1998. The molar ratios of phytate:Zn and millimmolar ratio of phytate${\times}$Ca:Zn were decreased due to the decreased phytate intake in South Koreans, which implies higher zinc bioavailability. The study results suggest that Zn nutriture has improved by increased dietary Zn intakes and the decreased molar ratio of phytate:Zn in South Koreans in both large city and rural areas.

A STUDY OF DENIAL ARCH FORM IN NORMAL OCCLUSION (정상교합의 치열궁형태에 관한 연구)

  • Cho, Joo-Hwan;Lee, Ki-Soo
    • The korean journal of orthodontics
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    • v.14 no.2
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    • pp.249-261
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    • 1984
  • This study was to investigate the fitness of the dental arch line to the parabola, and to estimate correlation between the parabola and some ratios of the dental arch measurements. The sample was consisted of the 64 plaster casts showing normal occlusion which was taken from males and females of Korea, aging from 15 to 18 years. The photos of occlusal surface of the plaster casts were taken, and 38 landmarks on the film were selected. The 3 dental arch lines on each dental arch were imaged. One is the dental arch line passing the points of the most buccal surfaces of the teeth, another is that passing the buccal cusp tips of the posterior teeth and the incisal edges, and the other is that passing the midpoints of the teeth. The landmarks on the film were digitized, and measurements and statistics were performed by the IBM computer. The results were as follows; 1. The fitness of the dental arch to the parabola was very good. The fitness of thor upper dental arch was above $91\%$, and that of the lower dental arch was $93\%$. 2. The dental arch line passing the points of the most buccal surfaces of teeth was best fit to the parabola, the buccal cusp tip arch line and the midpoint arch line in order. 3. Correlation between the ratio of oblique molar dental height to molar width and the parabola was very high. 4. The ratio of oblique molar dental height to molar width was devided into 4 groups by the quartiles, and mean parabolic equations and curves were calculated and drawn.

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Effect of PC(Polycarboxylate)-type Superplasticizer on the Hydration Reaction of Cement Paste (PC(Polycarboxylate)계 고유동화제가 시멘트 수화 반응에 미치는 영향)

  • Chae, Eun-Jin;Shin, Jin-Yong;Suh, Jeong-Kwon;Hong, Ji-Sook;Kim, Jae-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.533-536
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    • 2006
  • PC-type copolymers were synthesized using MPEG(Polyethylene glycol methyl ether methacrylate, Mn=2080) to different mole ratios of mono-carboxylic acid(AA : Acylic acid). The mole ratios of AA were 2, 3, 4. To investigate effects of PC-type co-polymers on the hydration of cement, experiments involving FT-IR, XRD, SEM have been analysed with cement paste specimens to 1, 3, 28 day. The hydration reaction rate of cement paste was slightly delayed at 1 day, due to increase in molar ratio of [AA] / [MPEG], it was recovered in the days after.

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Synthesis of SiC by Self-Propagating High Temperature Synthesis Chemical Furnace (SHS화학로에 의한 SiC의 합성)

  • Kim, Do-Kyung;Park, Sung;Cho, Kurn;Lee, Hyung-Bock
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1283-1292
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    • 1994
  • Ultra-fine $\beta$-SiC powders were fabricated by self-propagating high temperature synthesis process (SHS) using chemical furnace. The dependences of the C powders with different surface areas, the molar ratios of C/Si, the weight ratios of chemical fuel content, and pellet diameter-size on synthesis were investigated. Compositional and structural characterization of these powders was carried out by scanning electron micrograph and X-ray diffraction. The $\beta$-SiC powders which had C/Si mole ratio=1.05, 3 times chemical fuel contents, and pellet diameter=20 mm were optimum for synthesis efficiency. By optimizing process-variables, it is possible to fabricate $\beta$-SiC powders which have little secondary phases ($\alpha$-SiC).

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FT-IR analysis of flame resistant chemical mixture

  • Kim, Younsu;Seo, Jihyung;Choe, Yoong Kee;Sohn, Youngku;Kim, Jeongkwon
    • Analytical Science and Technology
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    • v.34 no.1
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    • pp.17-22
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    • 2021
  • In this study, flame retardant mixtures of decabromodiphenylethane (DBDPE) and Sb2O3 were analyzed using Fourier transform infrared (FT-IR) spectroscopy. The experimentally obtained wavenumbers of DBDPE and Sb2O3 were 1321 and 949 cm-1, respectively, whereas those obtained by theoretical calculation were 1370 and 818 cm-1, respectively. Strong correlation was observed between the mixing molar ratios and observed peak area ratios, suggesting that FT-IR analysis can be used to obtain relative amounts of the individual components of flame retardant mixture.

OCCLUSAL VARIATIONS IN THE POSTERIOR AND ANTERIOR SEGMENTS OF THE TEETH (구치부와 전치부의 교합 상태에 관한 연구)

  • Lee, Ki-Soo;Chung, Kyu-Rim;Ko, Jin-Hwan;Koo, Chung-Hoe
    • The korean journal of orthodontics
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    • v.10 no.1
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    • pp.71-79
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    • 1980
  • The purpose of this study was (1) to determine the prevalence of some causes by which dental occlusion might be affected , (2) to determine the prevalence of malocclusion, and types of molar, vertical incisor and horizontal incisor relationships, and (3) to examine the sex difference in the prevalence ratios, and (4) to determine the between-examiner differences in assessing types of dental occlusion. The material consisted of 1281 males and 811 females, total 2091 persons, aged 17 to 21 years. Two examiners who were graduate students in the orthodontic course, examined independently dental occlusion of the material. Before calculating the statistics, the subjects consisted of 156 mates and 164 females, total 320 persons, haying any one or more causes suspected to affect dental occlusion, was eliminated. Then the remained subjects, 1124 males and 647 females, total 1771 persons, were assessed. The results were as follows 1. The prevalence of some causes by which dental occlusion might be affected was 15.32 per cent. The missing rate of any one or more first molars was 8.85 percent, that of any one or more teeth positioned anterior to the first molar was 3.83 per cent. The prevalence of crossbite of the first molar was 0.48 per cent, that of retained primary teeth was 0.77 percent, and that of orthodontic treatment was 0.43 per cent. 8. The rate of between-examiner difference was 12.53 per cent in assessing the types of molar relationship, 18.86 percent in assessing the types of horizontal incisor relationship, and 26.37 percent in assessing the types of horizontal incisor relationship. 3. There was no sex difference in the prevalence ratios of the types of molar relationship. The prevalence of Class I molar relationship was 80.91 percent, that of Class II was 5,03, that of Class II subdivision was 4.01, Percent, that of Class III was 5.99 percent and that of Class III subdivision was 4.07 percent. 4. In the prevalence of the types of horizontal incisor relationship, there were no sex differences except that of Class II division 2. The prevalence of Class I horizontal incisor relationship was 73.12 percent, that of Class II division t was 12.03 percent, that of Class II division 2 was 6.58 percent in male and 4.33 percent in female, and that of Class III was 9.09 percent. 5. In the prevalence of the types of vertical incisor relationship, there were no sex differences except that of deep bite, The prevalence of open bite was 2.20 per cent, that of edge-to-edge bite was 9.15 percent, that of normal bite was 76,34 percent, and that of deep bite was 14.15 percent in male and 9.12 percent in female. 6. There was no sex difference in the prevalence of malocclusion the prevalence of malocclusion was 82.67 percent and that of normal occlusion was 17.33 percent. 7. There was a tendency that when Class I molar relationship changed to Class II, incisor relationships were to be larger overjet or upright upper incisors and deep bite, but when that changed to Class III molar relationship, these were to be cross bite and openbite.

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