• 자원환경지질
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• 제57권5호
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• pp.513-527
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• 2024

메탄은 이산화탄소에 이어 두 번째로 지구온난화에 미치는 영향이 큰 온실가스로, 기후변화에 상당한 영향을 미친다. 본 논문에서는 메탄 배출을 효율적으로 탐지하고 정량화하기 위해 사용되는 인공위성 원격탐사 기반 메탄 탐지 기술을 종합적으로 검토하고자 한다. 메탄 배출원은 크게 자연적 배출원(영구동토, 습지)과 인위적 배출원(농축산업, 석탄광, 석유 및 가스전, 폐기물 처리)으로 구분된다. 이 중 인위적 배출원에 대해 단파장적외선을 포함한 다양한 파장영역의 정보를 활용한 메탄 탐지의 원리와 이를 지원하는 주요 위성자료의 활용성에 대해 고찰하였다. 최근에는 위성자료를 활용한 메탄 탐지에서 딥러닝 기법을 적용한 연구들이 진행되고 있으며 이는 메탄 배출을 보다 정확하게 분석하는 데 기여하고 있다. 또한, 딥러닝 기법 적용 사례를 포함하여 전 지구, 지역 및 대형 사고 규모에서의 메탄 배출 탐지 사례를 종합적으로 검토하고 위성 기반 메탄 모니터링의 실용성을 평가하였다. 전 지구 규모에서는 Sentinel-5P TROPOspheric Monitoring Instrument (TROPOMI)와 같은 위성 센서를 사용한 연구들이 검토되었고 지역 규모에서는 주로 TROPOMI 자료와 상대적으로 고해상도의 위성자료(Sentinel-2 MultiSpectral Instrument (MSI), GHGSat Wide-Angle Fabry-Perot (WAF-P) Imaging Spectrometer 등)를 결합하여 메탄 배출 및 배출량을 탐지한 연구 사례를 소개하였다. 이러한 종합적 검토를 통해 위성 기반 메탄 탐지 기술의 현황과 활용성을 평가하였다.

• 센서학회지
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• 제20권1호
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• pp.53-57
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• 2011

We developed a small methane detection system because methane gas is used in many areas and is dangerous. The developed system consisted of LD(Laser Diode) tuned a wavelength of $1.65\;{\mu}m$, two mirrors to collect a laser beam, photo detector. It could detect methane gas at a long range and its sensitivity was 1.98 V/$CH_4%$.

• Journal of the Optical Society of Korea
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• 제12권1호
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• pp.1-6
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• 2008

We report the simple detection method of the small hydrocarbons, methane and ethane, by continuous-wave cavity ring-down spectroscopy near 1.67 ${\mu}m$ using an external cavity diode laser. The absorption lines of methane between 6002.48 $cm^{-1}$ and 6003.37 $cm^{-1}$ and ethane between 5955.65 $cm^{-1}$ and 5956.4 $cm^{-1}$ have been resolved and employed for the gas detection. The largest absorption cross sections were found to be 6.5$\times10^{-20}cm^2$ and 7.4$\times10^{-21}cm^2$ for methane and ethane, respectively, in each spectral range. The minimum detectable absorption limit of our spectrometer was 4.8${\times}10^{-9}cm^{-1}$/$\sqrt{Hz}$, which corresponds to the detection limits of 3 ppb/$\sqrt{Hz}$ and 27 ppb/$\sqrt{Hz}$ for methane and ethane, respectively. The near-IR continuous-wave cavity ring-down spectroscopic detection method of the small hydrocarbons can be applied for medical diagnosis and environmental monitoring as a fast and convenient method.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.163-166
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• 1998

The mechanism of methane sensing by Pd-SiC diode was investigated over the temperature range of 400~$600^{\circ}C$. The effects or methane gas reaction on the parameters such as barrier height, initial rate of methane gas reaction are investigated. The methane gas reaction kinetics on the device are also discussed. The physical and chemical mechanism responsible for methane detection are proposed. Analysis of steady-state reaction kinetics using I-V method confirmed that methane gas reaction processes are responsible for the barrier height change in the diode.

• E2M - 전기 전자와 첨단 소재
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• 제9권1호
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• pp.38-43
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• 1996

A coprecipitation method was used for preparing Ca and Pt doped $SnO_2$ fine powder. Components of the powder were investigated by XPS and SIMS. Crystallite size and specific surface area were investigated by TEM, XRD, and BET analysis. $SnO_2$(Ca)/Pt based thick film devices were prepared by a screen printing technique for methane gas detection. Then sensing characteristics of the devices were investigated. As Ca and Pt added, the crystal growth of $SnO_2$ was suppressed during calcining and sintering, and the sensitivity of $SnO_2$(Ca)/Pt thick film to methane gas was enhanced. For the Pt doped $SnO_2$ fine particle, the thick film device shows sensitivity of about 83% to 2000 ppm methane gas at an operating temperature of >$400^{\circ}C$.

• Journal of the Optical Society of Korea
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• 제17권6호
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• pp.481-485
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• 2013

A method for the measurement of the concentration of methane is experimentally demonstrated. The wavelength filter and gas cell are combined by using one Fabry-Perot etalon, which is filmed with the reflectivity of 96%. The optical broadband source is not only filtered to match the absorption wavelength of methane, but also absorbed by the methane in the same Fabry-Perot etalon. The concentration of the methane can be detected directly by measuring the transmission intensity. Compared with the conventional method, the proposed method possesses low costand high stability.

• 센서학회지
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• 제27권3호
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• pp.199-203
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• 2018

In this study, we develop a methane sensor module that can detect low concentrations below 5,000 ppm and measure up to the detection limit of 50 ppm with the NDIR method, with a long lifetime and high accuracy. Methane ($CH_4$) is one of a representative greenhouse gas, which is very explosive. Thus, it is important to quickly and accurately measure methane concentration in the air. To adjust the methane sensor for industrial field applications, a NDIR-based small sensor was implemented and characterized, where its volume was $4cm{\times}4cm{\times}2cm$ and its response time ($T_{90}$) was less than 30 sec. These results demonstrate that the proposed sensor is commercially available for low-concentration measurement, low volume, and fast response application, such as IoT sensor nodes and portable devices.

• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.285-290
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• 2003

An analytical method for the simultaneous determination of trace Ge, As and Se in biological samples by inductively coupled plasma/mass spectrometry has been investigated. The effects of added organic gas into the coolant argon gas on the analyte signal were studied to improve the detection limit, accuracy and precision. The addition of a small amount of methane (10 mL/min.) into the coolant gas channel improved the ionization of Ge, As and Se. The analytical sensitivity of the proposed Ar/CH₄system was superior by at least two-fold to that of the conventional Ar method. In the present method, the detection limits obtained for Ge, As and Se were 0.014, 0.012 and 0.064 ㎍/L, respectively. The analytical reliability of the proposed method was evaluated by analyzing the certified standard reference materials (SRM). Recoveries of 99.9% for Ge, 103% for As, 96.5% for Se were obtained for NIST SRM of freeze dried urine sample. The proposed method was also applied to the biological samples.

• 한국대기환경학회지
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• 제22권5호
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• pp.712-718
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• 2006

In order to investigate the analytical uncertainties associated with sampling and analysis of major greenhouse gaseous pollutants(carbon dioxide and methane), we attempted to quantify their adsorptive loss due to the contact with the container wall(such as Tedlar bag and vial). Using the GC/FID method, some basic experimental parameters(such as reproducibility and method detection limit) have been evaluated as part of the essential QA/QC The reproducibilities of carbon dioxide and methane were estimated as 2.02 and 0.2%, respectively. In addition, method detection limits were measured as 0.61 and 0.06 ng, respectively. A test of sample loss rate has also been made for Tedlar bag and vial by assessing the absolute amount of sample loss on the wall. By transferring the samples contained in Tedlar bag to various sizes of Tedlar bags, we measured differences in the absolute loss quantity due to such transfer. In addition, we also examined such loss mechanism as a function of elapsed time and light penetration rate for vial. As results, carbon dioxide and methane have shown about 2% of sample loss due to such contact. It is also noticed that the amount of loss with vial surface is lower than that of Tedlar bag. Therefore, field collection of greenhouse gases using various container types should be made more cautiously to minimize the possibility of sample loss and bias related to such loss.

• 농업과학연구
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• 제51권3호
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• pp.283-294
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• 2024

The objective of this study was to investigate the effect of supplementing concentrates in a forage-based diet on methane emissions of pregnant Hanwoo heifers. Twenty-one pregnant Hanwoo heifers (481 ± 42.4 kg) were divided into two groups: 1) a group receiving forage only (control, CON) and 2) the other group receiving forage with 4 kg of a concentrate mix (treatment, TRT). Methane (CH₄) concentration was measured using a laser methane detector, following an 18-d adaptation period, according to previously established protocols. Feed intake was recorded throughout the experimental period. Ruminal fluid was collected and analyzed for pH, ammonia-nitrogen (NH₃-N), and volatile fatty acid (VFA). The TRT exhibited higher dry matter and neutral detergent fiber intake than CON (p < 0.05) with elevated NH₃-N (p < 0.001) and total VFA concentrations (p = 0.013). The proportions of butyrate, valerate, and iso-valerate were higher in TRT than CON (p < 0.05). Notably, CH₄ concentrations per kg dry matter intake was lower in the TRT group, both from respiration and eructation (p < 0.05). In conclusion, supplementing concentrates in a low-quality forage-based diet for pregnant Hanwoo heifers fulfills nutrient requirements and reduces CH₄ emissions, suggesting a potential strategy to reduce environmental impact of Hanwoo production.