• Nuclear Engineering and Technology
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• v.54 no.2
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• pp.423-428
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• 2022

Very low contents (in the range of 10^-9 g/g) of Ir in mantle-derived rock samples (komatiites) were non-destructively determined by INAA coupled with coincidence gamma-ray spectrometry using 16 Ge detectors. Aliquots of the same samples were analyzed by NiS fire-assay ICP-MS for Ir and other platinum group elements. Because the INAA procedure used in this study is non-destructive and is almost free from spectral interference in gamma-ray spectrometry, the INAA values of Ir contents obtained in this study can be highly reliable. Iridium values obtained by ICP-MS were consistent with the INAA values, implying that the ICP-MS values of Ir obtained in this study are equally reliable. Under the present experimental conditions, detection limits were estimated to be 1 pg/g, which corresponds to 0.1 pg for a sample mass of 0.1 g. These levels can be even lowered by an order of magnitude, if necessary, which cannot be achieved by ICP-MS carried out in this study.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.109-114
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• 2004

A sensitive method for quantitation of glimepiride in human plasma has been established using liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI/MS/MS). Glipizide was used as an internal standard. Glimepiride and internal standard in plasma sample was extracted using diethyl etherethyl acetate (1 : 1). A centrifuged upper layer was then evaporated and reconstituted with the mobile phase of acetonitrile-5 mM ammonium acetate (60:40, pH 3.0). The reconstituted samples were injected into a $C_{18}$ reversed-phase column. Using MS/MS in the multiple reaction monitoring (MRM) mode, glimepiride and glipizide were detected without severe interference from human plasma matrix. Glimepiride produced a protonated precursor ion ([M+H]$^+$) at m/z 491 and a corresponding product ion at m/z 352. And the internal standard produced a protonated precursor ion ([M+H]]$^+$) at m/z 446 and a corresponding product ion at m/z 321. Detection of glimepiride in human plasma by the LC-ESI/MS/MS method was accurate and precise with a quantitation limit of 0.1 ng/mL. The validation, reproducibility, stability, and recovery of the method were evaluated. The method has been successfully applied to pharmacokinetic studies of glimepiride in human plasma.

• Safety and Health at Work
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• v.10 no.2
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• pp.196-204
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• 2019

Background: Liquid chromatography-tandem mass spectrometry (LC-MSMS) for simultaneous analysis of multiple microbial secondary metabolites (MSMs) is potentially subject to interference by matrix components. Methods: We examined potential matrix effects (MEs) in analyses of 31 MSMs using ultraperformance LC-MSMS. Twenty-one dust aliquots from three buildings (seven aliquots/building) were spiked with seven concentrations of each of the MSMs ($6.2pg/{\mu}l-900pg/{\mu}l$) and then extracted. Another set of 21 aliquots were first extracted and then, the extract was spiked with the same concentrations. We added deepoxy-deoxynivalenol (DOM) to all aliquots as a universal internal standard. Ten microliters of the extract was injected into the ultraperformance LC-MSMS. ME was calculated by subtracting the percentage of the response of analyte in spiked extract to that in neat standard from 100. Spiked extract results were used to create a matrix-matched calibration (MMC) curve for estimating MSM concentration in dust spiked before extraction. Results: Analysis of variance was used to examine effects of compound (MSM), building and concentration on response. MEs (range: 63.4%-99.97%) significantly differed by MSM (p < 0.01) and building (p < 0.05). Mean percent recoveries adjusted with DOM and the MMC method were 246.3% (SD = 226.0) and 86.3% (SD = 70.7), respectively. Conclusion: We found that dust MEs resulted in substantial underestimation in quantifying MSMs and that DOM was not an optimal universal internal standard for the adjustment but that the MMC method resulted in more accurate and precise recovery compared with DOM. More research on adjustment methods for dust MEs in the simultaneous analyses of multiple MSMs using LC-MSMS is warranted.

• Journal of Power Electronics
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• v.6 no.4
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• pp.298-306
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• 2006

A high efficiency and low cost sustain driver for a plasma display panel (PDP) utilizing a current pumping method is proposed. The main concept of the proposed circuit is using the current source to charge and discharge the panel. As a result, all power switches can achieve zero voltage switching (ZVS) and every auxiliary switch can also achieve zero current switching (ZCS). Since the inductor current can compensate for the discharge current, the current stress of all the power switches can be reduced considerably. Furthermore, it has features such as a simpler structure, less mass, lower cost, and lower electromagnetic interference than in previous circuits.

• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1177-1180
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• 2003

Thallium is quantitatively retained by 1,10-phenanthroline and tetraphenylborate onto benzophenone in the pH range 0-11 from a large volumes of aqueous solutions of various samples. After filtration, the solid mass consisting of thallium complex and benzophenone is dissolved with 5 mL of dimethylformamide and the metal was determined by flame atomic absorption spectrometric. About 0.4 ㎍ of thallium can be concentrated from 400 mL of aqueous sample, where its concentration is as low as 1.0 ng/mL. Eight replicate determinations of 8.0 ㎍/mL of thallium in final dimethylformamide solution gave a mean absorbance of 0.160 with a relative standard deviation of 1.7%. The sensitivity for 1% absorption was 0.22 ㎍/mL. The interference of a large number of anions and cations has been studied and the optimized conditions developed were utilized for the trace determination of thallium in various alloys and biological samples.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1995.10a
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• pp.470-473
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• 1995

There exist two critical in application of the magnetic bearing system. One is the control axis interference caused by gyroscopic effect and the other is the vibration caused by the unbalance on the rotor. To solve both problems at the same time, first, a centralized full-state feedback controller based on the LQR control theory was designed to compensate for the gyroscopic effect. Second, disturbance rejection control input based on the observer was designed to avoid the vibration causer by the unbalanced rotor. Balancing input computer accroding to LQR and output of the observer were derived in term of rotational speed. Effectiveness of the on-line balancing was verified through numerical simulation. The developed observer-based controller was also applied to the linear and nonlinear magnetic bearing systems.

• Economic and Environmental Geology
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• v.27 no.3
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• pp.313-321
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• 1994

Structural interpretation by using subsurface attitude of coal seam and outcrop patterns of folds and faults shows that wrench and thrust tectonics took place simultaneously in the study area. From the interference patterns of fold axes, three generations of folding are suggested: $F_1$ (NE-SW), $F_2$ (N-S), and $F_3$ (E-W). Differential displacement of rock mass from north to south yields to E-W fold and Osypcheon Fault. Geometry of subsurface coal seam show different patterns comparing to those of surface outcrop because of shallow-depth crustal shortening which took place post Cretaceous.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.32A no.6
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• pp.787-798
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• 1995

We implement the E-plane T-juncition manifold mutiplexer having low insertion loss for output multiplexer of Ku-band satellite transponder. Manifold multiplexer implemented here is composed of 2 channel filters, T-junctions, half-wave waveguide connecting channel filters and manifold, and manifold itself.[1-4] Considering the mass and volume of the satellite transponder, the channel filters are designed to dual-mode.[5-13] And Elliptic filter function is used, which has good characteristics of suppressing the interference between 2 channels. Since the performance of manifold multiplexer depends on the manifold waveguide transmission line length, it's necessary proper analysis. In this paper, we do optimization process of T-junction and other elements by using CAD and implement the manifold multiplexer. An experiment shows that characteristic response of multiplexer matches wel its modeling result.

• 한국전산유체공학회:학술대회논문집
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• 2008.03b
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• pp.464-467
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• 2008

An ejector is designed for the purpose of engine bay cooling. The primary flow of the ejector is the exhaust gas of the PW206C turboshaft engine. The mass flow of secondary flow is calculated by using the approximate analytic equation. And the effect of exhaust gas flow on the fuselage surface is investigated by using the Fluent Code. Three types of exhaust duct shape were compared in the viewpoint of surface temperature and aerodynamic drag. As a result, exhaust duct shape P3 shows minimum interference of exhaust gas and fuselage and minimum increment of drag among the three candidate shapes.

• Geomechanics and Engineering
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• v.5 no.4
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• pp.299-312
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• 2013

The horizontal pullout capacity of a group of two vertical strip plate anchors, placed along the same vertical plane, in a fully cohesive soil has been computed by using the lower bound finite element limit analysis. The effect of spacing between the plate anchors on the magnitude of total group failure load ($P_{uT}$) has been evaluated. An increase of soil cohesion with depth has also been incorporated in the analysis. For a weightless medium, the total pullout resistance of the group becomes maximum corresponding to a certain optimum spacing between the anchor plates which has been found to vary generally between 0.5B and B; where B is the width of the anchor plate. As compared to a single plate anchor, the increase in the pullout resistance for a group of two anchors becomes greater at a higher embedment ratio. The effect of soil unit weight has also been analyzed. It is noted that the interference effect on the pullout resistance increases further with an increase in the unit weight of soil mass.