• 제목/요약/키워드: major diffusion element

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공정조성 SnPb 솔더 라인의 온도에 따른 Electromigration 확산원소의 In-situ 분석 (In-situ Analysis of Temperatures Effect on Electromigration-induced Diffusion Element in Eutectic SnPb Solder Line)

  • 김오한;윤민승;주영창;박영배
    • 마이크로전자및패키징학회지
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    • 제13권1호통권38호
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    • pp.7-15
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    • 2006
  • 63Sn-37Pb 솔더의 실시간 electromigration 거동 관찰을 박막형 edge 이동 선형시편과 주사전자현미경을 이용하여 실시하였다. 공정조성 63Sn-37Pb 솔더의 electromigration에 의한 edge 이동 잠복기는 $90{\sim}110^{\circ}C$에서 뚜렷하게 존재하였다. 온도에 따른 electromigration 우선확산원소는 실험온도 $90{\sim}110^{\circ}C$에서 Pb, $25{\sim}50^{\circ}C$에서는 Sn으로 나타났고, $70^{\circ]C$에서는 Sn과 Pb가 거의 동시에 이동하여 우선확산 원소가 관찰되지 않았다. $90{\sim}110^{\circ}C$에서 관찰된 SnPb의 electromigration에 의한 edge 이동 잠복기는 Pb 우선이동에 의해 발생되었다. 이러한 edge 이동 잠복기의 존재는 플립칩 (flip chip) 솔더범프의 수명과 밀접한 관계를 가지는 것으로 보인다. Electromigration에 의해 발생되는 SnPb 솔더의 우선확산원소의 온도 의존성은 Pb와 Sn의 확산계수와 함께 $Z^*$ (전기장내의 유효전하 수)도 크게 영향을 미치는 것으로 생각된다.

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A MODEL STUDY ON MULTISTEP RECOVERY OF ACTINIDES BASED ON THE DIFFERENCE IN DIFFUSION COEFFICIENTS WITHIN LIQUID METAL

  • CHUN, YOUNG-MIN;SHIN, HEON-CHEOL
    • Nuclear Engineering and Technology
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    • 제47권5호
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    • pp.588-595
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    • 2015
  • This study presents an effective method for additional recovery of residual actinides in liquid electrodes after the electrowinning process of pyroprocessing. The major distinctive feature of this method is a reactor with multiple reaction cells separated by partition walls in order to improve the recovery yield, thereby using the interelement difference in diffusion coefficients within the liquid electrode and controlling the selectivity and purity of element recovery. Through an example of numerical simulation of the diffusion scenarios of individual elements, we verified that the proposed method could effectively separate the actinides (U and Pu) and rare-earth elements contained in liquid cadmium. We performed a five-step consecutive recovery process using a simplified conceptual reaction cell and recovered 58% of the initial amount of actinides (U + Pu) in high purity (${\geq}99%$).

전부도재교의치의 코어재료에 따른 파절강도 관찰 (Observation of Fracture Strengths According to the Core Materials for All Ceramic Bridge)

  • 정인성;김치영
    • 대한치과기공학회지
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    • 제32권4호
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    • pp.351-356
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    • 2010
  • Purpose: The purpose of this study was to evaluate the fracture strength between the core and veneering ceramic according to 2 core materials, In-Ceram Alumina and In-Ceram Zirconia, fabricated by electro ceramic layering technique. 2 different fixed partial denture cores of three units were veneered by veneering ceramic(Ceranion, Noritake) (n=10). Methods: The fracture strengths between the core and veneering ceramic were measured through the 3 point bending test. The interfaces between the core and veneering ceramic were observed with the X-ray dot mapping of EPMA. Results: The result of fracture strength was observed that IZP group, In-Ceram Zirconia core, had higher fracture strength. IPA group, In-Ceram Alumina core, had fracture strength of 359.9(${\pm}$86.2) N. IZP group, In-Ceram Zirconia core, had fracture strength of 823.2(${\pm}$243.0) N. X-ray dot mapping observation showed that a major element in the core and veneering ceramic of IPA group was alumina and silica, respectively. No binder was observed in interfaces between the core and veneering ceramic, and no ion diffusion or transition was observed between the core and veneering ceramic. However, apparent ion diffusion or transition was observed between the core and veneering ceramic of IZP group.

Correlation between rare earth elements in the chemical interactions of HT9 cladding

  • Lee, Eun Byul;Lee, Byoung Oon;Shim, Woo-Yong;Kim, Jun Hwan
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.915-922
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    • 2018
  • Metallic fuel has been considered for sodium-cooled fast reactors because it can maximize the uranium resources. It generates rare earth elements as fission products, where it is reported by aggravating the fuel-cladding chemical interaction at the operating temperature. Rare earth elements form a multicomponent alloy (Ce-Nd-Pr-La-Sm-etc.) during reactor operation, where it shows a higher reaction thickness than a single element. Experiments have been carried out by simplifying multicomponent alloys for mono or binary systems because complex alloys have difficulty in the analysis. In previous experiments, xCe-yNd was fabricated with two elements, Ce and Nd, which have a major effect on the fuel-cladding chemical interaction, and the thickness of the reaction layer reached maximum when the rare earth elements ratio was 1:1. The objective of this study is to evaluate the effect and relationship of rare earth elements on such synergistic behavior. Single and binary rare earth model alloys were prepared by selecting five rare earth elements (Ce, Nd, Pr, La, and Sm). In the single system, Nd and Pr behaviors were close to diffusion, and Ce showed a eutectic reaction. In the binary system, Ce and Sm further increased the reaction layer, and La showed a non-synergy effect.

CFD-DEM 연동을 통한 함정용 채프운의 시공간 분포 해석 (Numerical Simulation of Spatiotemporal Distribution of Chaff Clouds for Warship Defense using CFD-DEM Coupling)

  • 정욱진;김문홍;손동우
    • 한국전산구조공학회논문집
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    • 제36권2호
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    • pp.93-103
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    • 2023
  • 수많은 함정용 채프들은 폭발에 의해 확산되어 채프운을 형성하며, 채프운은 허위 레이더 반사 단면적을 생성하여 적의 레이더를 기만한다. 본 논문에서는 전산유체역학-이산요소법 단방향 연동 기법을 기반으로 공기 중에 분포하는 함정용 채프운의 시공간 분포를 해석하는 수치적 프레임워크를 구축하고 바람의 방향과 속도, 채프 카트리지의 초기 각도와 폭발 압력이 채프운 분포에 미치는 영향을 분석하였다. 채프운의 확산은 폭발에 의한 방사형 확산, 난류와 충돌에 의한 전 방향 확산, 낙하 속도 차이에 의한 중력 방향 확산과 같이 세 단계로 구분되는 것을 확인하였다. 바람은 채프운의 평균 위치를 이동시켰으며, 항력에 의한 확산 효과는 나타나지 않았다. 카트리지 초기 각도에 따라 폭발에 의한 방사형 확산 방향이 달라졌으며, 각도가 지면과 수직에 가까울수록 더 넓게 확산되었다. 폭발 압력이 증가할수록 채프운은 더 넓게 확산되었으나 중력 방향으로는 분포 차이가 작았다.

Monitoring the water absorption in GFRE pipes via an electrical capacitance sensors

  • Altabey, Wael A.;Noori, Mohammad
    • Advances in aircraft and spacecraft science
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    • 제5권4호
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    • pp.499-513
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    • 2018
  • One of the major problems in glass fiber reinforced epoxy (GFRE) composite pipes is the durability under water absorption. This condition is generally recognized to cause degradations in strength and mechanical properties. Therefore, there is a need for an intelligent system for detecting the absorption rate and computing the mass of water absorption (M%) as a function of absorption time (t). The present work represents a new non-destructive evaluation (NDE) technique for detecting the water absorption rate by evaluating the dielectric properties of glass fiber and epoxy resin composite pipes subjected to internal hydrostatic pressure at room temperature. The variation in the dielectric signatures is employed to design an electrical capacitance sensor (ECS) with high sensitivity to detect such defects. ECS consists of twelve electrodes mounted on the outer surface of the pipe. Radius-electrode ratio is defined as the ratio of inner and outer radius of pipe. A finite element (FE) simulation model is developed to measure the capacitance values and node potential distribution of ECS electrodes on the basis of water absorption rate in the pipe material as a function of absorption time. The arrangements for positioning12-electrode sensor parameters such as capacitance, capacitance change and change rate of capacitance are analyzed by ANSYS and MATLAB to plot the mass of water absorption curve against absorption time (t). An analytical model based on a Fickian diffusion model is conducted to predict the saturation level of water absorption ($M_S$) from the obtained mass of water absorption curve. The FE results are in excellent agreement with the analytical results and experimental results available in the literature, thus, validating the accuracy and reliability of the proposed expert system.

식품 유형간 이력추적시스템의 지속사용의도에 미치는 영향에 관한 연구 (The Study on User's Continuance Intention of Traceability System between Agricultural and Marine Products)

  • 이승육;박현숙
    • 유통과학연구
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    • 제14권4호
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    • pp.67-79
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    • 2016
  • Purpose - Over recent years, we have concerned about safety and quality on food products because of delivery complexity. The dependence of foreign food products escalate supply of products. And there are often negligent accident of marine and agricultural products. Therefore, the complexity increases the importance of safety on food and information quality for consumers. In spite of the interest augmentation of various interested parties, there is decrease in reliability and effectiveness, if it would be established without the right directivity. For the study, we tried to examine the first considerations the point of - view in service environment and information quality with accepting and diffusing the Traceability System. Then, we tried to verify the relationships between the factors of TS and the determinants of behavior decision. Next, we made efforts to find the mutual relationship among distributors, producers, consumers and the other prerequisite factors from the point of view in service environment and information quality in order to operate effectively the information perspective and system. Research design, data, and methodology - For the purpose of this study, the samples of consumers were targeted to Traceability System, and 661 people have been investigated. Through theoretical discussion of previous research, nine hypotheses were established, the influence of Continuous User Intention in TS. In order to test the hypotheses, a survey had conducted for 661 consumers as opinion leaders in their 20s-60s as data, and structural equation modeling was used. The difference analysis between Agricultural and Marine Products in TS; SPSS 22.0 and AMOS 22.0 were used for statistical analysis. Results - The major findings from this study were as follow; all factors of information quality excluding completeness and a social-impact had effects on the ease of use; all factors excluding understand ability in information quality and a social-impact had effects on the usefulness; completeness and social-impact had effects on perceived value; the ease of use had effects on usefulness and perceived value; usefulness had effects on perceived value and the intention of continuous use. From the results of different analysis, the CPLT(Completeness) factor has positive effects on Easy of USE and PV(Perceived Value) strongly in agricultural products. On the other hand, Social Duty has positive effects on Easy of Use strongly in marine products. Conclusion - In the age of information overflowing, TS will be a burden for users if it places too much emphasis upon accessibility. To accept and diffuse TS safely, therefore, Information System should be settled first into initial market formation. In addition, if TS elements are considered in conjunction with information factors and user environment, the acceptance and diffusion of TS would make synergy effect, even better. That is, this study contributes to the acceptance and diffusion of Traceability System. Accordingly, information quality will be settled into initial market formation. Also, social-impact element will be considered in conjunction with information quality's factors, and it will make synergy effect.

A RURAL HEALTH SERVICE MODEL FOR KOREA BASED OH A PRIMARY CARE NURSING SERVICE SYSTEM

  • Hong, Yeo-Shin
    • 대한간호학회지
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    • 제11권2호
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    • pp.5-8
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    • 1981
  • This study concerns itself with the development of a new model of comprehensive health service for rural communities of Korea. The study was conceived to resolve the problems of both underservice in rural communities and underutilization of valuable health manpower, namely the nurses, the disenchanted elite health personnel in Korea. On review of the current situation, the greatest deficiencies in the Korean health care system were found in the availability of primary care at the peripheries of md communities, in the dissemination of knowledge of disease prevention and health care, and in the induction of and guidance for active participation by the clientele in health maintenance at the personal, family and community level Abundant untapped health resources were identified that could be brough to bear upon the national effort to extend health services to every member of the Korean Population. Therefore, it was Postulated that the problem of underservice in rural communities of Korea can be structurcturally resolved by the effective mobilization and organization of untapped health resources, and that. a primary care Nursing Service System offers the best possibility for fulfillment of rural health service goals within the current health man-power situation. In order to identify appropriate strategies to combat the present difficulties in Korean rural health services and to utilize nurses and other health personnel in community-centered health programs, a search was made for examples of innovative service models throughout the world. An extensive literature survey and field visits to project sites both in Korea and in the United States were made. Experts in the field of world health, health service, planners, administrators, and medical and nursing practitioners in Korea, in the United States as well as visitors from other Asian countries were widely consulted. On the basis of information and inputs from these experts a new rural health service model has been constructed within the conceptual framework of community development, especially of the innovation diffusion Model. It is considered especially important that citizens in each community develop capacities for self-care with assistance and supports from available health professionals and participate in health service-related decisions that affect their own well-being. The proposed model is based upon the regionalization of health care planning utilizing a comprehensive Nursing Service System at the immediate delivery level The model features: (1) a health administration unit at each administrative level; (2) mechanisms for community participation; (3) a continuous source of primary health care at the local community level; (4) relative centralization of specialty care and provision of tertiary or super-specialty care only at major national metropolitan centers; and (5) a system for patient referral to the appropriate level of care. This model has been built around professional nurses as the key community health workers because their training is particularly suited and because large numbers of well-trained nurses are currently available and being trained. The special element in this model is a professional nurse-guided, self-care facilitating primary care Community Nursing Service System. This is supported by a Nursing Extension Service as a new training and support structure. (See attached diagrams). A broad spectrum of programs was proposed for the Community Nursing Service System. These were designed to establish a balance of activities between the clinic-centered individual care component and the field activity-centered educational and supportive component of health care services. Examples of possible program alternatives and proposed guidelines for health care in specific situations were presented, as well as the roles and functions of the key health personnel within the Community Nursing Service System. This Rural Health Service Model was proposed as a real alternative to the maldistributed, inequitable, uncoordinated solo-practice, physician-centered fee-for-service health care available to Koreans today.

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뉴잉글랜드 펠암돔 주변부 데본기 변성 이질암의 변성 온도-압력 경로 (Metamorphic P-T Paths from Devonian Pelitic Schists from the Pelham Dome, Massachusetts, USA)

  • 김형수
    • 암석학회지
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    • 제9권4호
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    • pp.211-237
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    • 2000
  • 북중부 Massachusetts 주에 위치하는 펠암돔의 북동부 연변부에서 산출되는 십자석대와 남정석대에서 채취한 시료내의 주구성 광물과 석류석 반상변정에 대해 주성분 분석과 화학적 누대구조를 분석하였다. 석류석 반상변정들은 결정 내의 내부 엽리 형태의 변화와 누대구조를 통해 이들은 다변형/변성 팍용을 거쳐서 성장했음을 지시한다. $X_{Mn}$ 의 역전 누대구조와 경사의 변화, Fe/(Fe+Mg) 비의증감 그리고 계단상의 $X_{Ca}$ 을 보이는 석류석의 비정상적인 누대구조들은 석류석 반상변정 내의 내부엽리 구조의 변화와 일치하는 경향성을 보인다. 이 내부 엽리의 형태와 광물의 산출상태, 그리고 사장석, 흑운모, 십자석 그리고 백운모의 화학성분은 석류석의 누대구조가 다음들의 조합에 의해 변화되었음을 지시한다. (i) 석류석의 소모 (석류석+녹니석+백운모 = 십자석+흑운모+석영+$H_2$O)와 생성 (십자석+백운모+석영=석류석+흑운모$+Al_2$$SiO_{5}$ $+H_2$O)와 포함하는 일변수와 이변수 반응들. (ii) 엽리 발동안 이온성 용해작용, 선택적인 확산작용과 원소의 재분포를 유포하는 변형작용. (iii) 석류석 성장 동안에 온도-압력의 변화. 암석학적 관찰과 석류석의 내부엽리 구조의 변화와 결합된 연구지역의 온도-압력 경로는 두가지로 구분된다: (1) NW-SE 압축운동 동안의 온도/압력 증가; (2) NNW-SSE 압축운동 동안의 온도/압력 감소. 기존의 펠암돔과 Bronson Hill 지역에서 모나자이트, 티타나이트, 각섬석, 흑운모, 백운모 그리고 K-장석들의 온도-시간적 (thermochronological) 자료와 후기 고생대 구조 모델에 근거해서, 아발론 암층과 표층암 경계를 따라 집중된 비균질 전단운동의 결과로 형성된 알레게니안 변성작용은 펠암돔 중부 Shutesbury 지역에서 펜실베니아기 동안(290-300Ma) 남정석-십자석-백운모 광물조합을 형성시켰다.

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