• 제목/요약/키워드: main chain

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선형 이관능성 DGEBF/선형아민(EDA, HMDA) 경화계의 경화제 사슬길이와 물성과의 관계에 대한 연구 (A Study of Relations of Chain Lengths and Properties for Bifunctional linear DGEBF/Linear Amino (EDA, HMDA) Cure Systems)

  • 명인호;이재락
    • Composites Research
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    • 제17권6호
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    • pp.37-43
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    • 2004
  • 경화제의 사슬길이와 화학구조 차이가 반응특성, 열적, 기계적특성에 미치는 영향을 조사하기 위하여 선형구조를 가지고 양쪽 막단기에 에폭시기를 갖는 범용 에폭시수지인 DCEBF를 양쪽 관능기가 동일하고 주쇄의 사슬길이가 서로 다른 선형아민 경화제인 EDA와 HMDA로 각자 1:1 당량비로 혼합하여 예비 및 후 경화조건으로 경화하였다. 그 결과, 수지 경화물의 특성은 경화제 주쇄의 탄소원자수에 따라 큰 영향을 받는 것으로 밝혀졌다. 즉, 주쇄의 길이가 짧은 EDA 경화계는 길이가 긴 HMDA 경화계보다 열안정성, 밀도, 부피수축(%), 유리전이온도, 인장탄성률 및 인장강도, 굴곡탄성률 및 굴곡강도의 값이 높게 나타났고, 반면에 최대발열온도, 에폭시기의 전환률, 선팽창계수의 값은 낮게 나타났다. 이는 주쇄의 탄소원자수 2개를 가지는 EDA가 3차원 망목상 공간구조 형성과정에서 packing capability가 우수하여 rigid한 특성을 가지기 때문이다. 굴곡 파단 특성은 굴곡탄성률과 굴곡강도와 밀접한 관계를 나타내었다.

Restoration of the Broken Lumbopelvic-hip Neuromuscular Chain and Coordinated Synergistic Activation in Low Back Pain

  • Park, Haeun;Park, Chanhee;You, Joshua (Sung) Hyun
    • 한국전문물리치료학회지
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    • 제29권3호
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    • pp.215-224
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    • 2022
  • Background: The presence of the lumbopelvic-hip neuromuscular chain is essential for dynamic spinal stabilization; its therapeutic effects on dynamic movements of the distal extremity segment and underpinning motor mechanism remain unknown and warrant further study on participants with low back pain (LBP). Objects: We aim to compare the effects of the broken chain exercise (BCE) and connected chain exercise (CCE) on electromyography (EMG) amplitude and onset time in participants with and without LBP. Methods: Randomized controlled clinical trial. A convenience sample of 40 nonathletic participants (mean age: 24.78 ± 1.70) with and without LBP participated in this study. All participants underwent CCE for 30 minutes, 30-minute daily. We measured EMG amplitude and onset times on bilateral erector spinae (ES), gluteus maximus (GM), hamstring (HAM), transverse abdominis (TrA), internal oblique (IO), and external oblique (EO) during the prone hip extension (PHE) test before and after the BCE and CCE. We used multivariate analysis of variance (MANOVA) to analyze the amplitude and onset time difference between exercises (BCE and CCE) and Pearson's correlations to determine any synergistic relationship among the HAM, GM, bilateral TrA/IO, and ES muscles. The statistical analyses were used at p < 0.05. Results: MANOVA showed that CCE was more decreased on EMG amplitude in HAM and bilateral ES, while increased GM and contralateral TrA/IO than BCE (p < 0.05). MANOVA EMG onset time data analyses revealed that the main effect of the conditions was significant for all HAM, GM, and bilateral ES muscles, whereas the main effect for the group was significant only for GM and contralateral ES in healthy and LBP groups. Pearson's correlation coefficient was computed to assess the relationship between BCE and CCE on dependent variables. In most of the muscles, there was a strong, positive correlation between the two variables, and there was a significant relationship (p < 0.001). Conclusion: CCE produced more effective and coordinated core stabilization and motor control mechanism in the lumbopelvic-hip muscles in participants with and without LBP during PHE than BCE.

수소이온 전달 특성에 미치는 바인더로 활용 가능한 나피온의 주쇄 길이의 영향 (Effect of Nafion Chain Length on Proton Transport as a Binder Material)

  • 강호성;박치훈
    • 멤브레인
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    • 제30권1호
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    • pp.57-65
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    • 2020
  • 본 연구에서는 고분자 전해질막을 구성하고 있는 고분자 주쇄의 반복단위 개수를 변경해 가며 수화채널 모폴로지와 이온전도도의 변화를 비교하였고, 최종적으로 분자동역학 전산모사 수행 시에 적정한 고분자 모델을 선정하기 위한 기준을 제시하고자 하였다. 고분자 주쇄의 길이가 가장 짧은 모델에서 주쇄 및 술폰산기의 움직임이 커지는 것을 관찰할 수 있었지만, 수화채널 모폴로지는 특별한 상관관계를 발견할 수 없었다. 또한, 수화채널 모폴로지에 가장 큰 영향을 받는 수소이온 전달 능력의 특성 상, 수소이온 전도도에서도 고분자 주쇄의 길이와 큰 상관관계를 보이지는 않았다. 이러한 결과는 특히 바인더용 이오노머 제조에 대한 중요한 정보를 제공한다. 일반적으로 바인더용 이오노머의 경우 고분자 전해질막 소재를 저분자량으로 합성하여 사용하게 되는데, 이때 주쇄/술폰산기의 움직임이 향상되므로 촉매층을 잘 둘러싸는 역할을 할 수 있는 반면에, 수소이온 전달 능력 자체에 있어서는 특별한 변화가 없을 것을 예상할 수 있다. 결론적으로, 바인더용 이오노머 제조시에는 수소이온 전달 성능보다는 물성에 좀 더 초점을 맞추어 분자량 및 구조 설계가 필요할 것이다.

A Fuzzy Multi-Objective Linear Programming Model: A Case Study of an LPG Distribution Network

  • Ozyoruk, Bahar;Donmez, Nilay
    • Industrial Engineering and Management Systems
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    • 제13권3호
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    • pp.319-329
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    • 2014
  • Supply chain management is a subject that has an increasing importance due to the developments in the global markets and technology. In this paper, a fuzzy multi-objective linear programming model is developed for the supply chain of a company dealing with procurement, storage, filling, and distribution of liquefied petroleum gas (LPG) in Turkey. The model intends to determine the quantities of LPG to be procured, stored, filled to cylinders, and transported between the plants and demand centers for six planning periods. In this model, which aims to minimize both total costs (sum of procurement, storage, filling, and transportation costs) and total transportation distances, demand quantities of the main demand centers and decision maker's aspiration levels about objective functions are fuzzy. After comparing the results obtained from the model with those obtained by using different methods, it is concluded that the proposed method can be applied to real world problems practically and it may be used in this type of problems in order to generate an efficient solution.

ON INTEGRAL DOMAINS IN WHICH EVERY ASCENDING CHAIN ON PRINCIPAL IDEALS IS S-STATIONARY

  • Hamed, Ahmed;Kim, Hwankoo
    • 대한수학회보
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    • 제57권5호
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    • pp.1215-1229
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    • 2020
  • Let D be an integral domain and S a multiplicative subset of D. An ascending chain (Ik)k∈ℕ of ideals of D is said to be S-stationary if there exist a positive integer n and an s ∈ S such that for each k ≥ n, sIk ⊆ In. As a generalization of domains satisfying ACCP (resp., ACC on ∗-ideals) we define D to satisfy S-ACCP (resp., S-ACC on ∗-ideals) if every ascending chain of principal ideals (resp., ∗-ideals) of D is S-stationary. One of main results of this paper is the Hilbert basis theorem for an integral domain satisfying S-ACCP. Also we investigate the class of such domains D and we generalize some known related results in the literature. Finally some illustrative examples regarding the introduced concepts are given.

마르코프 연쇄 몬테 카를로 샘플링과 부분집합 시뮬레이션을 사용한 컨테이너 크레인 계류 시스템의 신뢰성 해석 (Reliability Analysis of Stowage System of Container Crane using Subset Simulation with Markov Chain Monte Carlo Sampling)

  • 박원석;옥승용
    • 한국안전학회지
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    • 제32권3호
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    • pp.54-59
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    • 2017
  • This paper presents an efficient finite analysis model and a simulation-based reliability analysis method for stowage device system failure of a container crane with respect to lateral load. A quasi-static analysis model is introduced to simulate the nonlinear resistance characteristics and failure of tie-down and stowage pin, which are the main structural stowage devices of a crane. As a reliability analysis method, a subset simulation method is applied considering the uncertainties of later load and mechanical characteristic parameters of stowage devices. An efficient Markov chain Monte Carlo (MCMC) method is applied to sample random variables. Analysis result shows that the proposed model is able to estimate the probability of failure of crane system effectively which cannot be calculated practically by crude Monte Carlo simulation method.

상대좌표를 이용한 복합연쇄 로봇기구의 역기구학 (Inverse Kinematics of Complex Chain Robotic Mechanism Using Ralative Coordinates)

  • 김창부;김효식
    • 대한기계학회논문집A
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    • 제20권11호
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    • pp.3398-3407
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    • 1996
  • In this paper, we derive an algorithm and develope a computer program which analyze rapidly and precisely the inverse kinematics of robotic mechanism with spatial complex chain structure based on the relative coordinates. We represent the inverse kinematic problem as an optimization problem with the kinematic constraint equations. The inverse kinematic analysis algorithm, therefore, consists of two algorithms, the main, an optimization algorithm finding the motion of independent joints from that of an end-effector and the sub, a forward kinematic analysis algorithm computing the motion of dependent joints. We accomplish simulations for the investigation upon the accuracy and efficiency of the algorithm.

Using the MCDM of the Innovative Product Value Chain to Promote New Product Design

  • Liao, Shih-Chung
    • Asian Journal of Business Environment
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    • 제4권3호
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    • pp.27-37
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    • 2014
  • Purpose - In the past, designs for traditional products have usually focused on historic techniques. However, this tradition of using historic techniques has now been replaced by the trend of using the innovative design concept. Research design, data, and methodology - To measure future market trends and quality requirements, we apply the results of the questionnaires and analyze them with various experimental processes and a design methodology. In this way, we gauge the impact of the innovative product value chain on the promotion of new products. Results - Accompanied with an innovative product value chain, the product can stimulate the development of enterprise management, which has become the main issue in social and economic development in every developed country, and can facilitate the progress of enterprise management throughout the enterprise. Conclusions - Customer demand should be emphasized as the primary means to solve design problems, to design optimal solutions, to create differentiation with competitors, and to pursue optimal marketing strategies.

재고정책에 따른 군 공급체인 성과에 관한 연구 - 시스템 다이나믹스를 중심으로 - (A Study on the Effect of the Inventory Policy on Military Supply Chain Performance - Focused on System Dynamics -)

  • 안병기;김태현;문성임
    • 한국국방경영분석학회지
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    • 제28권2호
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    • pp.1-19
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    • 2002
  • This study shows the effect of inventory policy change from supplier-based to customer-based. We focus on the service level, cost, and information distortion of the Military Supply Chain(MSC) with System Dynamics. We design MSC model according to field practician interviews by using Vensim. The simulation makes a comparison between supply-based inventory policy performances and order-based inventory policy performances. In order to evaluate the MSC performances, we measure the accumulation of backlog(service level), supply chain cost, and order percentage overshoot(information distortion). The results show that 1) changing inventory policy from supplier-based to end customer order-based gets a good customer service, reduces MSC cost, and prevents information distortion, 2) changing inventory policy from supplier-based to immediate customer order-based reduces a small amount of MSC cost and deteriorates customer service, and 3) supply level is main factor for MSC performances improvement. This study implicates the policy change makes a improvement of MSC performance without introducing information system.

Dynamics of Poly[oxy-1,4-phenyleneoxy-2-{6-(4-(4-butylphenylazo)phenoxy)hexyloxy}terephthaloyl] and Poly[oxy-1,4-phenyleneoxy-2-{10-(4-(4-butylphenylazo)phenoxy)decyloxy}terephthaloyl] Studied by $^{13}C$ CP-MAS NMR

  • 조경규;한옥희;진정일
    • Bulletin of the Korean Chemical Society
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    • 제19권2호
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    • pp.178-183
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    • 1998
  • Carbon-13 CP-MAS NMR techniques were used to investigate dynamics of new combined type liquid crystalline polymers, poly[oxy-1,4-phenyleneoxy-2-{6-(4-(4-butylphenylazo)phenoxy)hexyloxy}terephthaloyl] and poly[oxy-1,4-phenyleneoxy-2-{10-(4-(4-butylphenylazo)phenoxy)decyloxy}terephthaloyl]. Noticeable mobility change of either aromatic groups or methylene groups is not detected between 25 ℃ and 82 ℃ from 13C spinlattice relaxation time in the rotating frame (T1ρ(C)) and contact time array experiments. However, line shape analysis shows the increase of mobility of methylene carbons in poly[oxy-1,4-phenyleneoxy-2-{6-(4-(4-butylphenylazo)phenoxy)hexyloxy}terephthaloyl] at higher temperature. The dynamics of side chanis does not seem to be affected in our experimental temperature range by the length of aliphatic chain which is connecting the side chain group to the main chain.