• Journal of the Mineralogical Society of Korea
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• v.22 no.4
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• pp.343-352
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• 2009

High-resolution Solid-state NMR provides element specific and quantitative information and also resolves, otherwise overlapping atomic configurations in multi-component non-crystalline silicates. Here we report the preliminary results on the effect of composition on the structure of CMAS (CaO-MgO-$Al_2O_3-SiO_2$) silicate glasses, as a model system for basaltic magmas, using the high-resolution 1D and 2D solid-state NMR. The $^{27}Al$ MAS NMR spectra for the CMAS silicate glasses show that four-coordinated Al is predominant, demonstrating that $Al^{3+}$ is network forming cation. The peak position moves toward lower frequency about 4.7 ppm with increasing $X_{MgO}$ due to an increase in $Q^4$(4Si) fraction with increasing Si content, indicating that Al are surrounded only by bridging oxygen. $^{17}O$ MAS NMR spectra for $CaAl_2SiO_6$ and $CaMgSi_2O_6$ glasses qualitatively suggest that NBO fraction in the former is smaller than that in $CaMgSi_2O_6$ glasses. As $^{17}O$ 3QMAS NMR spectrum of model quaternary aluminosilicate glass resolved distinct bridging and non-bridging oxygen environments, atomic structure for natural magmas can also be potentially probed using high-resolution 3QMAS NMR.

• Economic and Environmental Geology
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• v.22 no.1
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• pp.21-34
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• 1989

Chindong granites are classified into granodiorite, tonalite and quartz-diorite, and Yucheon - Eonyang granites into monzo-granite by the Streckeisen diagram. These granitic rocks of Cretaceous age show trend of calc-alkaline magma, and the magmatic evolution from basic to acidic rocks is consistant with the general crystallization path of the Cretaceous granitic rocks in the Gyeongsang basin. On the basis of petrological and petrochemical data, variation of major elements (K, Na, Ca, Mg) and trace elements (Rb, Sr, Ba) including ore metals (Cu, Pb, Zn) in the Cretaceous granitic rocks were studied in detail in order to investigate geochemical difference of the granitic rocks in relation to mineralization between Cu province and Pb-Zn province in the Gyeongsang basin. There is clear difference in content of the major elements between Chindong granites and Yucheon-Eonyang granites : Chindong granites have low content of K (1.62%) and Na (2.53%), and high content of Ca (3.75%) and Mg (1.42%) whereas Yucheon-Eonyang granites have high content of K (3.56-3.60%), and low content of Ca (0.96-0.26%) and Mg (0.26-0.21%). There is also clear difference in content of trace lithophile elements between Chindong granites and Yucheon-Eonyang, granites : Chindong granites have low content of Rb (86ppm) and Ba (330ppm), and high content of Sr (405ppm) while Yucheon-Eonyang, granites have high content of Rb (144-161ppm) and Ba (983-1030ppm), and low content of Sr (157-136ppm). The lithophile trace elements of Rb and Sr vary with close relationship to major elements of K and Ca, respectively. Therefore, Chindong granites are much easily distinguished from Yucheon-Eonyang granites by using relationship of K with Rb and Ca with Sr : K<3%, Rb<100ppm, Ca<2% and Sr>200ppm for Chindong granites, and K>3%, Rb>100ppm, Ca<2%, and Sr<200ppm for Yucheon-Eonyang granites. There is not clear difference in content of trace ore metals between Chindong granites and Yucheon-Eonyang granites : Chindong granites of the Cu province have low Cu content (15ppm) which is nearly equal to 13-14ppm of Yucheon-Eonyang granites of the Pb-Zn province, and Yucheon-Eonyang granites have Pb content (29-27ppm) which is rather lower than 37ppm of Chindong granites. But Cu is anomalously high in the mineralized part of Chindong granites in Gunbuk-Haman area, and Zn is apparently higher in Yucheon-Eonyang granites (51-37ppm) than in Chindong granites (29ppm). K/Pb ratio is also c1early distinguishable between Chindong granites (<850) and Yucheon-Eonyang granites (>850). Thus, it may be possible to apply geochemical difference of the granites to distinguish whether a Cretaceous granitic body is Cu related rock or Pb-Zn related rock, and whether it belongs to Cu province or Pb-Zn province in the Gyeongsang basin.

• Economic and Environmental Geology
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• v.25 no.2
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• pp.133-143
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• 1992

Ulsan granite is plotted mainly in the region of syeno-granite of the Streckeisen diagram, which consists with those of iron related granites in the area of Kimhae-Mulgum, while Chindong granites and Yucheon-Eonyang granites are plotted in the regions of granodiorite-diorite and monzo-granite, respectively. These granites show a differentiation trend of calc-alkaline magma, and their magmatic evolution from intermediate to acidic rocks is consistant with the general crystallization path of the Cretaceous granitic rocks in the Gyeongsang basin. The difference index (D.I.) is 70~90 for Ulsan granite, which lies between 35~80 of Chindong granites and 85~95 of Yucheon-Eonyang granites. These granites are distinguishable from each other by variation patterns of chemical elements. For instance, there is clear difference in content of some major and trace elements between Ulsan granite and Cu-related Chindong granites: Ulsan granite has high content of K (2.68%) and Ba (636 ppm), and low content of Ca (1.07%), Mg (0.50%) and Sr (185 ppm), whereas Chindong granites has less content of K (1.62%) and Ba (382 ppm), and higher content of Ca (3.75%), Mg (1.42%) and Sr (405 ppm). However, the content of Ulsan granite overlaps partly those of Yucheon-Eonyang granites, which are apparently dividable from Chindong granites. There is an usual trend that Cu content is high in Chindong granites of Cu province and Zn content is higher in Yucheon-Eonyang granites of Pb-Zn province. But it is unusual that Cu and Zn are higher in Ulsan granite (34 ppm, 74 ppm) than in Chindong granites (15 ppm, 22 ppm) and Yucheon-Eonyang granites (14 ppm, 43 ppm). This may be due to the reason that Ulsan granite is productive and Cu-Zn minerals are associated with iron ores. Productive Chindong granites in Haman-Gunbug area and Yuchon-Eonyang granites near ore deposits have higher content of Cu and Zn than Ulsang granite. Therefore, it is expected that chemical variation patterns of granites are applicable to distinguish mineral commodity of ore deposits (iron, copper, or lead-zinc) related with the granites in the Gyeongsasng basin.

• Economic and Environmental Geology
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• v.50 no.3
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• pp.181-193
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• 2017

Mn-Fe phosphate mineral complexes included within the pegmatite are observed at Jurassic Cheolwon two-mica granite in Gyeonggi Massif, South Korea. The genetic evolution between the Cheolwon two-mica granite and pegmatite, and various trend of Mn-Fe phosphate minerals is made by later magmatic, hydrothermal, and weathering process based on mineralogical, geochemical analysis. The Cheolwon two-mica granite is identified as S-type granite, considering its chemical composition (metaluminous ~ peraluminous), post-collisional environment, low magnetic susceptibility, and existence of biotite and muscovite. The K-Ar age (ca. 153 Ma) of pegmatite is well coincident with age of the Cheolwon two-mica granite ($151{\pm}4Ma$). It indicates that these two rocks are originated from the same magma. Pegmatite indicates the LCT geochemical signature, and was classified as muscovite-rare element class / Li subclass / beryl type / beryl-columbite-phosphate subtype pegmatite. The triplite $\{(Fe^{2+}{_{0.4}},Mn_{1.6})(PO_4)(F_{0.9})\}$ is dominant phosphates in later magmatic stage which partly altered to leucophosphite $\{KFe^{3+}{_2}(PO_4)_2OH{\cdot}2H_2O\}$ and jahnsite $\{(Fe^{3+}{_{0.7}},Mn_{2.3})(PO_4)_2OH{\cdot}4H_2O\}$ by hydrothermal alteration. In particular, near fractures, the triplite has been separatelty replaced by the phosphosiderite ($Fe^{3+}PO_4{\cdot}2H_2O$) and Mn-oxide minerals during weathering stage.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.323-336
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• 2019

The Mesozoic activity on the Korean Peninsula is mainly represented by the Triassic post-collisional, Jurassic orogenic, and Cretaceous post-orogenic igneous activities. The diversity of mineralization by each geological period came from various geothermal systems derived from the geochemical characteristics of magma with different emplacement depth. The Cretaceous metallic mineralization has been carried out over a wide range of time periods from ca. 115 to 45 Ma (main stage; ca. 100 to 60 Ma) related to post-orogenic igneous activity, and spatial distribution patterns of most metal deposits are concentrated along small granitic stocks. The late Cretaceous metal deposits in the Gyeonggi and Yeongnam massifs are generally distributed along the boundary among the Gongju-Eumseong fault system and the Yeongdong-Gwangju fault system and the Gyeongsang Basin, most of them are in the form of a distal epithermal~mesothermal Au-Ag vein or a transitional mesothermal Zn-Pb-Cu vein. On the other hand, diverse metal commodities in the Taebaeg Basin, the Okcheon metamorphic belt and the Gyeongsang Basin are produced from various deposit types such as skarn, carbonate-replacement, vein, porphyry, breccia pipe, and Carlin type. In the late Cretaceous metallic mineralization, various mineral deposits and commodities were induced not only by the pathway of the hydrothermal solution, but also by the diversity of precipitation environment in the proximity difference of the granitic rocks. The diversity of these types of Cretaceous deposits is fundamentally dependent on the geochemical characteristics such as degree of differentiation and oxidation state of related igneous rocks, and ore-forming fluids generally exhibit the evolutionary characteristics of intermediate- to low-sulfur hydrothermal fluids.

• The Journal of the Petrological Society of Korea
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• v.23 no.3
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• pp.273-277
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• 2014

This paper presents a brief historical review of various attempts to estimate the age of the Earth, and reappraises the study of Patterson (1956) which revealed for the first time that the age of the Earth is $4550{\pm}70Ma$ by measuring Pb isotope ratios of several meteorites and a marine sediment. The standard model for the planetary formation of early solar system is: formation of solid particles condensed from the cooling of hot nebular gas -> formation of planet-sized bodies by accretion of those solid particles. The Moon is supposed to have formed from the accretion of the relicts produced by the collision of proto-Earth with Mars-sized body. It is not easy to pinpoint the age of the Earth, considering the series of events related to the formation of the Earth. So, I propose that the collision age as that of the Earth, since the present status of the Earth is thought to be the direct product of the collision. According to the previous studies, the collision age can be broadly constrained between the age ($4567.30{\pm}0.16Ma$) of the earliest condensates (CAI, calcium-aluminum rich inclusion) of the nebula gas, i.e., the age of the solar system, and the oldest age ($4,456{\pm}40Ma$) among rocks and minerals of the Earth and the Moon. We need more precise estimation of the collision age, since it is important in estimating time scale for the formation of planet-size body and in revealing thermal evolution of magma oceans of the Earth and the Moon presumably developed right after the collision.

• The Journal of the Petrological Society of Korea
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• v.23 no.3
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• pp.279-292
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• 2014

Nd isotopic compositions analyzed from the Phanerozoic granitoids of Korea are integrated and discussed. Variations in Nd isotopic compositions can be explained either by temporal trend or by regional differences. Among the three active periods, first two periods during the Permian-Triassic and Jurassic seem to show variations from rather high ${\varepsilon}_{Nd}(t)$ values at the beginning to lower ${\varepsilon}_{Nd}(t)$ values during the later stages. Such trends probably reflect melting of the subducting oceanic crust and producing magma with higher proportion of depleted mantle derived materials during the early stage of subduction process, and subsequent magmas with greater proportion of old continental crust with progress of subduction. However, the Cretaceous-Paleogene period of active magmatism displays higher ${\varepsilon}_{Nd}(t)$ values during the advanced stage of the igneous activities, which is opposite to the previous active periods. The other explanation is that such differences in ${\varepsilon}_{Nd}(t)$ reflect regional differences, based on the observations that such high-${\varepsilon}_{Nd}(t)$ granitoids distribute in the northeastern Gyeongbuk Province and Gyeongsang Basin. If this is the case, the regions with highr ${\varepsilon}_{Nd}(t)$ values may have distinct crustal evolution histories, e.g. younger average age. The choice between the two hypothesis could be made through further studies.

• The Journal of the Petrological Society of Korea
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• v.28 no.1
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• pp.15-24
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• 2019

There are beautiful scenery with columnar jointing at 15 valley of southern slope of the Wangtian'e volcano in Mt. Baekdu volcanic field. The compositions of phenocryst minerals which have porphyritic textures in mafic volcanic rocks of this area were carried out. The Wangtian'e volcano consists of Changbai basalt~trachybasalt (lower part) and Wangtian'e basaltic trachyandesite~trachyte~alkali rhyolite (upper part). This study is focused on the mafic rocks of the Changbai trachybsalt and the Wangtian'e basaltic trachyandesite. Main phenocrysts are feldspar, pyroxene and olivine. The major element compositions of the phenocrysts were analyzed using EPMA. Plagioclase phenocrysts of the Wangtian'e basaltic trachyandesite are located at the border of andesine and oligoclase ($An_{24.1{\sim}36.0}$) in the An-Ab-Or diagram, and those of the Changbai trachybasalt are labradorite ($An_{54.2{\sim}65.2}$). Pyroxene phenocrysts are augite. Olivine phenocrysts of the Changbai trachybsalt are crysolite ($Mg_{0.79-0.77}Fe_{0.21-0.23}$) and microphenocrysts in the groundmass are hyalosiderite ($Mg_{0.58-0.56}Fe_{0.42-0.44}$). Calculated crystallization temperature of olivine phenocrysts is $1196{\sim}1123^{\circ}C$, clinopyroxene is $1122{\sim}1112^{\circ}C$, phenocrysts and laths of plagioclases are $1118{\sim}1107^{\circ}C$ and $1091{\sim}1089^{\circ}C$, respectively. The temperatures suggests that the olivine phenocrysts, clinopyroxene, plagioclase phenocrysts, and plagioclase laths were crystallized in the magma chamber in sequence.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.151-160
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• 2021

2:1 clay minerals such as smectite incorporating ammonium were extracted to investigate the ammonium behavior and nitrogen isotope characteristics for two different sediment cores which were collected from shimmering sites on seafloor of the Wakamiko crater, southwestern Japan. Inorganic nitrogen contents in clay fraction were estimated by calibration curve based on consistently decreasing carbon and nitrogen ratio during the treatment to decompose organic materials, after removing inorganic carbon. The results show that the proportions of inorganic nitrogen for total nitrogen in clay fraction of SWS site(Core#1094MR: av. 18.2%) are higher than those in SES site(Core#1093MG: av. 11.5%). Relatively good crystallinity of the former suggests that exchangeable ammonium was transformed to non-exchangeable ammonium during more evolving diagenetic process. Nitrogen isotope variance of clay fraction(SES site: Core#1093MG: -4.4 ~ +0.2 ‰, av. -2.4 ‰; SWS site: Core#1094MR: -0.7 ~ +3.0 ‰, av. +1.5 ‰) during sequential decomposition of exchangeable ammonium suggests that heat flow derived from deep magma led to nitrogen isotope fractionation between dissolved ammonium and ammonia in the fluids involved in the formation of 2:1 clay mineral incorporating ammonium with local temperature variation.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.4
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• pp.325-337
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• 2020

The Jurassic granitic rocks in the area of Gwangdeoksan located along the boundary between Hwacheon and Cherwon in northern Gyeonggi Massif consist of two-mica granite, garnet-bearing two-mica granite, mica-granite, and porphyritic biotite granite. These granitic rocks are calc-alkaline series and plotted in peraluminious domain in A/CNK vs. A/NK diagram. Petrographical and geochemical data indicate that the porphyritic biotite granite which intruded at the last period originated from distinct parental magma from two-mica granite, garnet-bearing two-mica granite, and mica-granite. On the basis of Rb/Sr vs. Rb/Ba diagram and Al2O3/TiO2 vs. CaO/Na2O, it is inferred the porphyritic biotite granite originated from protolith with less pelitic composition than 3 other granitic rocks. The enriched values of lithophile elements of Cs, Rb, and Ba and negative trough of Nb, P, Ti on spider diagram suggest that the peraluminous Jurassic granitic rocks in Gwangdeoksan area formed in subduction tectonic environment. Whole-rock zircon saturation thermometer indicates that the granitic rocks in the study area were melted at 692-795℃.