• Title/Summary/Keyword: low temperature reduction

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Treatment of palm oil mill effluent using 2 stage reactors combined anaerobic hybrid reactor and anaerobic attached growth reactor (혼합공정과 부착성장공정을 조합한 2단계 혐기 조합공정에서 palm oil mill effluent의 처리)

  • Shin, Chang-Ha;Son, Sung-Min;Jeong, Joo-Young;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.21-29
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    • 2013
  • Present study was conducted to evaluate the performance of Anaerobic Hybrid Reactor (AHR) combined with two types of anaerobic attached growth reactors at mesophilic temperature ($37^{\circ}C$). The reactor was operated at the influent substrate condition of 19,400 mg/L soluble chemical oxygen demand (sCOD). The organic loading rate (OLR) and flow rate were varied in the range of $9.5{\sim}22.5kg/m^3$. day and 10.6 ~ 26.0 L/day respectively since start-up was done. The COD removal efficiency of 93 % was measured at the OLR of $14kg/m^3$. day in AHR. However a reduction in removal efficiency to as low as 85 % could have been related to a combined effect of high concentration suspended solids (SS) concentration over 3,800 mg/L. On the other hand the total COD removal efficiencies were measured to be 96.3 % and 96.2 % for AHR+APF and AHR+ADF respectively. The pH of the POME was adjusted to neutral range by using sodium bicarbonate at the initial stages of the reactor feed, later stages pH adjustment was not required as the pH was maintained in the desired neutral range due to self-buffering capacity of the reactor. The reactor proved to be economically acceptable and operationally stable. The biogas was measured to have $CH_4$ and $CO_2$ with a ratio of 35:65, and methane gas production rate was estimated to be $0.17{\sim}10.269L\;CH_4/g\;COD_{removed}$.

Electronic Structure of Ce-doped ZrO2 Film: Study of DFT Calculation and Photoelectron Spectroscopy

  • Jeong, Kwang Sik;Song, Jinho;Lim, Donghyuck;Kim, Hyungsub;Cho, Mann-Ho
    • Applied Science and Convergence Technology
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    • v.25 no.1
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    • pp.19-24
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    • 2016
  • In this study, we evaluated the change of electronic structure during redox process in cerium-doped $ZrO_2$ grown by sol gel method. By sol-gel method, we could obtain cerium-doped $ZrO_2$ in high oxygen partial pressure and low temperature. After post annealing process in nitrogen ambient, the film is deoxidized. We used spectroscopic and theoretical methods to analysis change of electronic structure. X-ray absorption spectroscopy (XAS) for O K1-edge and Density Functional Theory (DFT) calculation using VASP code were performed to verify the electronic structure of the film. Also, high resolution x-ray photoelectron spectroscopy (HRXPS) for Ce 3d was carried out to confirm chemical bond of cerium doped $ZrO_2$. Through the investigation of the electronic structure, we verified as followings. (1) During reduction process, binding energy of oxygen is increase. Simultaneously, oxidation state of cerium was change to 4+ to 3+. (2) Cerium 4+ and cerium 3+ states were generated at different energy level. (3) Absorption states in O K edge were mainly originated by Ce 4+ $f_0$ and Ce 3+, while occupied states in valance band were mainly originated from Ce 4+ $f_2$.

A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.199-207
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    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

Mapping of Quantitative Trait Loci Associated with Viviparous Germination in Rice

  • Lee, Seung-Yeob;Ahn, Jeong-Ho;Cha, Young-Soon;Yun, Doh-Won;Lee, Myung-Cheol;Eun, Moo-Young
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.6
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    • pp.565-570
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    • 2006
  • The viviparous germination (VG) with lodging caused the yield reduction and quality deterioration in rice. We carried out the evaluation of VG tolerance (on the 40th day after heading) and mapping QTLs associated with VG tolerance using the recombinant inbred lines (M/G RILs) from a cross between Milyang 23 (japonica/indica) and Gihobyeo (japonica). The VG rates of Milyang 23 and Gihobyeo were 0.0 and 7.0%, respectively. The averaged VG rate of 162 M/G RILs was 7.7%, and their range was from 0.0 to 50.9%. Of the 162 RILs, 144 lines were tolerant less than 10%, and 18 lines were susceptible more than 10%. Using the M/G RIL Map, three QTLs associated with the viviparous trait were detected on chromosome 2 (qVG 2-1 and qVG 2-2) and 8 (qVG 8). qVG 2-1 was linked to RM 32D and RZ 166, and had LOD score of 2.97. qVG 2-2 was tightly linked to E13M59.119-Pl and E13M59.M003-P2, and showed higher LOD score of 3.41. qVG 8 was linked to RM33 and TCT116, and had LOD score of 2.67. The total phenotypic variance explained by the three QTLs was about 24.4% of the total variance in the population. The detection of new QTLs associated with VG tolerance will provide important informations for the seed dormancy, low temperature germination, or comparative genetics.

A Study on the High Functional Finishing of Polyester Flat Fabrics Treated with Chitosan (키토산 처리한 폴리에스테르 편평사 직물의 고기능화 가공에 관한 연구)

  • 이석영;박성우;김삼수
    • Textile Coloration and Finishing
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    • v.16 no.3
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    • pp.22-30
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    • 2004
  • The polyester fabrics were treated with the chitosan with various solubility in optimized treatment condition. The treatment method was discussed to be a high functional finishing for the polyester fabric to obtain the high moisture absorption and anti-microorganism property by evaluating the effect of the chitosan purification method on the yield and anti-microorganism property of the chitosan. On the other hand, soluble polyurethane was added to the chitosan treatment solution and/or plasma pretreatment was done. The addition of soluble polyurethane give a high add-on ratio as well as a linen like effect of treated polyester fabric. The results were as follows: 1. In the treatment of polyester fabric by the chitosan solution, a soluble PU resin and low temperature plasma treatment were done to obtain high binding force between the fabrics and the chitosan. The add-on rate and the moisture absorption ratio of the fabrics treated with the chitosan-PU after treated with the plasma slightly increased more than those of the fabrics treated with the chitosan only. 2. Anti-static property of the fabrics treated with the chitosan decreased rapidly with increasing of the chitosan concentration. The washing fastness of the fabrics treated with the chitosan-PU after treated with the plasma was better than those of the fabrics treated with chitosan only. The wrinkle resistance of the treated fabrics decreased constantly with the concentration of the chitosan. The bending rigidity of the treated fabrics increased greatly. On the treatment of polyester fabric under optimum condition, the microorganism reduction rate kept above 90% after 10times launderings. 3. As the polyester fabrics which has flat yam was used as a weft yams were treated with the chitosan-PU as give a functional finishing effects such as durability, moisture absorption, anti-static and anti- microorganism property. Treated polyester fabric showed a good functional finishing effect and a linen like property.

Impacts of green technologies in distribution power network

  • Suwanapingkarl, Pasist;Singhasathein, Arnon;Phanthuna, Nattaphong;Boonthienthong, Manat;Srivallop, Kwanchanok;Ketken, Wannipa
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.90-100
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    • 2015
  • Green technologies such as renewable energy resources, Electric Vehicles and Plug-in Hybrid Electric Vehicles (EVs/PHEVs), electric locomotives, etc. are continually increasing at the existing power network especially distribution levels, which are Medium Voltage (MV) and Low Voltage (LV). It can be noted that the increasing level of green technologies is driven by the reduction emission policies of carbon dioxide ($CO_2$). The green technologies can affect the quality of power, and hence its impacts of are analysed. In practical, the environment such as wind, solar irradiation, temperature etc. are uncontrollable, and therefore the output power of renewable energy in that area can be varied. Moreover, the technology of the EVs/PHEVs is still developed in order to improve the performance of supply and driving systems. This means that these developed can cause harmonic distortion as the control system is mostly used power electronics. Therefore, this paper aims to analyse the voltage variation and harmonic distortion in distribution power network in urban area in Europe due to the combination between wind turbine, hydro turbine, photovoltaic (PV) system and EVs/PHEVs. More realistic penetration levels of SSDGs and EVs/PHEVs as forecasted for 2020 is used to analyse. The dynamic load demands are also taken into account. In order to ensure the accurate of simulation results, the practical parameters of distribution system are used and the international standards such as Institute of Electrical and Electronics Engineers (IEEE) standards are also complied. The suggestion solutions are also presented. The MATLAB/Simulink software is chosen as it can support complicate modelling and analysis.

Characteristics of Microwelded BLU CCFL Electrode in Terms of Glass Beading Heat Treatment Temperature (미세 용접된 BLU CCFL 전극의 유리비딩 열처리 온도에 따른 접합부 특성)

  • Kim, Gwang-Soo;Kim, Sang-Duck;Kwon, Hyuk-Dong
    • Journal of Welding and Joining
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    • v.27 no.4
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    • pp.73-78
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    • 2009
  • Characterization of the microweld CCFL electrode for the TFT-LCD backlight unit was carried out in terms of the glass beading heat treatment conditions. We evaluate the weld zone and parent metal of the microweld CCFL electrodes that were exposed to simulated glass beading heat treatment. The CCFL electrode was composed of the cup made with pure Ni, the pin made with pure Mo and the lead wire made with Ni-Mn alloy. Each part of the electrode was assembled together by micro spot welding process and then the assembled electrodes were exposed to simulated glass beading temperatures of $700^{\circ}C,\;750^{\circ}C$ and $800^{\circ}C$. The microstructures of the microweld CCFL electrode were observed by using optical microscope, scanning electron microscope and EDS. Micro-tensile and microhardness test were also carried out. The results indicated that the grain coarsening in the HAZs(heat affected zones) for both the cup-pin weld and pin-lead wire were exhibited and the grain coarsening of the HAZ for the cup and the lead wire was more obvious than the HAZ of the pin. The micro-tensile test revealed that the fracture occurred at the cup-pin weld zone for all test conditions. The fracture surface could be classified into two parts such as pin portion and cup portion including weld nugget. The failure was seemed to be initiated from the boundary between nugget and pin through the weld joint. The result of the microhardness measurement exhibited that the relatively low hardness value, about 105HV was recorded at the HAZ of the cup. This value was about 50% less than that of the original value of the cup. The reduction of the microhardness was considered as the cause of the grain coarsening due to welding process. It was also appeared that there was no change in electric resistance for the standard electrodes and heat treated electrodes.

A Study on the Degradation Properties of Aqueous Trinitrotoluene by Palladium Catalyst and Formic Acid (Palladium 촉매와 포름산을 활용한 액상 trinitrotoluene 분해 특성 연구)

  • Jeong, Sangjo;Choi, Hyungjin;Park, Sangjin;Lee, Juneil
    • Journal of Korean Society on Water Environment
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    • v.31 no.5
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    • pp.468-475
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    • 2015
  • Various methods to degrade explosives efficiently in natural soil and water that include trinitrotoluene (TNT) have been studied. In this study, TNT in water was degraded by reduction with palladium (Pd) catalyst impregnated onto alumina (henceforth Pd-Al catalyst) and formic acid. The degradation of TNT was faster when the temperature of water was high, and the initial TNT concentration, pH, and ion concentration in water were low. The amounts of Pd-Al catalyst and formic acid were also important for TNT degradation in water. According to the experimental results, the degradation constant of TNT with unit mass of Pd-Al catalyst was $8.37min^{-1}g^{-1}$. The degradation constant of TNT was higher than the results of previous studies which used zero valent iron. 2,6-diamino-4-nitrotoluene and 2-amino-4,6-dinitrotoluene were detected as by-products of TNT degradation showing that TNT was reduced. The by-products of TNT were also completely degraded after reaction when both Pd-Al catalyst and formic acid existed. Even though there are several challenges of Pd-Al catalyst (e.g., deactivation, poisoning, leaching, etc.), the results of this study show that TNT degradation by Pd-Al catalyst and formic acid is a promising technique to remediate explosive contaminated water and soil.

Evaluation of Bank Filtrate Water Quality in Galjon, the Downstream of the Nakdong River (낙동강 하류 갈전지역에서의 강변여과수 수질평가)

  • Lee, Sooyoung;Chung, Taihak
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.487-494
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    • 2003
  • In this research, water qualities of river water and bank-filtrate were compared for six months including winter season. The location studied was Galjon area, the downstream of the Nakdong river. The well for bank-filtrate was installed 40 m apart from riverside. Main analytic results of bank-filtrate and river water were summarized as followings; the average concentrations in bank-filtrate were turbidity 0.8NTU, TN 0.4mg/l, $BOD_5$, 0.1mg/l, $KMnO_4$ consumption 1.6mg/l, heterotrophic bacteria 350cfu/ml, Fe 0.5mg/l, Mn 0.99mg/l while the average concentrations in river water were turbidity 6.1NTU, TN 3.9mg/l, $BOD_5$, 3.6mg/l, $KMnO_4$ consumption 11mg/l, heterotrophic bacteria 1,640cfu/ml, Fe 0.28mg/l, Mn 0.04mg/l. Water quality of bank-filtrate was mostly shown a good results than it of river water excepting Fe and Mn. In even basic constituents such as water temperature and pH, bank-filtrate was very settled while river water was extraordinary changable and high. In case of nitrogen, especially, total nitrogen of river water was 3.9mg/l while it of bank-filtrate was 0.4mg/l and its reduction was very high. The reason is that $NH^+_4-N$ among total nitrogen in the river water is nitrified and then denitrified in soil layer when it is pumped up as bank-filtrate. But Fe and Mn caused by the characteristics of soil was very high in bank-filtrate while Mn in river water was particularly very low and settled. As the distance between riverside and well was longer, concentration of Fe and Mn may be went up while its bacteria may be reduced.

Statistical Optimization for Monacolin K and Yellow Pigment Production and Citrinin Reduction by Monascus purpureus in Solid-State Fermentation

  • Jirasatid, Sani;Nopharatana, Montira;Kitsubun, Panit;Vichitsoonthonkul, Taweerat;Tongta, Anan
    • Journal of Microbiology and Biotechnology
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    • v.23 no.3
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    • pp.364-374
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    • 2013
  • Monacolin K and yellow pigment, produced by Monascus sp., have each been proven to be beneficial compounds as antihypercholesterolemic and anti-inflammation agents, respectively. However, citrinin, a human toxic substance, was also synthesized in this fungus. In this research, solidstate fermentation of M. purpureus TISTR 3541 was optimized by statistical methodology to obtain a high production of monacolin K and yellow pigment along with a low level of citrinin. Fractional factorial design was applied in this study to identify the significant factors. Among the 13 variables, five parameters (i.e., glycerol, methionine, sodium nitrate, cultivation time, and temperature) influencing monacolin K, yellow pigment, and citrinin production were identified. A central composite design was further employed to investigate the optimum level of these five factors. The maximum production of monacolin K and yellow pigment of 5,900 mg/kg and 1,700 units/g, respectively, and the minimum citrinin concentration of 0.26 mg/kg were achieved in the medium containing 2% glycerol, 0.14% methionine, and 0.01% sodium nitrate at $25^{\circ}C$ for 16 days of cultivation. The yields of monacolin K and yellow pigment were about 3 and 1.5 times higher than the basal medium, respectively, whereas citrinin was dramatically reduced by 36 times.