• Korean Journal of Materials Research
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• v.22 no.9
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• pp.454-458
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• 2012

Various adhesive materials are used in flip chip packaging for electrical interconnection and structural reinforcement. In cases of COF(chip on film) packages, low temperature bonding adhesive is currently needed for the utilization of low thermal resistance substrate films, such as PEN(polyethylene naphthalate) and PET(polyethylene terephthalate). In this study, the effects of anhydride and dihydrazide hardeners on the low-temperature snap cure behavior of epoxy based non-conductive pastes(NCPs) were investigated to reduce flip chip bonding temperature. Dynamic DSC(differential scanning calorimetry) and isothermal DEA(dielectric analysis) results showed that the curing rate of MHHPA(hexahydro-4-methylphthalic anhydride) at $160^{\circ}C$ was faster than that of ADH(adipic dihydrazide) when considering the onset and peak curing temperatures. In a die shear test performed after flip chip bonding, however, ADH-containing formulations indicated faster trends in reaching saturated bond strength values due to the post curing effect. More enhanced HAST(highly accelerated stress test) reliability could be achieved in an assembly having a higher initial bond strength and, thus, MHHPA is considered to be a more effective hardener than ADH for low temperature snap cure NCPs.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.628-631
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• 2004

In this paper, mechanical properties of concrete incorporating CKD are discussed with W/B and fluidity. For setting properties, an increase in W/B retarded setting time greatly in $5^{\circ}C$, while accelerated in $20^{\circ}C$. For fluidity, an increase in slump delayed the setting time with dosage of SP agent. The presence of CKD has little influence on setting time compared with plain concrete. For compressive strength, an increase in maturity enhanced compressive strength. Fluidity had no relation to compressive strength. At low curing temperature, concrete with CKD has slight strength loss compared with plain concrete. However, remarkable strength loss at low curing temperature in early stage was not found, which can be applicable to low temperature environment concrete placing.

• Polymer(Korea)
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• v.34 no.3
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• pp.191-197
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• 2010

To improve the curing method of anisotropic conductive film (ACF) at low temperature, it was studied to replace the thermal latent curing agent of imidazole compounds by the curing agent of cationically initiating type. Thermo-mechanical properties such as glass transition temperature, storage modulus, and coefficient of thermal expansion were investigated for the analysis of curing behavior. The reliability of ACF were observed in thermal cycle and high temperature-high humidity test. ACF using cationic initiator showed faster curing, lower CTE, and higher $T_g$ than the case of using imidazole curing agent, which is important for the high temperature stability. Furthermore, ACF using cationic initiator maintained a stable contact resistance in reliability test, although it was cured at low temperature and fast rate. With these results, it was confirmed that the curing method of epoxy had great effect on thermo-mechanical properties and reliability of ACF.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.5
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• pp.134-140
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• 2017

In this study, the flexural behavior of high strength concrete members with different curing condition of 90 MPa of compressive strength was investigated. Experimental parameters included normal and low temperature curing conditions, tensile steel amount and concrete compressive strength. 8 beam members were fabricated and flexural tests were carried out. Crack spacing, load-deflection relation, load-strain relation and ductility index were determined. Experimental results show that as the amount of rebar increases, the number of cracks increases and the crack spacing decreases. The higher the concrete strength, the smaller the number of cracks, but the effect is significantly smaller than the amount of rebar. As a result of comparison with the proposed average crack spacing in the design criteria, the experimental results are slightly larger than the results of the proposed formula, but the proposed formula does not reflect the concrete strength and curing conditions. The ductility index of normal temperature cured members was 3.36~6.74 and the ductility index of low temperature cured members was 1.51~2.82. The behavior of low temperature cured members was found to be lower than that of normal temperature cured members. As a result of comparing the ductility index with the existing studies similar to the experimental members, the ductility index of the high strength concrete member was larger than the ductility index of the ordinary strength concrete of the previous study. Further research is needed to understand more specific results.

• Journal of the Korean Geotechnical Society
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• v.19 no.2
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• pp.7-14
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• 2003

A series of laboratory tests, which can show how different curing conditions influence an aging effect on clay, were carried out for the clay samples collected in the area of Kwangyang Bay and Mokpo. Clay samples were remolded and reconsolidated under three different curing temperatures (20, 50, and 80 degree Celsius) and low different curing durations (1, 7, 14, and 40 days). To find out an aging effect and geotechnical characteristics between undisturbed samples and reconsolidated samples, laboratory tests, consisting of uniaxial compression tests, CU triaxial test, and consolidation tests, were preformed. Results showed that the compression index ratio is very useful factor to indicate the aging effect of natural clays. Also geotechnical characteristics of clays reconsolidated at high temperature were very similar to those of undisturbed clays. Finally, curing temperature and curing duration influenced an aging effect on clays. The best curing condition was 80 degree Celsius and 27 days.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.533-536
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• 2001

When fresh concrete is exposed to low temperature, the concrete may suffer frost damage due to freezing at early ages and strength development may be delayed. One of the solution methods for resolving these problems is to reduce freezing temperature of concrete by the use of chemical admixture called Accelerators for freezing resistance. In this study, we investigate the effect on strength development of cement mortar using accelerators for freezing resistance with the variance curing condition. As the result of this study, the mortar using accelerators for freezing resistance show that continuously strength development in curing condition of -5$^{\circ}C$. And compressive strength under the variance temperature condition was higher than fixed temperature condition in same maturity.

• Journal of the Korean Society for Precision Engineering
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• v.31 no.8
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• pp.653-658
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• 2014

Roll-to-Roll printing process has become a great issue as a breakthrough for low cost and mass production of electronic devices such as organic thin film transistor, and etc. To print the electronic devices, multi-layer printing is essential, and high precision register control is required for this process. Unlike stop-and-repeat printing process, it is impossible to control the register in a static state since the roll-to-roll process is a continuous system. Therefore, the behavior of web such as polyethylene terephthalate (PET) and polyimide (PI) by the tensile and thermal stress generated in the roll-to-roll process as well as motor control of driven rolls has to be considered for a high precision register control. In this study, the correlation between curing temperature and thermal deformation of PET web is analyzed. Finally, it is verified experimentally that the temperature disturbance generates the more serious register error under the higher curing temperature.

• Journal of the Korea Institute of Building Construction
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• v.16 no.4
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• pp.305-311
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• 2016

This study examined the long-term inelastic characteristics, including unrestrained shrinkage and creep, of low-heat cement concrete under different ambient curing temperatures. To achieve the designed compressive strength of 42MPa, water-to-binder ratios were selected to be 27.5, 30, and 32.5% for curing temperatures of 5, 20, and $40^{\circ}C$, respectively. Test results showed that the shrinkage strains of concrete mixtures tended to decrease with the decrease in curing temperature because of the delayed evaporation of internal capillary and gel waters. Meanwhile, creep strains were higher in concrete specimens under lower curing temperature due to the occurrence of the transition temperature creep. The design models of KCI provision gave better accuracy in comparison with test results than those of ACI 209, although a correction factor for low-heat cement needs to be established in the KCI provision.

• Journal of the Korean Society of Tobacco Science
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• v.7 no.2
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• pp.129-139
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• 1985

cent was carried out to study on the effect of temperature and humidity to chemical tobacco leaves during the yellowing stage. The results were follows : In the condition of high humidity and low temperature, yellowing time was delayed ; leaf color appeared lack clearness. In the higher temperature and the lower humidity during the yellowing stage : total sugar, reducing sugar and malic acid content were increased. Decomposition of nitrogenous components elevated in $38^{\circ}C$, 85%RH. Changes of total nitrogen content correlated with total curing time. Adecrease of linolenic acid with a corresponding increase of chlorogenic acid proceeded in the condition of low temperature and high humidity. In a view of tobacco quality by chemical components, the low temperature and high humidity during the yellowing stage decreased quality of tobacco leaves. It is considered to control of the proper condition of temperature and humidity during the yellowing.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.1199-1202
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• 2001

The objective of this study is to examine the effect of frost damage immediately after placement on compressive strength of concrete. Obviously frost damage produced under low curing temperature at early ages causes the loss of compressive strength of concrete. In order to find the degrees of the loss of compressive strength, compressive strength tests was peformed at 7 and 28-day ages on concrete specimen with various curing temperature history. The results from the tests showed that the loss of compressive strength relative to concrete cured under isothermal temperature at $20^{\circ}C$ was generally from 20 to 50% for 7-day ages and below 20% for 28 day ages. Considering the serious loss of compressive strength over 50% for some cases, careful attention may be needed to placing of concrete under low atmospheric temperature.