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A Review on Membranes and Catalysts for Anion Exchange Membrane Water Electrolysis Single Cells

  • Cho, Min Kyung;Lim, Ahyoun;Lee, So Young;Kim, Hyoung-Juhn;Yoo, Sung Jong;Sung, Yung-Eun;Park, Hyun S.;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.183-196
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    • 2017
  • The research efforts directed at advancing water electrolysis technology continue to intensify together with the increasing interest in hydrogen as an alternative source of energy to fossil fuels. Among the various water electrolysis systems reported to date, systems employing a solid polymer electrolyte membrane are known to display both improved safety and efficiency as a result of enhanced separation of products: hydrogen and oxygen. Conducting water electrolysis in an alkaline medium lowers the system cost by allowing non-platinum group metals to be used as catalysts for the complex multi-electron transfer reactions involved in water electrolysis, namely the hydrogen and oxygen evolution reactions (HER and OER, respectively). We briefly review the anion exchange membranes (AEMs) and electrocatalysts developed and applied thus far in alkaline AEM water electrolysis (AEMWE) devices. Testing the developed components in AEMWE cells is a key step in maximizing the device performance since cell performance depends strongly on the structure of the electrodes containing the HER and OER catalysts and the polymer membrane under specific cell operating conditions. In this review, we discuss the properties of reported AEMs that have been used to fabricate membrane-electrode assemblies for AEMWE cells, including membranes based on polysulfone, poly(2,6-dimethyl-p-phylene) oxide, polybenzimidazole, and inorganic composite materials. The activities and stabilities of tertiary metal oxides, metal carbon composites, and ultra-low Pt-loading electrodes toward OER and HER in AEMWE cells are also described.

An Investigation of Stress Corrosion Cracking Characteristics of SUS 304 Stainless Steel Weldments (SUS 304鋼 熔接部 의 SCC特性 에 관한 硏究)

  • 김영식;임우조
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.6
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    • pp.569-575
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    • 1984
  • The characteristics of the stress corrosion cracking of SUS 304 stainless steel weldments were studied with the speciments of the constant displacement type under the environment of 42% MgC $l_{2}$ boiled solution (143.+.-.2.deg.C). The susceptibility of initiation and propagation of the stress corrosion crack was quantitatively inspected in the weld metal, heat affected zone and heat affected zone with including the reinforcement shape, respectively. Also, those susceptibility were discussed in connection with the change of mechanical and microstructural characteristics caused by heating cycle of welding. Main results obtained are as follows: (1)Stress corrosion cracking is easiest to initiate and propagate in the heat affected zone of weldment. (2)The susceptibility of stress corrosion cracking of the weldment is largely improved by eliminating the reinforcement part of the weld bead. (3)The dominant factor of the cracking susceptibility of the heat affected zone appeared to be the phenomenon of softening and sensitizing caused by welding heat cycle. (4)Under the low loading conditions, the behavior of stress corrosion cracking of the SUS 304 steel weldment is largely influenced by the pitting phenomenon in the front region of the main crack.

Three-dimensional Flexure Modeling by Seamount Loading in the Western Pacific: Infinite Plate Model (서태평양에 위치한 해저산들의 3-D flexure 모델링 : 무한지판 모델)

  • Lee, Tae-Gook;Moon, Jai-Woon;Chi, Sang-Bum;Park, Cheong-Kee;Lee, Kie-Hwa
    • Ocean and Polar Research
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    • v.27 no.1
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    • pp.35-44
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    • 2005
  • The bathymetric and gravity data were obtained in 2001 and 2003 during a survey of seamounts in the northwest of the Marshall Islands, western Pacific. The study areas are located in the Pigafetta Basin which is the oldest part of the Pacific plate and in the Ogasawara Fracture Zone which formed from the spreading ridge between the Izanagi and Pacific plates in the Jurassic. The densities of seamounts and the elastic thickness values of the lithosphere are calculated by using three-dimensional flexure modeling considering the constant sediment layer in the infinite plate model. Very low elastic thickness values (5km), relatively young seamounts, and old lithosphere in the east study area suggest the possibility of the rejuvenation of lithosphere by widespread volcanisms, whereas the elastic thickness values (15km), relatively old seamounts, and young lithosphere of the west study area are suitable for a simple cooling plate model of $300-600^{\circ}C$ isotherm. The gravity residuals of OSM6-1 and OSM6-2 suggest the possibility of different load density or elastic thickness. Relatively older OSM6-2 formed on the younger lithosphere with relatively thin elastic thickness, while younger OSM6-1 on the older lithosphere with relatively thick elastic thickness.

Job Stress and Its Related Factors in South Korean Doctors (일부 의사들의 직무스트레스와 관련 요인)

  • Kam, Sin;Lee, Sang-Won;Chun, Byung-Yeol;Yeh, Min-Hae;Kang, Yune-Sik
    • Journal of Preventive Medicine and Public Health
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    • v.34 no.2
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    • pp.141-148
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    • 2001
  • Objective : To investigate the sources, extent and related factors in South Korean doctors. Methods : The study subjects were 934 doctors in Taegu, Kyungpook Province, Korea(540 independent practitioners, 105 employed at hospitals and 289 residents in training). Information concerning job stress was obtained using a 9-item questionnaire. Information regarding related factors such as demographic characteristics(age, sex, marital status), perceptions on the socioeconomic status of doctors and working conditions(work time, on-call days per week) was also obtained by self-administered questionnaire during April and May, 2000. Results : Major sources of job stress included clnical responsibility/judgement factor, patient factor and work loading factor. The job stress score of residents was the highest among three groups. The score was lower in older doctors. The score was low among those who thought doctors' socioeconomic status was not good. The longer the work time, the higher the job stress score was. Multiple regression analysis was conducted to control for the mutual influence of independent variables. In regression analysis, the score of residents was higher than practitioners. Work time and socioeconomic status perception had negative effects on job stress score. Conclusion : The average job stress score of the doctors was high. Age, work type, working conditions and perceptions of socioeconomic status were found to besignificantly related to job stress score. Although the job stress of doctors is somewhat inevitable due to the nature of the doctor's job, control of work time, development of coping tools and other intervention methods are needed to reduce job stress of doctors. Further studies are required to understand the characteristics of iob stress and reduce the job stress of doctors.

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Analysis of Sloping Ground When Lifting with Force Platform (힘판을 이용한 들기 작업시의 경사면 분석)

  • 서승록;김종석
    • Journal of Korea Society of Industrial Information Systems
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    • v.5 no.1
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    • pp.77-86
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    • 2000
  • Even manual materials handling tasks(MMHT) is decreasing by adopt of automatic manufacturing system & transportation supporting machine because of increase of productivity, wage lack of labor, safety, in fact working at inclined & complicated slope such as farm, orchard, harbor loading & unloading, logging place and mining place can't be substituted by machine perfectly. So, workers should do MMHT at this place by themselves, lifting on slope can cause much of hazard, include falling. Keeping balance net to slip can be a reason of low back pain(LBP) by overloaded musculoskeletal system but, there's no enough study about lift on slope. Therefore, In this study, we assessed and analyzed change of center of pressure(COP) when lifting on slope by force platform. The result showed that the length lengthen as increasing angle of slope. Especially, the length extremely increased over 15°. Through These basic result, present proper angle boundary, prevent industrial accidents and give proper data not only lifting but also pushing and pulling on slope someday.

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Investigation on the monotonic behavior of the steel rack upright-beam column connection

  • Cao, Yan;Alyousef, Rayed;Jermsittiparsert, Kittisak;Ho, Lanh Si;Alaskar, Abdulaziz;Alabduljabbar, Hisham;Alrshoudi, Fahed;Mohamed, Abdeliazim Mustafa
    • Smart Structures and Systems
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    • v.26 no.1
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    • pp.103-115
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    • 2020
  • The cold-formed steel storage racks are extensively employed in various industries applications such as storing products in reliable places and storehouses before distribution to the market. Racking systems lose their stability under lateral loads, such as seismic actions due to the slenderness of elements and low ductility. This justifies a need for more investigation on methods to improve their behavior and increase their capacity to survive medium to severe loads. A standardized connection could be obtained through investigation on the moment resistance, value of original rotational stiffness, ductility, and failure mode of the connection. A total of six monotonic tests were carried out to determine the behavior of the connection of straight 2.0 mm, and 2.6 mm thickness connects to 5 lug end connectors. Then, the obtained results are benched mark as the original data. Furthermore, an extreme learning machine (ELM) technique has been employed to verify and predict both moment and rotation results. Out of 4 connections, increase the ultimate moment resistance of connection by 13% and 18% for 2.0 mm and 2.6 mm upright connection, respectively.

Study on the Improvement of Water Quality by the strengthening of T-P effluent standard for Environmental Facilities in Paldang Basin (환경기초시설의 인 기준 강화에 따른 팔당호 유입 수계의 수질개선 효과분석)

  • Jeong, Won-Gu;Han, Young-Han;Rim, Jay-Myung
    • Journal of Industrial Technology
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    • v.30 no.B
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    • pp.125-135
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    • 2010
  • The influences on water quality of each river by effluents from environmental facilities $located^{*}$ in 14 unit watersheds of North- and South-Han River, and Gyungan-cheon were analyzed. Also, the water quality modeling for study area was carried out to analyze the improvement effect of water quality by the strengthening of T-P effluent standard of environmental facilities. For the calibration and verification of model, water quality data and effluent loading calculated for 2006 were used. Data of low water period were used for calibration, and normal water period for verification. The results of calibration and verification were well matched with the real water quality dataset of revers. Also, the validity of the results were estimated using RI (Reliability Index) method. When the T-P effluent standards for environmental facilities were strengthened, T-P concentrations were predicted to improve from $0.025mg/{\ell}$ to $0.023mg/{\ell}$ in the outlet location of North-Han River, from $0.056mg/{\ell}$ to $0.040mg/{\ell}$ for South-Han River,and from $0.233mg/{\ell}$ to $0.146mg/{\ell}$ for Gyungan-cheon. Also, the T-P concentrations of tributaries including Jojong-cheon, Dal-cheong, Sumgang, Chungmi-cheon, Bokha-cheon, Heuk-cheon, and Wonju-cheon were predicted to improve from $0.063mg/{\ell}$ to $0.010mg/{\ell}$, from $0.091mg/{\ell}$ to $0.053mg/{\ell}$, from $0.199mg/{\ell}$ to $0.100mg/{\ell}$, from $0.168mg/{\ell}$ to $0.148mg/{\ell}$, from $0.186mg/{\ell}$ to $0.105mg/{\ell}$, from $0.019mg/{\ell}$ to $0.013mg/{\ell}$, and from $0.822mg/{\ell}$ to $0.236mg/{\ell}$, respectively.

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Study on GIS based Automatic Delineation Method of Accurate Stream Centerline for Water Quality Modeling (GIS기반의 수질모델링 지원을 위한 정확도 높은 하천중심선의 자동 추출기법에 관한 연구)

  • Park, Yong-Gil;Kim, Kye-Hyun;Lee, Chol-Young
    • Spatial Information Research
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    • v.18 no.4
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    • pp.13-22
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    • 2010
  • For implementing TMDL(Total Maximum Daily Loading) to adopt more effective management of water pollution, water quality modeling is pre-requisite and such modeling requires the extraction of stream centerline. The institutes responsible for the water quality modeling, however, generates the stream centerline with their own criteria and this lead to low accuracy of the extracted centerline as well as different modeling results for the same watershed. Therefore, this study mainly focused on the development of extraction method of the stream centerline. For that, an automated method has been developed through the integration of the centerline extraction method using a maximum inscribed circle with GIS. The result has shown that the newly developed method could enable to represent more details of the stream topography along with enhanced accuracy compared with conventional extraction method. Furthermore, the new method can afford centerline extraction for the island areas which has been the limitation of the conventional method thereby supporting water quality modeling in a detailed level.

Development of HRP-modified Carbon Composite Biosensor and Electrochemical Analysis of H2O2 (Horseradish peroxidase가 변성된 탄소복합 바이오센서 개발 및 전기화학적 H2O2분석)

  • Park, Deog-Su
    • Journal of the Korean Chemical Society
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    • v.56 no.5
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    • pp.571-576
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    • 2012
  • A sol-gel derived carbon composite electrodes (CCEs) were fabricated by mixing horseradish peroxidase (HRP), sol of tetraethoxysilane (TESO), and graphite powder. The HRP solution was added to the sol solution of TEOS, and then graphite powder was added to this mixture. The resulting carbon ceramic network effectively encapsulated HRP and shows a catalytic reduction starting at -0.2 V for $H_2O_2$. The optimum conditions for $H_2O_2$determination have been characterized with respect to the enzyme loading ratio and pH. The linear range and detection limit of $H_2O_2$ detection were from 0.2 mM to 2.2 mM and 0.035 mM, respectively. The common electroactive interferences such as ascorbic acid, acetaminophene, and uric acid were not affected upon the response to $H_2O_2$ at the HRP biosensor due to low detection potential.

Application of Equivalent Walking Loads for Vibration Analysis of Building Floor Subjected to Footstep Loadings (보행하중을 받는 건축물 바닥판의 진동해석을 위한 등가 보행하중의 적용)

  • 김기철;이동근
    • Journal of the Earthquake Engineering Society of Korea
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    • v.5 no.5
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    • pp.35-45
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    • 2001
  • Recently, the floor systems those require large open space may have low inherent damping due to the decline of the use of curtain walls. Furthermore, the use of the high strength materials has resulted in more flexible and longer spanning in floor systems. The long span structures such as shopping malls, offices and large assembly rooms may lead to significant dynamic response due to human activities. Excessive vibrations make the occupants uncomfortable and deteriorate the serviceability of buildings. It is now proved that footfall loading is the major source of floor vibrations. The common method of application of walking loads for the vibration analysis of structures subjected to walking loads is to inflict measured walking loads and periodic function at a node. But this method could not account for the moving effect of walking. In this study, natural frequency and damping ratio of example structure are evaluated by heel drop tests. And the application of equivalent walking loads is used for on efficient vibration analysis of the plate structures subjected to walking loads.

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