• Macromolecular Research
• /
• 제10권5호
• /
• pp.266-272
• /
• 2002

Although the reptational model of Doi and Edwards gives a successful description of viscoelasticity of flexible linear polymers, the success is restricted to the terminal region./sup 1/ There have been several attempts to modify the Doi-Edwards model to describe wider range of time or frequency./sup 2-6/ This paper suggests a simple phenomenological model which can describe wider range of molecular weight than such molecular models can. Although our model is a phenomenological one, it is practical and convenient to predict the effect of molecular weight distribution on linear viscoelastic data because of its simple mathematical form.

• 한국유변학회:학술대회논문집
• /
• 한국유변학회 2002년도 추계학술발표회 논문집
• /
• pp.81-84
• /
• 2002

• Korea-Australia Rheology Journal
• /
• 제13권2호
• /
• pp.67-81
• /
• 2001

The development of new techniques for the dynamic measurement of linear viscoelastic properties is an active area of rheometry, and this paper surveys some novel deformation geometries which have been recently reported e.g. oscillating probe-type devices which are imbedded in or placed on the surface of the sample. Small amplitude band-limited pseudorandom noise is used for the displacement signal, with Fourier analysis of the complex waveform of the resistance force yielding the frequency dependent viscoelastic material functions (e.g. storage and loss moduli G", G"). Theoretical calculations of the fundamental equations relating force to displacement and instrument geometry, were carried out with the aid of the correspondence principle of linear viscoelasticity. The rapidity of the tests and flexibility in terms of sample preparation and stiffness mean that this basic technique should find many applications in rheometry. Three examples of oscillatory tests are presented in detail squeeze flow, imbedded needle and concentric sliding cylinder geometries.eometries.

• 한국유변학회:학술대회논문집
• /
• 한국유변학회 2002년도 춘계 학술발표회 논문집
• /
• pp.97-100
• /
• 2002

• 대한의용생체공학회:의공학회지
• /
• 제19권5호
• /
• pp.495-502
• /
• 1998

Y.C. Fung[1]에 의한 연조직의 점탄성에 관한 수학적 모델이론 (Fung's Quasi-linear vlscoelastic theory)을 이용하여 인간의 인두조직의 점탄성(vlscoelatlcity)특성을 측정하기 위하여 반복성하중(cyclic load) ,응력완화 (tensile stress relaxation), incremental load, 그리고 일축성인장 (uniaxial tensile) 시험 등을 실시하였다. 실험적으로 측정한 인두조직의 점탄성특성이 이미 조사된 다른 조직의 점탄성특성과 정량적으로 비교되었다. 인두조직의 점탄성특성의 정량화를 위하여 Y.C.Fung의 수학적 모델이 적용되었는데 응력완화(tensile stress relaxation) 시험 측정결과로부터 도출된 표준화된 응력완화(reduced stress relaxation)함수 G(t)와 일축성인장(uniaxial tensile)시험에서 도출된 탄성반응(elastic response)함수 5(t)를 이용하여 시간에 따른 응력의 궤적을 산출하여 이를 반복성 하중(cyclic load)실험에서 측정된 결과와 비교, 분석하였다. 이러한 인두조직의 점탄성특성에 관한 연구결과는 향후 유한요소를 이용한 인두의 생체역학적 모델의 기본 데이터로 이용될 수 있다.

• Korea-Australia Rheology Journal
• /
• 제21권2호
• /
• pp.135-141
• /
• 2009

Effect of activation energy and crystallization kinetics of polyethylenes (PEs) on the dynamics and stability has been investigated by changing rheological properties and crystallization rate in film casting process. The effect of changes of these properties has been shown using a typical example of short-chain branching (SCB) in linear polyethylenes. SCBs in linear polymers generally lead to the increase of the flow activation energy, and to the decrease of the crystallization rate, making polymer viscosity lower in the case of equivalent molecular weight. In general, the increment of the crystallinity of polymers under partially crystallized state helps to enhance the process stability by increasing tension, and lower fluid viscoelasticity possesses the stabilizing effect for linear polymers. It has been found that the fluid viscoelasticity plays a key role in the control of process stability than crystallization kinetics which critically depends on the cooling to stabilize the film casting process of short-chain branched polymers operated under the low aspect ratio condition.

• 대한기계학회논문집A
• /
• 제20권7호
• /
• pp.2148-2158
• /
• 1996

Uncoupled, quasi-static and linear thermoviscoelastic problems are analyzed in time domain by the finite element approximation which is developed using the principle of virtual work and viscoelasticity matrices instead of shear and bulk relaxation functions as in usual formulations. The material is assumed to be isotropic, homegeneous and thermorheologically simple, which means that the temperature-time equivalence postulate is effective. The stress-strain laws are expressed by relaxation-type hereditary integrals. In spatial and time discritizations, isoparametric quadratic quadrilateral finite elements and linear time variations are adopted. For explicit derivations, the viscoelastic material is assumed to behave standard linear solid in shear and elastically in dilatation. Two-dimensional examples are solved under general temperature distributions T = T(x, t), and compared with other opproximate solutions to show the versatility of the presented analysis.

• 대한기계학회논문집
• /
• 제16권8호
• /
• pp.1429-1437
• /
• 1992

본 연구에서는 이완형 물성방정식을 바탕으로 하며 프와송 비가 일정하다는 가정을 하지 않는다. 또한 점탄성 지배방정식에 변분원리를 적용하고 유도되어진 식 에 유한요소해법을 사용하여 시스템 기본해석을 위한 연립방정식을 유도한다. 이와 함께 점탄성 물성함수의 유도 및 응력계산을 위한 공식화 과정도 설명한다. 제시된 방법론의 타당성 및 정확성을 보이기 위해서 평면응력 및 평면변형 문제의 변위 및 응력을 수치해석하여 이론해와 비교 검토하며, 아울러 시간증분의 변화와 Gauss poi- nts수가 수치정확도에 끼치는 영향을 조사한다.

• Korea-Australia Rheology Journal
• /
• 제14권2호
• /
• pp.57-62
• /
• 2002

The sensitivity of the final filament to the ongoing sinusoidal disturbances has been Investigated in the viscoelastic spinning using frequency response method. Amplification ratios or gains of the spinline cross-sectional area at the take-up to any disturbances show resonant peaks along the frequency regime, where the frequencies at theme points directly correspond to the imaginary parts of the successive leading eigenvalues from the linear stability analysis. As shown in Jung et al. (1999) and Lee et al (2001), the sensitivity results on the effect of various process conditions such as spinline cooling and fluid viscoelasticity, obtained by dynamic transient simulation have been corroborated in this study. That is, increasing spinline cooling makes the system less sensitive to disturbances, thus stabilizes the spinning. Also, an increasing viscoelasticity for extension-thickening fluids decreases the sensitivity of the spinning. i.e., stabilizing the system, where, as it increases the sensitivity of the spinning of extension-thinning fluids. Furthermore, it has been found in the present study that the inertia force as one of secondary forces causes the system to be more stabile or less sensitive to process disturbances.

• 전산구조공학
• /
• 제10권4호
• /
• pp.229-238
• /
• 1997

본 논문에서는 반복하중에 의해 손상을 입은 아스팔트 콘크리트의 점탄성 구성모델에 대한 역학적 접근방법을 제시하였다. 모의변수로 나타낸 탄성-점탄성 일치원리는 아스팔트 콘크리트의 점탄성과 시간의존 손상의 증가를 별도로 평가하도록 적용되었다. 선형-점탄성 파괴역학에 사용되고 있는 미소균열의 증가법칙이 물체내 손상증가를 나타내는데 성공적으로 사용되었다. 응력과 모의변형도로 나타나는 구성방정식은 먼저 변형도조절에 대해 세워졌으며, 응력과 모의변형도를 모의응력과 변형도로 간단하게 대체함으로써 응력조절 구성방정식으로 변형되었다. 모의응력으로 나타낸 변형된 구성방정식은 응력조절모드에서 파괴에 이르는 아스팔트 콘크리트의 모든 역학적 거동을 충분히 예측하고 있다.