• Title/Summary/Keyword: light scattering characteristics

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Comparison of Characterization Techniques of the Pore in Paper Sheet (종이의 기공 특성 측정 기법의 비교)

  • Won, Jong-Myoung;Nam, Ki-Young;Chung, Soon-Ki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.1-6
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    • 2007
  • Paper is a composite consisted of various solid materials including pulp, filler and other additives. The pore is also one of components consisting the paper structure. Thus the characterization of pore structure of paper is very helpful in the understanding the structural properties of paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers pointed out the problem that the distortion of the pore structure can be occurred by the application of high pressure during mercury intrusion. Thus in this study, we tried to evaluate the potential of SEM and image analysis method as means for analyzing pore structure of the paper. The new pore analysis technique with SEM and image analysis does not require the application of high pressure, and gave better relation between the measured pore characteristics and the bulk of sheet than mercury intrusion method.

Mixing Effect by Tone-Excitation In Round Jet Diffusion Flame (원형분류확산화염에서의 음파가진에 의한 혼합효과)

  • Kim, Tae Kwon;Park, Jeong;Shin, Hyun Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.795-801
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    • 1999
  • An experimental investigation has been conducted with the objective of studying the mixing mechanism near the nozzle exit in a tone-excited jet diffusion flame. The fuel jet was pulsed by means of a loudspeaker-driven cavity. The excitation frequencies were chosen for the two cases of the non-resonant and resonant frequency identified as a fuel tube resonance due to acoustic excitation. The effect of tone-excitations on mixing pattern near the nozzle exit and flame was visualized using various techniques, including schlieren photograph and laser light scattering photograph from $TiO_2$ seed particles. In order to clarify the details of the flame feature observed by visualization methods, hotwire measurements have been made. Excitation at the resonant frequency makes strong mixing near the nozzle. In this case, the fuel jet flow in the vicinity of nozzle exit breaks up into disturbed fuel parcels. This phenomena affects greatly the combustion characteristics of the tone excited jet and presumably occurs by flow separation from the wall inside the fuel nozzle. As a result, in the resonant frequency the flame length reduces greatly.

Soot Formation Characteristics of Concentric Diffusion Flames with Mixture Fuels (이중동축류 화염을 이용한 혼합연료의 매연생성 특성에 관한 연구)

  • Lee, Won-Nam
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.123-128
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    • 2002
  • The synergistic effect of ethylene/propane and ethylene/methane mixtures on soot formation is studied experimentally with a concentric co-flow burner. The integrated soot volume fractions, laser light scattering signal and PAH concentrations are measured for different fuel supply configurations. The synergistic effect in ethylene/propane diffusion flames is found to be affected not only by the composition of mixture but also by the way of mixing. Comparing to the homogeneously mixed ethylene/propane case, the increase of soot formation is observed when propane is supplied through the inner nozzle, while the decrease is observed when propane is supplied through the outer nozzle. However, the measured PAH concentration distributions are inconsistent with the current view of the synergistic effect of ethylene./propane mixture on soot formation. Virtually no synergistic effect is observed in ethylene-methane flames regardless of the fuel supply configuration, which suggests the important role of $C_3$ species produced during the propane pyrolysis process for the synergistic effect.

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Large Scale Applications of Nanocellulosic Materials - A Comprehensive Review -

  • Lindstrom, Tom;Naderi, Ali;Wiberg, Anna
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.5-21
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    • 2015
  • The common production methods of nanocellulosic (cellulosic nanofibrils, CNF) materials from wood are being reviewed, together with large scale applications and particularly papermaking applications. The high energy demand for producing CNF has been one particular problem, which has been addressed over the years and can now be considered solved. Another problem was the clogging of homogenizers/microfluidizers, and the different routes to decrease the energy demand. The clogging tendency, related to the flocculation tendency of fibres is discussed in some detail. The most common methods to decrease the energy demand are TEMPO-oxidation, carboxymethylation and mechanical/enzymatic pre-treatments in the order of increased energy demand for delamination. The rheology characteristics of CNF materials, i.e. the high shear viscosity, shear thinning and the thixotropic properties are being illuminated. CNF materials are strength adjuvants that enhance the relative bonded area in paper sheets and, hence increase the sheet density and give an increased strength of the paper, particularly for chemical pulps. At the same time papers obtain a lower light scattering, higher hygroexpansion and decreased air permeability, similar to the effects of beating pulps. The negative effects on drainage by CNF materials must be alleviated through the appropriate use of microparticulate drainage aids. The use of CNF in films and coatings is interesting because CNF films and coatings can provide paper/board with good oxygen barrier properties, particularly at low relative humidities. Some other high volume applications such as concrete, oil recovery applications, automotive body applications and plastic packaging are also briefly discussed.

Enhanced Light Transmittance of Densely Packed Metal Nanoparticle Layers (밀집된 금속 나노 입자 레이어의 광학 특성)

  • Jeon, Hyunji;Choi, Jinnil
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.701-708
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    • 2020
  • Irradiation of the metal nanoparticles causes local plasmon resonance in a specific wavelength band, which can improve the absorption and scattering properties of a structure. Since noble metal nanoparticles have better resonance effects than those of other metals, it is easy to identify plasmonic reactions and this is advantageous to find the optical tendency. Compared to having a particle gap or randomly arranged particle structures, densely and evenly packed structures can exhibit more uniform optical properties. Using the uniform properties, the structure can be applied to optical filtering applications. Therefore, in this paper, validation tests about metal nanoparticles and thin film structures are conducted for more accurate analysis. The optical properties of monolayer and bilayer noble metal nanoparticle structures with different diameters, packed in a uniform array, are investigated and their optical trends are analyzed. In addition, a thin film structure under identical conditions as metal nanoparticle structure is evaluated to confirm the improved optical characteristics.

Analysis of Wafer Cleaning Solution Characteristics and Metal Dissolution Behavior according to the Addition of Chelating Agent (착화제 첨가에 따른 웨이퍼 세정 용액 특성 분석 및 금속 용해 거동)

  • Kim, Myungsuk;Ryu, Keunhyuk;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.28 no.1
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    • pp.25-30
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    • 2021
  • The surface of silicon dummy wafers is contaminated with metallic impurities owing to the reaction with and adhesion of chemicals during the oxidation process. These metallic impurities negatively affect the device performance, reliability, and yield. To solve this problem, a wafer-cleaning process that removes metallic impurities is essential. RCA (Radio Corporation of America) cleaning is commonly used, but there are problems such as increased surface roughness and formation of metal hydroxides. Herein, we attempt to use a chelating agent (EDTA) to reduce the surface roughness, improve the stability of cleaning solutions, and prevent the re-adsorption of impurities. The bonding between the cleaning solution and metal powder is analyzed by referring to the Pourbaix diagram. The changes in the ionic conductivity, H2O2 decomposition behavior, and degree of dissolution are checked with a conductivity meter, and the changes in the absorbance and particle size before and after the reaction are confirmed by ultraviolet-visible spectroscopy (UV-vis) and dynamic light scattering (DLS) analyses. Thus, the addition of a chelating agent prevents the decomposition of H2O2 and improves the life of the silicon wafer cleaning solution, allowing it to react smoothly with metallic impurities.

Resonance Scattering Characteristics of Multi-layered Dielectric Gratings under Conical Incidence (원추형 입사에서 다층 유전체 격자구조의 공진 산란특성)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.22 no.5
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    • pp.123-128
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    • 2022
  • Applying rigorous modal transmission-line theory (MTLT), the properties of resonant diffraction gratings under conical light incidence is investigated. The mode vectors pertinent to resonant diffraction under conical mounting vary less with incident angle than those associated with diffraction gratings in classical mounting. Furthermore, as the evanescent diffracted waves drive the leaky modes responsible for the resonance effects, the conical mounting imbues diffraction gratings with larger angular tolerance than their classical counterparts. Based on these concepts, the angular-spectral and wavelength-spectral performance of resonant diffraction gratings in conical and classical mounts by numerical calculations with spectra found for conical incidence are quantified. These results will be useful in various applications demanding resonant diffraction gratings that are efficient and physically sparse.

Characterization of Groundwater Colloids From the Granitic KURT Site and Their Roles in Radionuclide Migration

  • Baik, Min-Hoon;Park, Tae-Jin;Cho, Hye-Ryun;Jung, Euo Chang
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.3
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    • pp.279-296
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    • 2022
  • The fundamental characteristics of groundwater colloids, such as composition, concentration, size, and stability, were analyzed using granitic groundwater samples taken from the KAERI Underground Research Tunnel (KURT) site by such analytical methods as inductively coupled plasma-mass spectrometry, field emission-transmission electron microscopy, a liquid chromatography-organic carbon detector, and dynamic light scattering technique. The results show that the KURT groundwater colloids are mainly composed of clay minerals, calcite, metal (Fe) oxide, and organic matter. The size and concentration of the groundwater colloids were 10-250 nm and 33-64 ㎍·L-1, respectively. These values are similar to those from other studies performed in granitic groundwater. The groundwater colloids were found to be moderately stable under the groundwater conditions of the KURT site. Consequently, the groundwater colloids in the fractured granite system of the KURT site can form stable radiocolloids and increase the mobility of radionuclides if they associate with radionuclides released from a radioactive waste repository. The results provide basic data for evaluating the effects of groundwater colloids on radionuclide migration in fractured granite rock, which is necessary for the safety assessment of a high-level radioactive waste repository.

Effect of organic solvents on catalyst structure of PEM fuel cell electrode fabricated via electrospray deposition

  • Koh, Bum-Soo;Yi, Sung-Chul
    • Journal of Ceramic Processing Research
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    • v.18 no.11
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    • pp.810-814
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    • 2017
  • Proton exchange membrane fuel cells (PEMFCs) are some of the most efficient electrochemical energy sources for transportation applications because of their clean, green, and high efficiency characteristics. The optimization of catalyst layer morphology is considered a feasible approach to achieve high performance of PEMFC membrane electrode assembly (MEA). In this work, we studied the effect of the solvent on the catalyst layer of PEMFC MEAs fabricated using the electrostatic spray deposition method. The catalyst ink comprised of Pt/C, a Nafion ionomer, and a solvent. Two types of solvent were used: isopropyl alcohol (IPA) and dimethylformamide (DMF). Compared with the catalyst layer prepared using IPA-based ink, the catalyst layer prepared with DMF-based ink had a dense structure because the DMF dispersed the Pt/C-Nafion agglomerates smaller and more homogeneously. The size distribution of the agglomerates in catalyst ink was confirmed through Dynamic Light Scattering (DLS) and the microstructure of the catalyst layer was compared using field emission scanning electron microscopy (FE-SEM). In addition, the electrochemical investigation was performed to evaluate the solvent effect on the fuel cell performance. The catalyst layer prepared with DMF-based ink significantly enhanced the cell performance (1.2 A cm-2 at 0.5 V) compared with that fabricated using IPA-based ink (0.5 A cm-2 at 0.5 V) due to the better dispersion and uniform agglomeration on the catalyst layer.

Visual Signal Luminance Analysis and Light Source Color Application Study for Escape Guidance in Underground Common Duct (지하공동구 내 탈출 유도를 위한 비주얼 시그널 휘도 분석 및 광색 적용 연구)

  • Jongmin Lim;Hyojoo Kong;Jinsoo Shin;Sangwuk Shin;Seongsik Yoo
    • Journal of the Society of Disaster Information
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    • v.18 no.4
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    • pp.806-816
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    • 2022
  • Purpose: In this study, the luminance measurement analysis results of the smoke generation state are considered for visual signal display light color for real-time escape guidance in the underground common area. Method: We will analyze the scattering characteristics of light in the atmosphere and optical technology based on the visibility theory, and try to classify the elemental technology as a guidance function through a prototype of a visual signal display device for evacuation guidance. Result: In the experiment conducted under the smoke-generating condition, the results were derived with low luminance ratio and good visibility in the order of red, green, and yellow. However, this result is different from general lighting in which color rendering is considered, and is limited to signals for signals and detection. Conclusion: A conclusions were drawn by reflecting both the luminance measurement results in the smoke generation situation and the preference survey results conducted in previous studies for the light color of the visual signal for signal and detection. When events such as smoke occur, it is better to use the escape guidance visual signal in red or green.