• Title/Summary/Keyword: layered structure

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Small Polaron Hopping Conduction of n=3 Ruddlesden-Popper Compound La2.1Sr1.9Mn3O10 System (II) (n=3인 Ruddlesden-Popper형 La2.1Sr1.9Mn3O10 세라믹스의 Small polaron Hopping 전도 (II))

  • Jung, Woo-Hwan;Lee, Joon-Hyung;Sohn, Jeong-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.878-883
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    • 2002
  • Electrical resistivity and thermoelectric power measurements on Mn-based $La_{2.1}Sr_{1.9}Mn_3O_{10}$ with layered perovskite structure as functions of temperature are presented. The experimental results demonstrate that the electronic transport in $La_{2.1}Sr_{1.9}Mn_3O_{10}$ is well described by the Emin-Holstein adiabatic small polaron model. The thermoelectric power data in the small polaron regime above Curie temperature is nearly equal to that predicted by nominal $Mn^{4+}$ valence arguments. This indicates that transport involves small polaron hopping.

A Study on the Composition of Spaces and Forms in Residential Architecture by Gwathmey Siegel - Focused on Single family House Projects - (과쓰미 씨걸의 주거건축에서 보여지는 공간 및 형태의 입체적 구성에 관한 연구 - 단독주택 작품들을 중심으로 -)

  • John, Yong-Seok
    • Korean Institute of Interior Design Journal
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    • v.21 no.3
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    • pp.95-102
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    • 2012
  • The purpose of this study is to analyze characteristics of residential architecture designed by Gwathmey Siegel in terms of their way of composing spaces and forms. Charles Gwathmey, one of the founders of Gwathmey Siegel, is a worldly famous architect who actively developed Neo-Modernistic architecture in his career. For this study, 15 major houses designed by Gwathmey Siegel were selected and analyzed in terms of their approaches on how to compose various spaces and forms, and how these approaches evolved as time passed. The analysis was mainly based on the drawings and photos of the houses published. The main characteristics found in this study can be summarized as follows: elevated LDK level, split-level composition, use of framing structure, layered space, and linear galleries as a spine of circulation with collaged volumes attached. It turned out these characteristics appeared, faded away, or evolved affecting each other. In early days, Gwathmey often elevated LDK level from ground level for providing privacy, views, and also for separating private rooms. Soon they composed spaces by splitting levels. It not only helped provide privacy where needed effectively, but made space composition more interesting. As sizes of the houses they designed grew, Gwathmey came up with the framing idea for expressing his original architectural language in larger scale. With the split-level composition, the framing method represented Gwathmey's in 70's. This framing introduced layers of interior spaces, and the layers started to break down the monumental framing into individual volumes by bringing in linear spine of circulation. These characteristics helped Gwathmey Siegel develop their own architectural language.

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An Interpretation of the Cultural Landscape by Using Adjectives on Place Memory of Local People (장소기억을 통한 문화경관의 층위 해석 - 형용사를 사용하여 -)

  • Park, Jaemin;Kim, Moohan
    • Journal of the Korean Institute of Landscape Architecture
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    • v.42 no.2
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    • pp.10-18
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    • 2014
  • This paper interprets the hidden structure, layers and figures into cultural landscape, invisible landscape, by using landscape adjectives based on Place Memory of locals. Methods for obtaining local landscape information are through semi-standardized interview and autobiographical questionnaires. As a research site, Janghang in Korea which have experienced not only colonized and autonomous industrialization but also de-industrialization is a typical modern industrial landscape even in Asia. Thus, the landscape is interpreted as layered images like a stratum and as a dynamic landscape that changes over time. People only remember selected memories such as regional and national images affected from industrial developing paradigm in Korea. Some images of the landscape are distorted by powers and influenced by places of memory. This study brings us some discussions that 'What do we look at and remember about the landscape?'

Development of Pressure Sensor for Identifying Guinea Pig's Large Intestinal Motility Caused by Drug (약물 투여에 따른 기니피그 대장 운동 측정을 위한 압력센서 개발)

  • Park, Jae-Soon;Park, Jung-Ho;Kim, Eung-Bo;Cho, Sung-Hwan;Jang, Su-Jeong;Joung, Yeun-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.23-29
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    • 2016
  • In this paper, in order to quantify the peristalsis occurrence in a guinea pig's large intestine, a miniaturized air-gap capacitive pressure sensor was fabricated through micro-electro-mechanical system (MEMS). The proposed pressure sensor is a two-layered biocompatible polyimide substrate consisting of an air-gap capacitive plates between the substrates. The proposed pressure sensor was designed with a careful consideration of the structure and motility mechanism of the guinea pig's large intestine. Artificial pellets were mounted on a prototype pressure sensor to provide some redundancies in the form of size and shape of the guinea pig feces. Capacitance of a prototype sensor was recorded to be 2.5 ~ 3 pF. This capacitance value was later converted to count value using a lab fabricated data conversion system. Sensitivity of the pressure sensor was recorded to be below 1 mmHg per atmospheric pressure. During in vivo testing, artificial peristalsis caused by drug injection was measured by inserting the prototype pressure sensor into the guinea pig's large intestine and pressure data obtained due to artificial peristalsis was graphed using a labview program. The proposed pressure sensor could measure the pressure changes in the proximal, medial, and distal parts of the large intestine. The results of the experiment confirmed that pressure changes of guinea pig's large intestine was proportional to the degree of drug injection.

Design, fabrication and characterization of a flap valve mircopump using an ionic polymer-metal composite actuator (이온성 폴리머-금속 복합재료 작동층을 사용한 플랩 밸브 마이크로 펌프의 설계, 개발 및 특성 규명)

  • Nguyen, Thanh Tung;Nguyen, Vinh Khanh;Yoo, Young-Tai;Goo, Nam-Seo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.4
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    • pp.302-307
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    • 2007
  • In this paper, a flap valve micropump with an ionic polymer-metal composite (IPMC) actuator was designed, fabricated, and experimentally characterized. A multilayered IPMC based on Nafion/layered silicate and Nafion/silica nanocomposites was fabricated for the actuation section of the micropump. The IPMC diaphragm, a key element of the mircopump, was designed so that the IPMC actuator was supported by a flexible polydimethylsiloxane (PDMS) structure at its perimeter. This design feature enabled a significantly high displacement of the IPMC diaphragm. The overall size of the micropump is $20{\times}20{\times}5$ ${mm}^3$. Water flow rates of up to 760 ${\mu}l$/min and a maximum backpressure of 1.5 kPa were recorded. A significant advantage of the proposed micropump is its low driven voltage from only 1-3 V. In addition, a simple and effective design, and an ease of manufacturing are other advantages of the present micropump.

Ferroelectric properties of $Y_2O_3$ and $MnO_2$ doped $SrBi_2Nb_2O_9$ ceramics ($Y_2O_3$$MnO_2$를 첨가한 $SrBi_2Nb_2O_9$ 세라믹스의 강유전 특성)

  • Suk, Jong-Min;Lee, Yong-Hyun;Noh, Jong-Ho;Cho, Jeong-Ho;Chun, Myoung-Pyo;Kim, Byung-Ik;Ko, Tae-Gyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.346-347
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    • 2006
  • 기계적 품질계수(Qm)를 향상시키기 위해 $Y_2O_3$$MnO_2$를 첨가함에 따른 $SrBi_2Nb_2O_9$ 세라믹스의 강유전 특성을 알아보았다. 합성분말의 입도를 분석 한 결과 $SrBi_2Nb_2O_9$의 경우 781.27nm였고, $Y_2O_3$$MnO_2$를 첨가한 경우 각 각 830.4nm와 981.1nm로 particle size는 증가하였고, 소결 후 소결밀도는 차이가 거의 없었으며, grain size는 $SrBi_2Nb_2O_9$$Y_2O_3$를 첨가했을 경우 $1{\mu}m$이하이며 반면, $MnO_2$를 첨가하였을 때 결정립이 성장하여 $3{\sim}4{\mu}m$로 나타났다. 또한, 모두가 $450^{\circ}C$ 이상의 상전이온도를 갖았다.

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Real-Time XRD Analysis of Polystyrene/Clay Nanocomposites by In-Situ Polymerization (In-situ 중합법에 의한 폴리스티렌/점토 나노복합재료의 실시간 X선 분석)

  • Kim, Jang-Yup;Hwang, Seok-Ho;Hong, Yoo-Seok;Huh, Wan-Soo;Lee, Sang-Won
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.87-90
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    • 2005
  • In this study, we have examined the exfoliation behavior of layered clay during in-situ polymeriztion with styrene by using real-time XRD analysis. The 4C1 beam line at the Pohang Accelerator Laboratory (PAL) was used for this study. Different exfoliation behaviors have been shown to depend on the cation exchange capacity (CEC) of clay and the chemical structure of organic modifiers. For 10A-MMT and 15A-MMT having high CEC, no peak shifts were observed on real-time XRD analysis during polymerization. However, 2$\theta$ for 25A-MMT and VDAC-MMT, each having low CEC’s as well as aromatic benzene moieties and vinyl groups, respectively, decreased as polymerization time increased.

Wavelet Transform Based Doconvolution of Ultrasonic Pulse-Echo Signal (웨이브렛 변환을 이용한 초음파 펄스 에코 신호의 디컨볼루션)

  • Jhang, Kyung-Young;Jang, Hyo-Seong;Park, Byung-Yll;Ha, Job
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.6
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    • pp.511-520
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    • 2000
  • Ultrasonic pulse echo method comes to be difficult to apply to the multi-layered structure with very thin layer, because the echoes from the top and the bottom of the layer are superimposed. We can easily meet this problem when the silicon chip layer in the semiconductor is inspected by a SAM equipment using fairly low frequency lower than 20MHz by which severe attenuation in the epoxy mold compound of packaging material can be overcome. Conventionally, deconvolution technique has been used for the decomposition of superimposed UT signals, however it has disabilities when the waveform of the transmitted signal is distorted according to the propagation. In this paper, the wavelet transform based deconvolution(WTBD) technique is proposed as a new signal processing method that can decompose the superimposed echo signals with superior performances compared to the conventional deconvolution technique. WTBD method uses the wavelet transform in the pre-stage of deconvolution to extract out the common waveform from the transmitted and received signal with distortion. Performances of the proposed method we shown by through computer simulations using model signal with noise and we demonstrated by through experiments for the fabricated semiconductor sample with partial delamination at the top of silicon chip layer.

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Development of Electrode Materials for Li-Ion Batteries and Catalysts for Proton Exchange Membrane Fuel Cells (리튬 이차전지용 전극 및 연료전지 촉매 소재 연구 개발 동향)

  • Yun, Hongkwan;Kim, Dahee;Kim, Chunjoong;Kim, Young-Jin;Min, Ji Ho;Jung, Namgee
    • Ceramist
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    • v.21 no.4
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    • pp.388-405
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    • 2018
  • In this paper, we review about current development of electrode materials for Li-ion batteries and catalysts for fuel cells. We scrutinized various electrode materials for cathode and anode in Li-ion batteries, which include the materials currently being used in the industry and candidates with high energy density. While layered, spinel, olivine, and rock-salt type inorganic electrode materials were introduced as the cathode materials, the Li metal, graphite, Li-alloying metal, and oxide compound have been discussed for the application to the anode materials. In the development of fuel cell catalysts, the catalyst structures classified according to the catalyst composition and surface structure, such as Pt-based metal nanoparticles, non-Pt catalysts, and carbon-based materials, were discussed in detail. Moreover, various support materials used to maximize the active surface area of fuel cell catalysts were explained. New electrode materials and catalysts with both high electrochemical performance and stability can be developed based on the thorough understanding of earlier studied electrode materials and catalysts.

Preparation and Properties of PAA/PHA/Organoclay Nanocomposite (PAA/PHA/Organoclay 나노복합재료의 제조 및 특성)

  • Yoon, Doo-Soo;Choi, Jae-Kon;Jo, Byung-Wook
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.326-332
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    • 2010
  • Nanocomposite films were prepared by blending poly(amic acid)(PAA), poly(o-hydroxyamide)( PHA) and organically modified montmorillonite (OMMT) that has a layered structure. XRD, SEM and TEM were used to study the morphology of PAA/PHA nanocomposites, and DMA, TGA, UTM, LOI and PCFC techniques were used to characterize the mechanical and thermal properties, and flame retardancy of the nanocomposites. TEM images revealed that OMMT layers were well dispersed in the PAA/PHA matrix and showed exfoliation and intercalation behavior. The addition of 3 wt% OMMT to the PAA/PHA blend increased the initial modulus of PAA/ PHA blend to 3.68 GPa that was ca. 48% higher than that of the control PAA/PHA blend. Above 4 wt%, however, both the initial modulus and the tensile strength were found to decrease, which might be due to the aggregation of OMMT in PAA/PHA matrix. When the OMMT content was below 3 wt%, the thermal stability and flame retardancy of the PAA/PHA nanocomposites increased with increasing OMMT content.