• Journal of the Korean Society of Food Science and Nutrition
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• v.17 no.3
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• pp.220-225
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• 1988

Rice and rice flour were stored at $13^{\circ}C$, $23^{\circ}C$ and $38^{\circ}C$ for 6 months and Quality indicator according to the correlation between physicochemical properties and sensory scores, was monitored. rat acidity was the most effective indicator for quality changes during storage and its increasing rate showed 1st-order reaction kinetics. The Arrhenius activation energies were 50,953 KJ/Kmol in rice and 59,750 KJ/Kmol in rice flour. On the basis of relation between the acceptable sensory score(3.0) and fat acidity, shelf-life of rice and rice flour were 378 and 358 days at $13^{\circ}C$ and 163 and 145 days at $23^{\circ}C$, respectively.

• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.429-434
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• 2009

The OH($X^2{\Pi},\;{\nu}$"=0, 1) internal state distributions from the reaction of electronically ground state oxygen atoms with HSi$Cl_3$ were measured using laser-induced fluorescence. The ground-state O$(^3P_J)$ atoms with kinetic energies above the reaction barrier were produced by photolysis of N$O_2$ at 355 nm. The OH product revealed strong vibrational population inversion, P(${\nu}$"=1)/P(${\nu}$"=0) = 4.0 ${\pm}$ 0.6, and rotational distributions in both vibrational states exhibit substantial rotational excitations to the limit of total available energy. However, no preferential populations in either of the two $\Lambda$ doublet states were observed from the micropopulations, which supports a mechanism involving a direct abstraction of hydrogen by the atomic oxygen. It was also found that the collision energy between O and HSi$Cl_3$ is effectively coupled into the excitation of the internal degrees of freedom of the OH product ($$ = 0.62, and $<\;f_{rot}>$ = 0.20). The dynamics appear consistent with expectations for the kinematically constrained reaction which supports the reaction type, heavy + light-heavy $\rightarrow$ heavy-light + heavy (H + LH′ $\rightarrow$ HL + H′). The dynamics of oxygen atom collision with HSi$Cl_3$ are discussed in comparison to those with Si$H_4$.

• Resources Recycling
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• v.17 no.3
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• pp.48-55
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• 2008

Leaching of copper and silver from mobile phone PCBs(printed circuit boards) with nitric acid was performed to investigate the effects of nitric acid concentrations, leaching temperatures, agitation speeds, and pulp densities on the leaching behaviors of Cu and Ag. The leaching rate considerably increased with increasing acid concentration and temperature. The leaching ratios of Cu and Ag were found to be 96.4% and 96.5%, respectively, under the optimum condition; at $80^{\circ}C$ with 2mol/L $HNO_3$ and 120g/L in pulp density within 39minutes. The kinetic parameters were determined based on the shrinking core model with reaction control corresponding to small particles. The activation energies for the leaching of copper and silver were found to be 45.5kJ/mol and 60.5kJ/mol at $35{\sim}80^{\circ}C$ with 2mol/L $HNO_3$, respectively.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.875-879
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• 2008

A method for the depolymerization of polycarbonate waste by glycolysis using ethylene glycol without catalyst was explored in order to get the monomer bisphenol A (BPA). The effect of operation variables such as reaction time, reaction temperature, EG/PC weight ratio and the kinetic of glycolysis were studied. It was found that the polymerization reaction has two different activation energies depending on the reaction temperature. A drop in activation energy with temperature indicates that the reaction mechanism has shifted from one of a succession of elementary steps to another in the series. The maximum yield of BPA of 95.6% was achieved at reaction temperature $220^{\circ}C$ for 85min with EG/PC weight ratio 4.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.15 no.3
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• pp.399-407
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• 2002

A three-dimensional method of analysis is presented for determining the free vibration frequencies and mode shapes of hollow bodies of revolution (i.e., thick shells), not limited to straight line generators or constant thickness. The middle surface of the shell may have arbitrary curvatures, and the wall thickness may vary arbitrarily. Displacement components$U_\Phi, U_z, U_\theta$ in the meridional, normal and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in$\theta$, and algebraic polynomials in the$\Phi$and z directions. Potential(strain) and kinetic energies of the entire body are formulated, and upper bound values of the frequencies are obtained by minimizing the frequencies. As the degrees of the polynomials are increased, frequencies converge to the exact values. Novel numerical results are presented for two types of thick conical shells and thick spherical shell segments having linear thickness variations. Convergence to four digit exactitude is demonstrated for the first five frequencies of both types of shells. The method is applicable to thin shells, as well as thick and very thick ones.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.5
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• pp.405-414
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• 2015

Fluid transport is a key issue in the development of microfluidic systems. Recently, Myong (2014) has proposed a new concept for droplet transport without external power sources and numerically validated the results for a hypothetical 2D, initially having a hemicylindrical droplet. In this paper, the movement of an actual water droplet, initially having a 3D hemispherical shape, on horizontal hydrophilic/hydrophobic surfaces is simulated using a commercial computational fluid dynamics (CFD) package, Fluent, with VOF (volume of fluid) method. The results are compared with the 2D analysis of Myong (2014), and the transport mechanism for the actual water droplet is examined based on the numerical results of the time evolution of the droplet shape, as well as the total kinetic, gravitational, surface free and pressure energies inside the droplet.

• Journal of Korean Association for Spatial Structures
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• v.4 no.4 s.14
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• pp.113-128
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• 2004

A three-dimensional (3-D) method of analysis is presented for determining the free vibration frequencies and mode shapes of solid paraboloidal and complete (that is, without a top opening) paraboloidal shells of revolution with variable wall thickness. Unlike conventional shell theories, which are mathematically two-dimensional (2-D), the present method is based upon the 3-D dynamic equations of elasticity. The ends of the shell may be free or may be subjected to any degree of constraint. Displacement components $u_r,\;u_{\theta},\;and\;u_z$ in the radial, circumferential, and axial directions, respectively, are taken to be sinusoidal in time, periodic in ${\theta}$, and algebraic polynomials in the r and z directions. Potential (strain) and kinetic energies of the paraboloidal shells of revolution are formulated, and the Ritz method is used to solve the eigenvalue problem, thus yielding upper bound values of the frequencies by minimizing the frequencies. As the degree of the polynomials is increased, frequencies converge to the exact values. Convergence to four digit exactitude is demonstrated for the first five frequencies of the complete, shallow and deep paraboloidal shells of revolution with variable thickness. Numerical results are presented for a variety of paraboloidal shells having uniform or variable thickness, and being either shallow or deep. Frequencies for five solid paraboloids of different depth are also given. Comparisons are made between the frequencies from the present 3-D Ritz method and a 2-D thin shell theory.

• Korean Journal of Food Science and Technology
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• v.35 no.4
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• pp.660-665
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• 2003

Effect of freezing on the hydration rate and growth characteristics of bean sprout of two domestic cultivars of soybean, Eunha beans and Taegwang beans, was investigated. Freezing of the soybeans at $-80^{\circ}C$ affected characteristics of the hydration and growth of soybean sprout of the beans. Hydration rate of the frozen beans depended on the hydration temperature. It decreased up to 50% at lower than $60^{\circ}C$ of hydration temperature, but it did not decrease at higher than $60^{\circ}C$. Activation energies of frozen Eunha and Taegwang beans were 39.79 and 39.25 kJ/mol, respectively. Kinetic compensation effect between activation energy values and the pre-exponential factor for the hydration of soybeans with or without freezing was observed. Germination rate and thickness of the bean sprout increased by freezing, however, yield and weight were not affected by freezing.

• Journal of Sensor Science and Technology
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• v.8 no.5
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• pp.388-393
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• 1999

In this study, the $CaSO_4:Eu$ TLDs are fabricated and their trap parameters are determined. The optimum concentration of Eu for fabrication of the $CaSO_4:Eu$ TLD is 0.5 mol% and optimum temperature is $600^{\circ}C$ for 2 hours sintering in air. The glow curve of $CaSO_4:Eu$ consists of two glow peaks and these peaks are isolated by thermal bleaching method. Trap parameters of two glow peaks are measured using the initial rise, the peak shape, the heating rate and the least square curve fitting methods. The activation energies of the glow peak I and II are 1.00 eV and 1.09 eV, and the frequency factors are $7.04{\times}10^{11}\;s^{-1}$ and $5.12{\times}10^{11}\;s^{-1}$ and the kinetic orders are 1.11 and 1.33, respectively.

• Applied Biological Chemistry
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• v.37 no.5
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• pp.414-420
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• 1994

Birnessite, pyrolusite and hausmannite were synthesized and tested for the ability to oxidize Cr(III) to Cr(VI). These oxides differed in zero point of charge, surface area, and crystallinity. The kinetic study showed that Cr(III) oxidation on the Mn-oxide surface is a first-order reaction. The reaction rate was various for different oxide at different conditions. Generally the reaction by hausmannite, containing Mn(III), was faster than the others, and oxidation by pyrolusite was much slower. Solution pH and initial Cr(III) concentration had a significant effect on the reaction. Inhibited oxidation at higher pH and initial Cr(III) concentration could be due to the chance of Cr(III) precipitation or complexing on the oxide surface. Oxidations by birnessite and hausmannite were faster at lower pH, but pyrolusite exhibited increased oxidation capacity at higher pH in the range between 3.0 and 5.0. Reactions were also temperature sensitive. Although calculated activation energies for the oxidation reactions at pH 3.0 were higher than the general activation energy for diffusion, there is no experimental evidence to suggest which reaction is the rate limiting step.