• 제목/요약/키워드: ion Permeability

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Effect of Slag Grade and Cement Source on the Properties of Concrete

  • Becknell, Natalie Peterson;Hale, William Micah
    • International Journal of Concrete Structures and Materials
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    • v.5 no.2
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    • pp.119-123
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    • 2011
  • Presented in the paper are findings of a project that examined the effect of slag grade and cement source on the performance of concrete mixtures. Slag cement contents were 20, 40, and 60 percent of the total cementitious material content. Two grades of slag cement were examined (Gr. 100 and Gr. 120) along with two sources of Type I cement. Compressive strength, durability, and permeability were measured. The results showed that the cement source affected the early age strength of the mixtures. At 28 days of age, mixtures containing Gr. 120 slag cement had higher compressive strengths than mixtures containing Gr. 100 slag cement, but by 90 days of age, the trend reversed. As for the chloride ion penetrability, mixtures cast with Gr. 100 slag cement passed fewer coulombs at 28 and 90 days of age than similar mixtures containing Gr. 120 slag. Mixtures containing Gr. 120 slag had the greatest durability factors.

The Effects of Non-Stoichiometry and Sintering Temperature on the Magnetic Properties of Ni-Zn Ferrites (비양론 화학적 조성 및 소결온도가 Ni-Zn Ferrite 의 자기적 성질에 미치는 영향)

  • 박준철;임호빈
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.89-95
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    • 1980
  • The effect of non-stoichimetry and sintering temperature on the magnetic properties of materials in the system $Ni_{0.39}Zn_{0.61}Fe_{2.0+x}O_4$ have been investigated. The value of x used in initial weighing of oxides were varied from -0.04 to -0.12. The value of x, however, appears to be from +0.04 to -0.04 after ferrite powder preparation due to iron pick up during ball mill mixing and grinding. The densities of specimens which were deficientinrion were higher than those with excess ion. Specimens with near stoichiometric composition showed maximum initial permeability an dminimum coercivity whereas high values of quality factor (Q) were observed in iron deficient specimens. The quality factor decreased monotonically with increasing sintering temperature, but the permeability showed maxima with increasing sintering temperature. Thus highest value of figure of merit $\mu$Q was obtained in composition $Ni_{0.39}Zn_{0.61}Fe_{1.98O4}$ sintered at 100$0^{\circ}C$ for 3 hrs. in an air atmosphere.

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Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
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    • v.43 no.3
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

Preparation of Ion Exchange Membranes for Fuel Cell Based on Crosslinked Poly(vinyl alcohol) with Poly(acrylic acid-co-maleic acid)

  • Kim, Dae-Sik;Park, Ho-Bum;Lee, Chang-Hyun;Lee, Young-Moo;Moon, Go-Young;Nam, Sang-Yong;Hwang, Ho-Sang;Yun, Tae-II;Rhim, Ji-Won
    • Macromolecular Research
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    • v.13 no.4
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    • pp.314-320
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    • 2005
  • Crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at various crosslinking temperatures using poly(acrylic acid-co-maleic acid) (PAM) containing different PAM contents. The thermal properties of these PVA/PAM membranes prepared at various reaction temperatures were characterized using differential scanning calorimetry (DSC). The proton conductivity and methanol permeability of PVA/PAM membranes were then investigated as PAM content was varied from 3 to 13 wt%. It was found that the proton and methanol transport were dependent on PAM content in their function both as crosslinking agent and as donor of hydrophilic -COOH groups. Both these properties decreased monotonously with increasing PAM concentration. The proton conductivities of these PVA/PAM membranes were in the range from $10^{-3}\;to\;10^{-2}S/cm$ and the methanol permeabilities from $10^{-7}\;to\;10^{-6}cm^{2}/sec$. In addition, the effect of operating temperature up to $80^{\circ}C$ on ion conductivity was examined for three selected membranes: 7, 9 and 11 wt% PAM membranes. Ion conductivity increased with increasing operating temperature and showed and S/cm at $80^{\circ}C$, respectively. The effects of crosslinking and ionomer group concentration were also examined in terms of water content, ion exchange capacity (IEC), and fixed ion concentration. In addition, the number of water molecules per ionomer site was calculated using both water contents and IEC values. With overall consideration for all the properties measured in this study, $7{\sim}9\;wt%$ PAM membrane prepared at $140^{\circ}C$ exhibited the best performance. These characteristics of PVA/PAM membranes are desirable in applications related to the direct methanol fuel cell (DMFC).

A Study for Development and Actual Application of High Durability Concrete (고내구성 콘크리트 개발 및 실용화 연구)

  • 오병환;정원기;강승희;장봉석;조윤구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.155-158
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    • 1995
  • High durabitiy concrete increasingly sutudied in various countries. This report presents the data on durability related properties such as the chloride ion permeability, the resistance to freezing-thawing, the corrosion of steel and the resistance attack. To promote the actual application of high durability concrete, several series of high durability concrete have been made and applied to actual structures.

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Separation of Organic Liquid Mixtures using Plasma Membrane (플라즈마 멤브레인을 이용한 유기용매 혼합을 분리)

  • 김성오;박복기;김두석;박진교;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.642-644
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    • 1999
  • We have prepared the plasma-polymerized membrane for pervaporation of organic-liquid mixtures by the plasma polymerization technique. Plasma polymerization techniques were utilized in the development of hydrophilic composite membranes having high hydrogen ion permeability and excellent dimensional stability. To develop an organic liquid permselective Membrane, suppressing membrane swearing as well as enhancing the solubility difference is impotant. the objectives of the present study are to disign a suitable membrane for an organic-mixture system by the control of the plasma-polymer solubility.

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Study of Fundamental Properties of Latex-Modified Concrete Using Blast-furnace Slag (고로(高爐)슬래그 미분말(微粉末)을 사용(使用)한 라텍스개질(改質) 콘크리트의 기초물성(基礎物性) 연구(硏究))

  • Hong, Chang-Woo;Jeong, Won-Kyong;Kim, Kyeong-Jin
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.10-17
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    • 2006
  • The purpose of this study was to evaluate the effects of blast-furnace slag on strength development and durability of latex-modified concrete (LMC) and ordinary portland cement concrete as slag contents. Main experimental variables were performed latex contents (0%, 10%, 15%) and slag contents (0%, 30%). The compressive and flexural strengths, chloride-ion rapid permeability and chemical attacks resistance were measured to analyze the characteristic of the developed LMC and BS-LMC(latex-modified concrete added blast-furnace slag) on hardened concrete. The test results showed that compressive and flexural strength of BS-LMC increased as the slag contents increased from 0% to 30% at the long term of curing. It considers blast furnace slag used when latex content was up to 10%. The permeability resistance of BS-LMC(latex 10%, blast 30%) was extremely good at the curing time 90 days. Also. the effects of added blast furnace slag on OPC and LMC were increased on the permeability and chemical attacks resistance.

An Experimental Study on Ternary System Concrete Using Blast-furnace Slag and Fly-ash (고로(高爐)슬래그 미분말(微粉末)과 플라이애쉬를 이용(利用)한 3성분계(性分系) 콘크리트의 기초물성(基礎物性)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Hwa-Joong;Hong, Chang-Woo;Kim, Kyeong-Jin
    • Resources Recycling
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    • v.18 no.4
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    • pp.31-37
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    • 2009
  • The purpose of this study was to evaluate the effects of fly-ash and blast-furnace slag on strength development and durability of ternary blended concrete (TBC) and ordinary portland cement concrete as fly ash and slag contents. Main experimental variables were performed fly ash contents (0%, 10%) and slag contents (0%, 10%, 20%, 30%). The compressive and flexural strengths, chloride-ion rapid permeability and chemical attacks resistance were measured to analyze the characteristic of the developed TBC on hardened concrete. The test results showed that compressive and flexural strength of TBC increased as the slag contents increased from 0% to 30% at the long term of curing. It considers blast furnace slag used when fly ash content was up to 10%. The permeability resistance of TBC(fly ash 10%, blast 30%) was extremely good at the curing time 90 days. Also, the effects of added blast furnace slag on OPC and TBC were increased on the permeability and chemical attacks resistance.

Development and Characterization of Polymer Electrolyte Membranes Containing Polysilsesquioxane Spheres (Polysilsesquioxane 구를 함유하는 고분자 전해질 막 제조 및 특성 연구)

  • Hong Seong Uk;Cheon Hun Sang;Kim Young Baik;Park Hun Hwee
    • Membrane Journal
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    • v.15 no.1
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    • pp.1-7
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    • 2005
  • Polymer electrolyte membranes containing polysilsesquioxane (PSQ) spheres were prepared with the blend of sulfonated poly(ether ether ketone) (SPEEK) (60%) and poly(ether sulfone) (PES) (40%). The amount of PSQ spheres was fixed at 10 wt%. The prepared polymer electrolyte membranes were characterized in terms of methanol permeability, proton conductivity, and ion exchange capacity. In all cases, both methanol permeability and proton conductivity of the polymer electrolyte membranes containing PSQ spheres were lower than the values of Nafion 117 and higher than those of SPEEK/PES (6:4) blend without PSQ spheres. The experimental results indicated that the polymer electrolyte membranes containing MS64 and VTMOS spheres were the best choice in terms of the ratio of proton conductivity to methanol permeability.