• Title/Summary/Keyword: inversion layer

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Study on the Removal of Water Vapor Using PEI/PEBAX Composite Hollow Fiber Membrane (PEI/PEBAX 복합 중공사 막을 이용한 수분 제거에 관한 연구)

  • Park, Chun-Dong;Hyung, Chan-Heui;Kim, Kee-Hong;Choi, Won-Kil;Park, Yeong-Seong;Lee, Hyung-Keun
    • Membrane Journal
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    • v.23 no.2
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    • pp.119-128
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    • 2013
  • In this research, PEI/PEBAX composite hollow fiber membrane was used for the removal of water vapor from gases. PEI (Polyetherimide) substrate membrane was spinned by dry-wet phase inversion method and coated with PEBAX (Polyether block amides) 3533 and PEBAX1657. Fabricated fibers typically had an asymmetric structure of a dense top layer supported by a sponge-like substructure through scanning electron microscopy (SEM). $H_2O/N_2$ mixture gas was used to compare the performance of separation according to temperature, pressure and water activity. The results of PEBAX3533 and PEBAX1657 composite membranes respectively showed $H_2O/N_2$ selectivity of 61.7~118.5 and 85.3~175.4 according to operating conditions. PEBAX3533 composite hollow fiber membranes module showed the water vapor removal of 90%.

증착조건에 따른 $ZrO_2$ 게이트 유전막의 특성

  • 유정호;남석우;고대홍
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.106-106
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    • 2000
  • 반도체 소자가 미세화 됨에 따라 게이트 유전막으로 사용되는 SiO2의 박막화가 요구되나, boron penetration에 의한 Vt shift, 게이트 누설전류, 다결정 실리콘 게이트의 depletion effect 그리고 quantum mechanical effect 때문에 ~20 급에서 한계를 나타내고 있다. 이에 0.1$\mu\textrm{m}$이상의 design rule을 갖는 logic이나 memory 소자에서 요구되어지는 ~10 급 게이트 산화막은 SiO2(K=3.9)를 대신하여 고유전율을 갖는 재료의 채택이 필수 불가결하게 되었다. 고유전 박막 재료를 사용하면, 두께를 두껍게 해도 동일한 inversion 특성이 유지되고 carrier tunneling 이 덜하여 등가 산화막의 두께를 줄일 수 있다. 이러한 고유전박막 재료중 가장 활발히 연구되고 있는 재료는 Ta2O5, Al2O3, STO 그리고 BST 등이 있으나 Ta2O5, STO, BST 등은 실리콘 기판과 직접 반응을 한다는 문제를 가지고 있으며, Al2O3는 유전율이 낮의 재료가 최근 주목받고 있다. 본 실험에서는 ZrO2, HfO2 또는 그 silicates 등의 재료가 최근 주목 받고 있다. 본 실험에서는 ZrO2 박막의 증착조건에 따른 물리적, 전기적 특성 변화에 대하여 연구하였다. RCA 방식으로 세정한 P-type (100) 실리콘 기판위에 reactive DC sputtering 방법으로 압력 5mtorr, power 100~400W, 기판온도는 100-50$0^{\circ}C$로 변화시켜 ZrO2 박막을 증착한 후 산소와 아르곤 분위기에서 400-80$0^{\circ}C$, 10-120min으로 열처리하였다. 증착직후의 시편들과 열처리한 ZrO2 박막의 미세구조와 전기적 특성 변화를 관찰하였다. 우선 굴절율(RI)를 이용해 ZrO2 박막의 밀도를 예측하여 power와 기판온도에 따라 이론값 2.0-2.2 에 근접한 구조를 얻은 후 XRD, XPS, AFM, 그리고 TEM을 사용하여 ZrO2 박막의 chemical bonding, surface roughness 그리고 interfacial layer의 특성을 관찰하였다. 그리고 C-V, I-V measurement를 이용해 capacitance, 유전율, 누설전류 등의 전기적 특성을 관찰해 최적 조건을 설정하였다.

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Pervaporation Separation of Water-isopropanol Mixtures Through Modified Asymmetric Polyetherimide membranes: the Effect of NaOH Concentration for the Modification of Skin Layers on the Pervaporation Characteristics (개질 비대칭 폴리에테르이미드막을 통한 물-이소프로판올 혼합물의 투과증발 분리: 투과증발 특성에 미치는 표면층 개질에 사용된 NaOH 농도의 영향)

  • Kim, Sang-Gyun;Jegal, Jonggeon;Lee, Kew-Ho
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.319-323
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    • 1999
  • Asymmetric polyetherimide membranes were prepared by phase inversion method. In the modification of the skin layers of polyetherimide membranes, the effects of NaOH concentration on the morphology and pervaporation separation of water-isopropanol mixtures were investigated. With increasing concentration of NaOH solution, polyamicacid structure was formed by the hydrolysis of imide group of polyetherimide, and the thickness of dense layer of the asymmetric membrane increased. In the pervaporation separation of water-isopropanol mixtures the overall permeation rate decreased and the separation factor increased with increasing concentration of NaOH solution. However, when the concentration of NaOH solution was very high, the permeation rate increased but separation factor decreased. From these results, it was found that the permeation behaviors of asymmetric polyetherimide membranes depended upon the concentration of NaOH solution. These modified membranes showed that both the permeation rate and separation factor increased as the operating temperature increased.

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Case History for Safe Diagnosis of Embankment Dike using Composite Analysis of Various Geophysical surveys (물리탐사 결과 복합해석을 통한 방조제 제체 정밀안전진단 사례)

  • Song, Sung-Ho;Seong, Baek-Uk;Kim, Young-Gyu;Kang, Mi-Kyung;Lee, Gyu-Sang;Kim, Yang-Bin
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.107-112
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    • 2007
  • To establish the reinforce region and technique through the embankment dike after identifying the region of seawater inflow, we carried out small-loop electromagnetic (EM) survey, electrical resistivity survey and refraction seismic method. We also analyzed the distribution of electrical conductivity in reservoir with depth every two month and monitored water level variations with tidal variation in four observation wells located at seaside and reservoir side in order to analyze the relationship with survey results. From both the cross-correlation between tidal and water level variation at four wells and the distribution of electrical conductivity in reservoir with depth, the major portion of seawater inflow are identified through the embankment dike. From electromagnetic and electrical resistivity survey results, it was found that the seawater inflow were happened through several small regions at seaside and became wider near reservoir side. The 2-D inversion sections of refraction seismic method showed that the pebble-bearing sand layer is spread over the whole region with two to four width. From the this study, small-loop EM, electrical resistivity and refraction seismic surveys accompany with the distribution of electrical conductivity in reservoir with depth and the monitoring results for water level variations are revealed to be effective to identify seawater inflow pathway through embankment dike and to establish the reinforce region and technique through the embankment dike.

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PVDF/h-BN hybrid membranes and their application in desalination through AGMD

  • Moradi, Rasoul;Shariaty-Niassar, Mojtaba;Pourkhalili, Nazila;Mehrizadeh, Masoud;Niknafs, Hassan
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.221-231
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    • 2018
  • A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.

Theoretical Modeling of Surface Wave Propagation for SASW Testing Method (수중 주파수영역표면파괴기법의 역해석 과정에서 적용되는 파동해석기법)

  • Lee, Byung-Sik
    • Journal of the Korean Geophysical Society
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    • v.3 no.4
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    • pp.251-260
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    • 2000
  • Applicabilities of two numerical methods, the 2-dimensional and the 3-dimensional method, are evaluated to inverse test results obtained from the underwater SASW(Spectral -Analysis-of-Surface-Waves) method. As a result of this study, it has been found that the 2-dimensional method can supposed to be applicable for the cases where stiffness of soil layer increases gradually with depth, and the stiffness is relatively low. For the other cases, however, it has been concluded that the 3-dimensional method needs to be applied to determine realistic theoretical dispersion curves. An example is also shown that in situ soil profile underwater is estimated from experimental dispersion curves using the 3-dimensional method. As a results, it can be concluded that the underwater SASW method can be effectively applied to explore the underwater soil condition.

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Drain Induced Barrier Lowering(DIBL) SPICE Model for Sub-10 nm Low Doped Double Gate MOSFET (10 nm 이하 저도핑 DGMOSFET의 SPICE용 DIBL 모델)

  • Jung, Hakkee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.8
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    • pp.1465-1470
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    • 2017
  • In conventional MOSFETs, the silicon thickness is always larger than inversion layer, so that the drain induced barrier lowering (DIBL) is expressed as a function of oxide thickness and channel length regardless of silicon thickness. However, since the silicon thickness is fully depleted in the sub-10 nm low doped double gate (DG) MOSFET, the conventional SPICE model for DIBL is no longer available. Therefore, we propose a novel DIBL SPICE model for DGMOSFETs. In order to analyze this, a thermionic emission and the tunneling current was obtained by the potential and WKB approximation. As a result, it was found that the DIBL was proportional to the sum of the top and bottom oxide thicknesses and the square of the silicon thickness, and inversely proportional to the third power of the channel length. Particularly, static feedback coefficient of SPICE parameter can be used between 1 and 2 as a reasonable parameter.

Gangwon Yeongdong Wind Experiments (G-WEX) Pilot Study: Downslope windstorms in the Taebaek Mountains, South Korea (강원영동 강풍 관측설계와 예비 관측결과)

  • Kim, Ji-Eun;Kwon, Tae-Yong;Park, Gyun-Myeong;Han, Youn-Deok;Shin, Dong-Hyun
    • Atmosphere
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    • v.31 no.4
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    • pp.361-376
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    • 2021
  • "Gangwon Yeongdong Wind Experiments (G-WEX) Pilot Study: Downslope windstorms in the Taebaek Mountains, South Korea" is promoted based on joint organization by Gangwon Regional Office of Meteorology and National Institute of Meteorological Research and participation by 12 institutions to understand the mechanism in development of Yeongdong wind phenomena. The special observation (G-WEX) involved total of 5 intensive observations in March 2020 and April 2020. To collect the data necessary for the research on Yeongdong wind phenomena, (1) high-resolution surface observation network was used to examine surface wind and (2) atmospheric soundings were observed by using Rawinsonde, Wind profiler, Wind Lidar, and Drone. This study covers the detailed information on the special observational experiments for downslope windstorms in the leeward of the Taebaek Mountains, named as the Yeongdong wind, including the observational strategies, experimental designs, and pilot studies during the Intensified Observing Period (IOPs). According to 2020 G-WEX observation results, downslope windstorms were observed in 2~3 km of upper atmosphere when the strong winds happened around the top of the mountain near Daegwallyeong. Also, dry adiabatic expansion related to downslope windstorms caused temperature rise and led to formation of an inversion layer in altitude below 2.5 km. Bands of strong wind were located right under the altitude where downslope windstorms are observed with temporal rise of the temperature. As these are preliminary observation results, there needs to be continuous related researches and high-resolution weather observation.

Comparative Investigation of Interfacial Characteristics between HfO2/Al2O3 and Al2O3/HfO2 Dielectrics on AlN/p-Ge Structure

  • Kim, Hogyoung;Yun, Hee Ju;Choi, Seok;Choi, Byung Joon
    • Korean Journal of Materials Research
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    • v.29 no.8
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    • pp.463-468
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    • 2019
  • The electrical and interfacial properties of $HfO_2/Al_2O_3$ and $Al_2O_3/HfO_2$ dielectrics on AlN/p-Ge interface prepared by thermal atomic layer deposition are investigated by capacitance-voltage(C-V) and current-voltage(I-V) measurements. In the C-V measurements, humps related to mid-gap states are observed when the ac frequency is below 100 kHz, revealing lower mid-gap states for the $HfO_2/Al_2O_3$ sample. Higher frequency dispersion in the inversion region is observed for the $Al_2O_3/HfO_2$ sample, indicating the presence of slow interface states A higher interface trap density calculated from the high-low frequency method is observed for the $Al_2O_3/HfO_2$ sample. The parallel conductance method, applied to the accumulation region, shows border traps at 0.3~0.32 eV for the $Al_2O_3/HfO_2$ sample, which are not observed for the $Al_2O_3/HfO_2$ sample. I-V measurements show a reduction of leakage current of about three orders of magnitude for the $HfO_2/Al_2O_3$ sample. Using the Fowler-Nordheim emission, the barrier height is calculated and found to be about 1.08 eV for the $HfO_2/Al_2O_3$ sample. Based on these results, it is suggested that $HfO_2/Al_2O_3$ is a better dielectric stack than $Al_2O_3/HfO_2$ on AlN/p-Ge interface.

Characteristics of Sea Breezes at Coastal Area in Boseong (보성 해안 지역에서의 해풍 특성)

  • Lim, Hee-Jeong;Lee, Young-Hee
    • Atmosphere
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    • v.29 no.1
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    • pp.41-51
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    • 2019
  • The characteristics of the sea breeze were investigated using the wind and temperature data collected from 300-m tower at Boseong from May 2014 to April 2018. Sea breeze day was detected using following criteria: 1) the presence of a clear change in wind direction near sunrise (between 1 hour after sunrise and 5 hours before sunset) and sunset (from 1500 LST to midnight), 2) presence of thermal forcing of sea breeze and 3) no heavy precipitation (rain < $10mm\;d^{-1}$). Sea breeze days occurred on 569 days for 4 years. The monthly distribution of sea breeze day occurrence shows maxima in May and September and minimum in December. The average onset and cessation times of the sea breeze are 0942 LST and 1802 LST, respectively. Although the 10-m wind shows clockwise rotation with time in the afternoon, the observed hodograph does not show an ideal elliptical shape and has different characteristics depending on the upper synoptic wind direction. Vertical structure of sea breeze shows local maximum of wind speed and local minimum of virtual potential temperature at 40 m in the afternoon for most synoptic conditions except for southeasterly synoptic wind ($60^{\circ}{\sim}150^{\circ}$) which is in the same direction as onshore flow. The local minimum of temperature is due to cold advection by sea breeze. During daytime, the intensity of inversion layer above 40 m is strongest in westerly synoptic wind ($240^{\circ}{\sim}330^{\circ}$) which is in the opposite direction to onshore flow.