• Title/Summary/Keyword: internal electrode

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Application of Ag-Ceramic Composite Electrodes to Piezoelectric Multilayer Ceramic Actuators (적층형 압전 세라믹 액추에이터에 대한 Ag-세라믹 복합소재 전극의 응용)

  • Kim, Sung-Hoon;Lee, Yong-Hui;Cho, Sung-Youl;Choi, Mun-Seok;Lee, Jae-Shin;Kim, Ill-Won;Jeong, Soon-Jong;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.331-332
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    • 2006
  • Ag-ceramic composite materials were investigated as internal electrodes for multilayer ceramic actuators (MLCA). Ag-ceramic pastes were prepared by adding PZT-based ceramic powders to a Ag patse in a range of 0 to 50 wt.%. PZT/Ag-PZT multilayered laminates were fabricated by tape casting and fired at low temperatures below $950^{\circ}C$. The addition of ceramic into the Ag electrode resulted in a decrease in the thermal expansion mismatch between the electrode and the ceramic sheet. The maximum strain of PZT/Ag-PZT multilayered actuators were $9{\times}10^{-4}$ under an electric field of 2.5MV/m. In conclusion, Ag-PZT composite materials are efficient for low cost piezoelectric MLCAs.

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Fatigue Characteristics of PZT Thin Films Deposited by ECR-PECVD

  • Chung, Su-Ock;Lee, Won-Jong
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.177-185
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    • 2005
  • Fatigue characteristics of lead zirconate titanate (PZT) films deposited by electron cyclotron resonance plasma enhanced chemical vapor deposition (ECR-PECVD) were investigated. The fatigue characteristics were investigated with respect to PZT film thickness, domain structure, fatigue pulse height, temperature, electrode materials and electrode configurations. The used top and bottom electrode materials were Pt and $RuO_2$. In the fatigue characteristics with fatigue pulse height and PZT film thickness, the fatigue rates are independent of the applied fatigue pulse height at the electric field regions to saturate the P-E hysteresis and polarization $(P^*,\;P^A)$ characteristics. The unipolar and bipolar fatigue characteristics of PZT capacitors with four different electrode configurations $(Pt//Pt,\;Pt//RuO_2,\;RuO_2//Pt,\;and\;RuO_2//RuO_2)$ were also investigated. The polarization-shifts during the unipolar fatigue and the temperature dependence of fatigue rate suggest that the migration of charged defects should not be expected in our CVD-PZT films. It seems that the polarization degradations are attributed to the formation of charged defects only at the Pt/PZT interface during the domain switching. The charged defects pin the domain wall at the vicinity of Pt/PZT interface. When the top and bottom electrode configurations are of asymmetric $(Pt//RuO_2,\;RuO_2//Pt)$, the internal fields can be generated by the difference of charged defect densities between top and bottom interfaces.

Fabrication of Nano-Channeled Tin Oxide Film Electrode and Evaluation of Its Electrochemical Properties (나노 채널 구조를 가진 산화 주석 박막 전극 제조 및 전기화학적 특성 평가)

  • Park, Su-Jin;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.1-7
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    • 2012
  • Thin film electrode consisting purely of porous anodic tin oxide with well-defined nano-channeled structure was fabricated for the first time and its electrochemical properties were investigated for application to an anode in a rechargeable lithium battery. To prepare the thin film electrode, first, a bi-layer of porous anodic tin oxides with well-defined nano-channels and discrete nano-channels with lots of lateral micro-cracks was prepared by pulsed and continuous anodization processes, respectively. Subsequent to the Cu coating on the layer, well-defined nano-channeled tin oxide was mechanically separated from the specimen, leading to an electrode comprised of porous tin oxide and a Cu current collector. The porous tin oxide nearly maintained its initial nano-structured character in spite of there being a series of fabrication steps. The resulting tin oxide film electrode reacted reversibly with lithium as an anode in a rechargeable lithium battery. Moreover, the tin oxide showed far more enhanced cycling stability than that of powders obtained from anodic tin oxides, strongly indicating that this thin film electrode is mechanically more stable against cycling-induced internal stress. In spite of the enhanced cycling stability, however, the reduction in the initial irreversible capacity and additional improvement of cycling stability are still needed to allow for practical use.

Electrochemical Properties of Platinized Counter Electrode on based Stainless Steel Sheet for Dye-Sensitized Solar Cells (SUS 기판을 이용한 염료감응형 태양전지용 백금 상대전극의 전기화학적 특성)

  • Park, Kyung-Hee;Kim, Tae-Young;Back, Hyung-Ryul;Gu, Hal-Bon;Kim, Seung-Jai;Cho, Sung-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.262-263
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    • 2005
  • Pt counter electrode based on flexible metal for dye-sensitized solar cells(DSCs) has been investigated. Photovoltaic structures on lightweight substrates have several advantages over the heavy glass-based structures in both terrestrial and space applications. Cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of Pt counter electrode both FTO glass and SUS sheet substrate. The DSCs composed of the counter electrode based on a stainless steel substrate has obtained conversion efficiencies comparable to that based on the conducting glass. The counter electrode based on the stainless steel substrate has the merit of improving the fill factor and conversion efficiency of the DSCs by reducing its internal resistance.

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Piezoelectric Properties of PZW-PMN-PZT Low Loss Multilayer Actuator according to the Number of Multilayer using Pure Ag Internal Electrode (순수한 Ag 내부전극을 사용한 PZW-PMN-PZT 저손실 적층 액츄에이터의 적층수에 따른 압전 특성)

  • Yoo, Ju-Hyun;Lee, Kab-Soo;Lee, Il-Ha
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.524-529
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    • 2008
  • In this paper, in order to develop low loss multilayer actuator, piezoelectric properties of PZW-PMN-PZT multilayer actuator sintered at $900^{\circ}C$ low temperature were investigated according to the number of multilayer. The multilayer actuator was fabricated using tape casting method and used pure Ag internal electrode. The density above $8.0\;g/cm^3$ was obtained at all specimens. With increasing number of multilayer, effective electromechanical coupling factor($k_{eff}$) was increased. $k_{eff}$ of multilayer actuator shows the maximum value of 0.283 at 11 layers actuator. However, effective mechanical quality factor(Qm') was decreased according to the increase of number of multilayer. The Qm' of multilayer actuator showed the maximum value of 920 at 5 layers actuator.

The characteristics of Silent discharge using RF power source (고주파 전원인가에 의한 무성방전 특성에 관한 연구)

  • Lee, Sang-Keun;Lee, Dong-Wook;Chun, Byung-Joon;Song, Hyun-Jig;Lee, Kwang-Sik;Kwon, Hyuk-Han
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.570-572
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    • 2000
  • The characteristics of ozone generation were investigated in accordance with varying the diameter of internal electrode in an ozonizer using RF power source. The characteristics of ozone generation were improved with the diameter of internal electrode increased, but thermal loss was increased. Therefore, it was found that it is inevitable that the cooler has to be installed in an ozonizer which uses RF power source.

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2-D Model Analysis on the Multilayer Piezoelectric Ceramic Actuators (적층 압전세라믹 액츄에이터의 2차원모델 해석에 관한 연구)

  • 홍재일;류주현;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.307-310
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    • 1998
  • Finite element analysis was investigated on the stress distribution at the 2-D model of piezoelectric ceramic actuators. The y direction maximum stress decreased with a(internal electrode gap) size until 0.4 mm and is not much difference with c(external electrode thickness) size. The stress distribution with internal layers is almost same, and the stress distribution of load condition is higher than that of no load condition. The y direction maximum stress increased exponentially with the number of layer and saturated at 260 layers. In the case of defective actuator, the stress distribution is smaller than that of normal actuator.

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A Study on Polarization of MCFC (MCFC의 분극특성에 관한 연구)

  • Eom, S.W.;Kim, G.Y.;Yun, M.S.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1242-1244
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    • 1993
  • As increasing of internal resistance value at MCFC electrode, out voltage of battery is decreased currently. We measured overpotential and IR drop which consist of resistance factors in MCFC electrode, and calculated out voltage from open circuit voltage.

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Conductivity Imaging of a Canine Head using a 3T MREIT System with a Carbon-Hydrogel Electrode: Postmortem Experiment (3T MREIT 시스템을 이용한 실험견 사체의 두부 도전율 영상)

  • Jeong, Woo-Chul;Kim, Young-Tae;Minhas, Atul S.;Kim, Hyung-Joong;Lee, Tae-Hwi;Kang, Byeong-Teck;Park, Hee-Myung;Woo, Eung-Je
    • Journal of Biomedical Engineering Research
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    • v.30 no.2
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    • pp.179-184
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    • 2009
  • Magnetic Resonance Electrical Impedance Tomography (MREIT) is a new bio-imaging modality providing cross-sectional conductivity images from measurements of internal magnetic flux densities produced by externally injected currents. Recent MREIT studies demonstrated successful conductivity image reconstructions of postmortem and in vivo canine brain. However, the whole head imaging was not achieved due to technical issues related with electrodes and noise in measured magnetic flux density data. In this study, we used a new carbon-hydrogel electrode with a large contact area and injected 30 mA imaging current through a canine head. Using a 3T MREIT system, we performed a postmortem canine experiment and produced high-resolution conductivity images of the entire canine head. Collecting magnetic flux density data inside the head subject to multiple injection currents, we reconstructed cross-sectional conductivity images using the harmonic $B_z$ algorithm. The conductivity images of the canine head show a good contrast not only inside the brain region including white and gray matter but also outside the brain region including the skull, temporalis muscle, mandible, lingualis proprius muscle, and masseter muscle.