• 제목/요약/키워드: initial equilibrium state

검색결과 94건 처리시간 0.024초

전지구수치예측모델의 토양수분 초기화를 위한 오프라인 Noah 지면모델 스핀업 특성분석 (Analyzing off-line Noah land surface model spin-up behavior for initialization of global numerical weather prediction model)

  • 전상희;박정현;부경온;강현석
    • 한국수자원학회논문집
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    • 제53권3호
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    • pp.181-191
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    • 2020
  • 본 연구에서는 전지구수치예보모델의 예측성능에 주요한 영향을 주는 요소 중 하나인 토양수분 초기장을 적절히 생산하기 위해, 오프라인 Noah 지면모델을 구축하여 스핀업실험을 수행하고 그 변동특성을 살펴보았다. 스핀업실험은 지면기후장 생성과 목표연도에 대한 현실화의 2단계로 구성되었다. 첫 번째 단계의 지면기후장 생성은 2008~2017년 기간에 대해 평균한 대기강제력으로 10년 동안 지면모델을 반복적으로 수행하는 방식으로 이루어졌으며, 토양수분 모의가 평형상태에 도달하는데 소요되는 시간은 토양깊이와 코펜 정의에 기반한 기후구 특성에 따라 차이가 컸다. 토양 첫 번째 층은 극지역에서 가장 길었고, 두 번째 층 부터 네 번째 층까지는 건조지역에서 평형상태에 도달하는 시간이 가장 늦어 최대 7년 내외의 시간이 소요되었다. 결과적으로 10년의 spin-up을 거치면 지면모델이 평형상태에 도달함을 알 수 있다. 이 소요시간은 지상기온과 강수량과 음의 상관관계를 보였다. 두 번째 단계에서는 2018년을 목표연도로 설정하고 지면기후장을 이용하여 추가 적분을 수행하고, 그 결과 6개월 이내에 지면모델에서 모의된 토양수분, 지표기온, 증발산량은 2018년 지면상태에 도달하는 것을 확인하였다. 이에 구축된 오프라인 Noah 지면모델 스핀업 시스템은 안정적으로 전구수치예보모델의 토양수분 초기장을 생산함으로써 전지구수치모델에 결합된 지면모델의 물리과정과 기초자료가 변하더라도 유연하게 대응할 수 있는 가능성을 확인하였다.

분자동역학법에 의한 기체분자의 속도분포에 관한 연구 (A Study on the Velocity Distribution of Gas Molecules by the Molecular Dynamics Method)

  • 최순호
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권3호
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    • pp.441-450
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    • 2004
  • The velocity distribution of gas molecules from the experimental results was confirmed as the same with the Maxwell-Boltzmann's theoretical results within the experimental error. This study is on the realization of the Maxwell-Boltzmann's velocity distribution of gas molecules by the molecular dynamics(MD) method. The Maxwell-Boltzmann's velocity distribution of gas molecules is extremely important to confirm the equilibrium state because the properties of a thermodynamic system shall be obtained from the system's equilibrium configuration in the MD method. This study is the first trial in the successive researches to calculate the properties of a thermodynamic system by the computer simulations. We confirmed that the maxwell-boltzmann's velocity distribution is developed in some transient time after starting a simulation and dependent on the size of a system. Also it is found that the velocity distribution has no relation with an initial configuration of gas molecules.

Existence of a nash equilibrium to differential games with nonlinear constraints

  • Kim, Yang-Yol
    • 한국경영과학회:학술대회논문집
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    • 한국경영과학회 1989년도 추계학술발표회 발표논문초록집; 이화여자대학교, 서울; 23 Sep. 1989
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    • pp.45-50
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    • 1989
  • The above theorm states that much larger classes of differential games have an equilibrium. The most severe assumption is the second one. It requires that state dynamic equations be linear on his own control variables. But, the dynamic programming approach applied in the above is hardly implementable for the purpose of computation. It is very difficult to solve (SP$_{it}$) directly. Notice, however, the problem can be transformed into a Hamiltonian maximization problem which is easy to solve if initial conditions are given. In this way, it is possible to design a solution algorithm to problems with nonlinear constraints. The above two theorems probide a basis for such an algorithm.m.

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Presteady State Kinetics of ATP Hydrolysis by Escherichia coli Rho Protein Monitors the Initiation Process

  • Jeong, Yong-Ju;Kim, Dong-Eun
    • Bulletin of the Korean Chemical Society
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    • 제27권2호
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    • pp.224-230
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    • 2006
  • Escherichia coli transcription termination factor Rho catalyzes the unwinding of RNA/DNA duplex in reactions that are coupled to ATP binding and hydrolysis. We report here the kinetic mechanism of presteady state ATP binding and hydrolysis by the Rho-RNA complex. Presteady state chemical quenched-flow technique under multiple turnover condition was used to probe the kinetics of ATP binding and hydrolysis by the Rho-RNA complex. The quenched-flow presteady state kinetics of ATP hydrolysis studies show that three ATPs are bound to the Rho-RNA complex with a rate of $4.4\;{\times}\;10^5M^{-1}s^{-1}$, which are subsequently hydrolyzed at a rate of $88s^{-1}$ and released during the initiation process. Global fit of the presteady state ATP hydrolysis kinetic data suggests that a rapid-equilibrium binding of ATP to Rho-RNA complex occurs prior to the first turnover and the chemistry step is not reversible. The initial burst of three ATPs hydrolysis was proposed to be involved in the initialization step that accompanies proper complex formation of Rho-RNA. Based on these results a kinetic model for initiation process for Rho-RNA complex was proposed relating the mechanism of ATP binding and hydrolysis by Rho to the structural transitions of Rho-RNA complex to reach the steady state phase, which is implicated during translocation along the RNA.

Molecular dynamics study of liquid sodium film evaporation and condensation by Lennard-Jones potential

  • Wang, Zetao;Guo, Kailun;Wang, Chenglong;Zhang, Dalin;Tian, Wenxi;Qiu, Suizheng;Su, Guanghui
    • Nuclear Engineering and Technology
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    • 제54권8호
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    • pp.3117-3129
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    • 2022
  • Deeply understanding the phase change of thin liquid sodium film inside wick pore is very important for further studying high-temperature sodium heat pipe's heat transfer. For the first time, the evaporation and condensation of thin liquid sodium film are investigated by the Lennard-Jones potential of molecular dynamics. Based on the startup and normal operation of the sodium heat pipe, three different cases are simulated. First, the equilibrium is achieved and the Mass Accommodation Coefficients of the three cases are 0.3886, 0.2119, 0.2615 respectively. Secondly, the non-equilibrium is built. The change of liquid film thickness, the number of gas atoms, the net evaporation flux (Jnet), the heat transfer coefficient (h) at the liquid-gas interface are acquired. Results indicate that the magnitude of the Jnet and the h increase with the basic equilibrium temperature. In 520-600 K (the startup of the heat pipe), the h has approached 5-6 W m-2 K-1 while liquid film thickness is in 11-13 nm. The fact shows that during the initial startup of the sodium heat pipe, the thermal resistance at the liquid-gas interface can't be negligible. This work is the complement and extension for macroscopic investigation of heat transfer inside sodium heat pipe. It can provide a reference for further numerical simulation and optimal design of the sodium heat pipe in the future.

카올리나이트의 납 흡착 특성 (Adsorption Characteristics of Lead on Kaolinite)

  • 장경수;강병희
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제7권4호
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    • pp.24-30
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    • 2002
  • 본 연구에서는 카올리나이트에 대한 납의 흡착 특성을 규명코자 실내에서 회분식 흡착시험을 수행하였다. 회분식 흡착시험에서는 흡착평형도달시간, 흡착능 및 흡착등온식을 연구하였고 pH와 혼합비에 따른 카올리나이트에 대한 납의 흡착특성에 미치는 영향을 분석하였다. 실험결과 카올리나이트에 대한 납의 흡착은 24시간 이내에 평형에 도달하였고 초기오염농도가 증가함에 따라 카올리나이트에 대한 납의 흡착량은 증가하나 초기농도 198mg/l 이상에서는 흡착율은 감소하였다 Freundlich 흡착등온식에 적용한 결과 흡착강도를 나타내는 계수 1/n은 0.9584이다. 그리고 pH 값이 증가함에 따라 초기오염농도에 관계없이 카올리나이트에 대한 납의 흡착량 및 흡착율은 증가되었으며 pH 8 이상에서는 일정한 값에 수렴하였다. 또한 혼합비가 증가함에 따라 흡착량은 증가하였다. 반면에 흡착율은 점점 증가하다가 일정 혼합비 8 이상에서는 감소하는 경향이 있음을 알 수 있었다.

증분형(增分形) 유한요소법(有限要素法)에 의한 축대칭(軸對稱) Shell구조(構造)의 좌굴해석(挫屈解析) (Buckling Analysis of Axisymmetric Shells by Incremental Finite Element Mothod)

  • 김재복;김창렬
    • 대한조선학회지
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    • 제22권1호
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    • pp.21-30
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    • 1985
  • This paper deals whth the buckling as well as postbuckling analysis of axisymmertric shells taking the initial deflection effects into account. Incremental equilibrium equations, based on the principle of virtual work, were derived by the finite element method, the successive step-by-step Newton-Raphson iterative technique was adopted. To define the transition pattern of postbuckling behavior from the prebuckling state more accurately, a simple solution method was developed, i.e. the critical load was calculated by the load extrapolation method with the determinant of tangent stiffness matrix and the equilibrium configuration in the immediate postbuckling stage was obtained by perturbation scheme and eigenvalue analysis. Degenerated isoparametric shell elements were used to analyse the axisymmetric shell of revolution. And by the method developed in this paper, the computer program applicable to the nonlinear analysis of both thin and moderately thick shells was constructed. To verify the capabilities and accuracies of the present solution method, the computed results were compared with the results of analytical solutions. These results coincided fairly well in both the small deflection and large deflection ranges. Various numerical analyses were done to show the effect of initial deflection and shape of shells on buckling load and postbuckling behavior. Futhermore, corrected directions of applied loads at every increment steps were used to determine the actual effects of large deflection in non-conservative load systems such as hydrostatic pressure load. The following conclusions can be obtained. (1) The method described in this paper was found to be both economic and effective in calculating buckling load and postbuckling behavior of shell structure. (2) Buckling and postbuckling behavior of spherical caps is critically dependent upon their geometric configuration, i.e. the shape of spherical cap and quantities of the initial deflection. (3) In the analysis of large deflection problems of shells by the incremental method, corrections of the applied load directions are needed at every incremental step to compensate the follower force effects.

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비대칭적 정보 하에서 진입 억제와 가격 경쟁 (Entry Deterrence and Price Competition under Asymmetric Information)

  • 맹주열;최성용
    • 경영과학
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    • 제33권4호
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    • pp.65-75
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    • 2016
  • We study limit pricing in a price-based duopoly market under asymmetric information on the demand state. An incumbent, who is a monopolist in the initial period, has complete information on the size of a market, while a potential entrant only knows it partially. After observing the sales price of the incumbent in the first period, the entrant decides whether to enter a duopoly market and the sales price if she chooses to. We present a separating perfect Bayesian equilibrium, which indicates that limit pricing can deter the entry of a potential entrant under price competition when there is information asymmetry about the demand state.

비선형 내력법을 이용한 단일 공기막의 형상 탐색 (Form Finding of a Single-layered Pneumatic Membrane Structures by Using Nonlinear Force Method)

  • 손수덕;하준홍;이승재
    • 한국공간구조학회논문집
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    • 제21권4호
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    • pp.49-56
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    • 2021
  • This study aims to develop a form-finding algorithm for a single-layered pneumatic membrane. The initial shape of this pneumatic membrane, which is an air-supported type pneumatic membrane, is to find a state in which a given initial tension and internal pneumatic pressure are in equilibrium. The algorithm developed to satisfy these conditions is that a nonlinear optimization problem based on the force method considering the deformed shape is formulated, and, it's able to find the shape by iteratively repeating the process of obtaining a solution of the governing equations. An computational technique based on the Gauss-Newton method was used as a method for obtaining solutions of nonlinear equations. In order to verify the validity of the proposed form-finding algorithm, a single-curvature pneumatic membrane example and a double-curvature air pneumatic membrane example were adopted, respectively. In the results of these examples, it was possible to well observe the step-by-step convergence process of the shape of the pneumatic membrane, and it was also possible to confirm the change in shape according to the air pressure. In addition, the calculation results of the shape and internal force after deformation due to initial tension, air pressure, and self-weight were obtained.

Preparation of Alginate/Poly(N-isopropylacrylamide) Hydrogels Using Gamma-ray Irradiation Grafting

  • Lee, Young-Moo;Lee, Sang-Bong;Seo, Sung-Mi;Lim, Youn-Mook;Cho, Seong-Kwan;Nho, Young-Chang
    • Macromolecular Research
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    • 제12권3호
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    • pp.269-275
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    • 2004
  • To graft N-isopropylacrylamide (NIPAAm) onto alginate, varying dosages of ${\gamma}$-rays were irradiated onto alginate films in deionized water and methanol media, which are non-solvents of alginate. We investigated the hydrogels graft ratio, mechanical strength, swelling kinetics and ratio, and behavior with respect to drug release. The graft yield of NIPAAm increased upon increasing the irradiation dose. The use of the aqueous solution increased the graft yield relative to that obtained in methanol. The mechanical strength of the grafted hydrogels increased after grafting with NIPAAm. In a study of the swelling kinetics, we found that all hydrogels reached an equilibrium swollen state within 3 h. The equilibrium swelling ratio of the hydrogels decreased upon increasing the irradiation dose. The swelling ratio of the hydrogels decreased dramatically between 30 and 35$^{\circ}C$ because phase separation of NIPAAm occurred at 32$^{\circ}C$. The swelling process, with respect to the temperature change, was repeatable. An NIPAAm-grafted alginate containing a drug sustained its release rate until 3 h after an initial high drug release caused by a burst effect.