• Preventive Nutrition and Food Science
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• 제21권4호
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• pp.338-347
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• 2016

The present study investigated the volatile compound, physicochemical, and antioxidant properties of beany flavor-removed soy protein isolate (SPI) hydrolyzates produced by combined high temperature pre-treatment and enzymatic hydrolysis. Without remarkable changes in amino acid composition, reductions of residual lipoxygenase activity and beany flavor-causing volatile compounds such as hexanol, hexanal, and pentanol in SPI were observed after combined heating and enzymatic treatments. The degree of hydrolysis, emulsion capacity and stability, 2,2-diphenyl-1-picrylhydrazyl radical scavenging activity, and superoxide radical scavenging activity of SPI were significantly increased, but the magnitudes of apparent viscosity, consistency index, and dynamic moduli (G', G") of SPI were significantly decreased after the combined heating and enzymatic treatments. Based on these results, it was suggested that the enzymatic hydrolysis in combination with high temperature pre-treatment may allow for the production of beany flavor-removed SPI hydrolyzates with superior emulsifying and antioxidant functionalities.

• Macromolecular Research
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• 제16권7호
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• pp.620-625
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• 2008

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

• 폴리머
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• 제38권3호
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• pp.406-410
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• 2014

아연이온이 포함된 thiuram 구조를 가진 zinc dibutyldithiocarbamate(ZDBC)와 아연이온을 포함하고 있지 않은 thiuram계 촉진제인 tetramethylthiuram disulfide(TMTD), dipentamethylenethiuram tetrasulfide(DPTT)를 실리카가 충전된 천연고무에 첨가하여 가황특성 및 기계적 물성(모듈러스, 인장강도, 신장률)에 미치는 영향을 비교 평가하였다. ZDBC는 가장 빠른 반응개시시간(t10)과 높은 보강성(R.I.), 그리고 marching 거동을 보였다. 메커니즘을 고찰하고 제시하였다.

• Journal of Oral Medicine and Pain
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• 제34권1호
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• pp.11-21
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• 2009

목적 ; 본 연구는 가스분석검사기의 일종인 Oral $Chroma^{(R)}$(CHM-1, Osaka, Japen)를 이용하여 건강검진센터에 내원하는 환자를 대상으로 전신질환 판정검사에서 이상소견을 가진 환자에서 구취를 일으키는 휘발성 황화합물을 측정 비교하여 전신질환이 구취에 미치는 영향을 알아보고자 하였다. 방법 ; 수집된 자료는 통계분석 프로그램인 Statistical Package for the Social Science12.0(SPSS Inc, Chicago, IL, USA)을 이용하여 구강검사(CPI index, 탐침 시 출혈 유무, 설태의 유무) 결과 및 각 검사별 전신질환의 유무에 따른 황화수소, 메틸 머캅탄, 황화 디메틸의 농도를 교차분석으로 분석하였다. 결과 ; 휘발성 황화합물과 관계있는 질환은 간질환과 담낭질환이라는 사실을 확인할 수 있었으며 그 외 골밀도와 혈압, 지질검사 등에서의 관련성도 관찰되어 추후 연구가 더 필요할 것으로 생각된다.

• 한국산학기술학회논문지
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• 제11권8호
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• pp.2935-2941
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• 2010

본 논문은 SLS의 함유정도를 다르게 한 A(0%), B(1.1%), C(2.2%)의 세가지 실험세치제를 제작하여 구취변화를 실험하였다. 대상은 전신질환이 없는 20대 성인 150명이었으며 50명씩 세 그룹(A, B, C )으로 나누어 진행되었다. SLS함량에 따른 세치제의 4주간사용 후 3집단의 구취변화를 황화물가스와 암모니아 양의 변화로 측정한 결과 3집단 모두 집단내의 변화는 있는 것으로 나타났지만 SLS함량에 따른 상관관계를 본 결과에서는 구강황(r=0.412)과 호기황(r=0.285)에서만 상관관계가 있는 것으로 나타났다. 이는 잇솔질의 개선으로 인한 변화라고 볼 수 있으며 SLS의 함량이 높을수록 타액분비율을 저하시켜, 구강건조를 유발하므로 구강 황화합물과 호기 황화합물의 수치가 높게 나온 것으로 생각된다.

• Elastomers and Composites
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• 제44권2호
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• pp.156-163
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• 2009

사출성형 시 흐름자국이 생기지 않는 흐름성이 향상된 PP(Polypropylene) 복합재료를 제조하기 위한 연구를 진행하였다. PP는 분자량 분포와 용융지수(MI)가 다른 4종류의 PP를 사용하였으며, PP, 탈크, 고무와 약간의 첨가제로 구성된 PP컴파운드의 유변학적 특성은 Spiral Flow(SF), MI, 전단점도를 측정함으로써 평가하였다. 분자량 분포가 넓은 PP를 사용한 경우 MI가 상대적으로 낮다 하더라도 SF는 MI가 높은 PP보다 높게 관찰되는 경우도 있었다. 사출성형시 표면에 흐름자국이 발생하지 않도록 하기 위해서는 분자량 분포가 넓은 PP를 사용하는 것이 바람직 함을 확인하였다.

• Elastomers and Composites
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• 제45권3호
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• pp.223-229
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• 2010

가공기기의 기하학적 구조(geometry)가 실리카 분산에 대해 미치는 영향을 알아보기 위해서 롤밀(two roll mill)과 밀폐식 혼합기(internal mixer)를 사용하여 실리카가 충전된 부틸고무 가황물을 제조하여 가황특성, 인장특성 및 실리카 분산을 비교하였다. 가공 시, 롤밀을 사용하여 제조한 배합물은 밀폐식 혼합기를 사용하여 제조한 배합물보다 경화 속도($t_{90}$)는 약간 느렸으나, 긴 유도시간($ts_2$), 높은 최대 토크 값($T_{max}$)을 보였다. 또한 롤밀을 사용하여 제조한 배합물은 실리카 입자의 분산 및 기계적 물성의 특성에 있어서 밀폐식 혼합기를 사용했을시 보다 상대적으로 우수함을 보였다.

• 방사선산업학회지
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• 제10권4호
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• pp.231-242
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• 2016

This study was conducted to evaluate the synergistic protective effects of mixtures of corn silk, perilla leaf and grape stem extract (CPG mixture) against UVB-induced skin damage and compound 48/80-induced pruritus in mice. The results showed that treatment with CPG mixture exhibited much stronger suppressive effect on erythema and melanin index as well as melanin formation than treatment with ascorbic acid (AA) in UVB-irradiated mice. Moreover, the treatment with CPG mixture showed ameliorative effect on immune cell infiltration and collagen fiber destruction in UV-irradiated mice. The treatment with CPG mixture inhibited glutathione (GSH) depletion, lipid peroxidation and production of pro-inflammatory cytokines in UVB-irradiated mice. Furthermore, the treatment with CPG mixture inhibited compound 48/80-induced scratching behavior and histological changes in mice. Taken together, these results indicated that CPG mixture has potentials as functional and therapeutic materials against skin damage and itch-related skin diseases.

• 대한본초학회지
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• 제28권4호
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• pp.71-76
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• 2013

Objectives : The biological activities and compound contents of herbal medicine vary depending on manufacturing processes. In this study, we compared anti-inflammatory effects and compound contents of three kinds of multi-herbal extract HT008 produced by different manufacturing processes in order to determine chemical and biological equivalence. Methods : HT008 was produced by three different manufacturing methods: 1. Freeze dried extract of Eleutherococcus senticosus, Scutellaria baicalensis and Angelica sinensis (HT008 FD), 2. Spray dried extract of E. senticosus and S. baicalensis combined with reflux extract of A. sinensis (HT008 SD), 3. Spray dried extract of E. senticosus and S. baicalensis combined with supercritial fluid extract of A. sinensis (HT008 SF). Anti-inflammatory effects were evaluated using acetic acid induced pain model and ${\lambda}$-carageenan induced paw edema model. Compound contents were evaluated by HPLC quantitative analysis of standard compounds of HT008, eleutheroside E, baicalin, z-ligustilide. Results : HT008 FD, HT008 SD and HT008 SF significantly decreased acetic acid induced pain index and ${\lambda}$-carrageenan induced paw edema volume compared with that of control group. There was no significant difference in efficacy among the HT008 FD, HT008 SD and HT008 SF. Standard compound contents of HT008 FD, HT008 SD and HT008 SF were quantified within the range of Korean pharmacopoeia or other research. Conclusions : Three different manufacturing methods of multi-herbal extracts have been developed without noticeable difference in the efficacy or compound contents. The results might be used to establish manufacturing process and industrialization of herbal extracts.

• 한국염색가공학회지
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• 제10권4호
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• pp.30-36
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• 1998

The need for the effective flame retardant finishing for synthetic fiber Is required. This paper is focussed on the analysis of physical properties of nylon 6 fabric treated with tris(2-chloroethyl) phosphate(TCEP) in comparision with the untreated fabric. In order to evaluate the flame retardance effect, limiting oxygen index and burn rate were determined. Above 20% add-on of TCEP on nylon 6 fabric, reasonable flame retardancy was observed. Thermal stability of the treated nylon 6 fabric was evaluated by TGA. It seems that TCEP acts via a condensed phase mechanism. Tenacity and moisture regain of the treated fabrics were not changed and washfastness of those was excellent.