• 제목/요약/키워드: in situ spectroscopy

검색결과 271건 처리시간 0.024초

Effect of Various Supports on the Physico-chemical Properties of V-Sb Oxides in the Oxidative Dehydrogenation of Isobutane

  • Shamilov, N.T.;Vislovskiy, V.P.
    • 대한화학회지
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    • 제55권5호
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    • pp.812-818
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    • 2011
  • [ $V_{0.9}Sb_{0.1}O_x$ ]systems, bulk and deposited on different supports (five types of ${\gamma}$-aluminas, ${\alpha}$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

Comparison of Near-Infrared Spectroscopy with Raman Spectroscopy from the Point of Nondestructive Analysis of Biological Materials

  • Takeyuki Tanaka;Hidetoshi Sato;Jung, Young-Mee;Yukihiro Ozaki
    • Near Infrared Analysis
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    • 제1권2호
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    • pp.9-20
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    • 2000
  • Recently, near-infrared (NIR) spectroscopy and Raman spectroscopy have received keen interest as powerful techniques for nondestructive analysis of biological materials. The purpose of this review paper is to compare the advantages of NIR and Raman spectroscopy in the nondestructive analysis. Both methods are quite unique and often complementary. For example. NIR spectroscopy is very useful in monitoring in situ the content of components inside biological materials while Raman spectroscopy is very suitable for identifying micro-components on the surface of biological materials. In this article specific characters of the two spectroscopic methods are discussed first and then several examples of applications of NIR and Raman spectroscopy to the biological nondestructive analysis are introduced.

레이저를 이용한 방전 플라즈마중의 전계측정 기술 동향 (Technical tendency of electric field measurements in glow discharge plasmas using laser spectroscopy)

  • 최영욱;;촌강극기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 E
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    • pp.1663-1665
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    • 1997
  • Direct measurements of electric fields in a glow discharge are difficult because the measurement method should be sensitive to the electric field and non-intrusive. Laser spectroscopy is very suitable in that it is non-intrusive and allow in-situ measurements to be made. In this report, the measurement techniques of electric fields in glow discharge using laser spectroscopy were described.

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In situ Gel Forming Stereocomplex Composed of Four-Arm PEG-PDLA and PEG-PLLA Block Copolymers

  • Jun, Yeo-Jin;Park, Kyung-Min;Joung, Yoon-Ki;Park, Ki-Dong;Lee, Seung-Jin
    • Macromolecular Research
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    • 제16권8호
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    • pp.704-710
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    • 2008
  • Injectable hydrogels are quite promising materials due to their potential to minimize invasive implantation and this provides versatile fitness irrespective of the damaged regions and facilitates the incorporation of bioactive agents or cells. In situ gel formation through stereocomplex formation is a promising candidate for injectable hydrogels. In this paper, a new series of enantiomeric, four-arm, PEG-PLA block copolymers and their stereocomplexed hydrogels were prepared by bulk ring-opening polymerization of D-lactide and L-lactide, respectively, with stannous octoate as a catalyst. The prepared polymers were characterized by $^1H$ nuclear magnetic resonance (NMR) spectroscopy, Fourier-transform infrared (FT IR) spectroscopy, gel permeation chromatography (GPC) and thermal gravitational analysis (TGA), confirming the tailored structure and chain lengths. The swelling and degradation behavior of the hydrogels formed from a selected copolymer series were observed in different concentrations. The degradation rate decreased with increasing polymer content in the solution. The rheological behavior indicated that the prepared hydrogel underwent in situ gelation and had favorable mechanical strength. In addition, its feasibility as an injectable scaffold was evaluated using a media dependence test for cell culture. A Tris solution was more favorable for in situ gel formation than PBS and DMEM solutions were. These results demonstrated the in situ formation of hydrogel through the construction of a stereocomplex with enantiomeric, 4-arm, PEG-PLA copolymers. Overall, enantiomeric, 4-arm, PEG-PLA copolymers are a new species of stereocomplexed hydrogels that are suitable for further research into injectable hydrogels.

Laser-Induced Fluorescence spectroscopy을 이용한 환경 중 PAHs 화합물의 실시간 현지 모니터링 (In-situ Monitoring of PAHs in the Environment Using Laser-Induced Fluorescence Spectroscopy)

  • 이철규;;김영준
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.358-359
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    • 2001
  • PAHs는 불완전연소 과정과 주유소나 타르 생산공장 주변에서 발생하는데 돌연변이와 발암의 잠재력으로 인하여 특별한 관심이 요구되는 것들이고 US-EPA에서도 우선 오염물질로 선정되었다. PAHs를 검출하는 훌륭한 기술들이 존재하나, 이러한 기술들은 연속적인 모니터링이 요구되거나 많은 수의 샘플을 분석해야할 경우에 상당한 양의 비용과 시간이 요구된다. 그러나 분광학 기술을 바탕으로 한 Laser-Induced Fluorescence(LIF) spectroscopy를 이용한 방법은 실시간으로 연속적인 측정을 가능하게 할 뿐 아니라 여러 가지 PAHs, 유류오염물질 등의 물질을 동시에 측정할 수 있다. (중략)

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장곡사 미륵불 괘불탱의 채색 재료 분석을 위한 휴대용 라만 분광기의 적용성 연구 (Application of Handheld Raman Spectroscopy for Pigment Identification of a Hanging Painting at Janggoksa Temple(Maitreya Buddha))

  • 이나라;유영미;김소진
    • 헤리티지:역사와 과학
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    • 제56권4호
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    • pp.216-228
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    • 2023
  • 본 연구는 대형불화 현장 조사에 비파괴 조사장비 중 하나인 휴대용 라만 분광기를 적용하고 그 결과를 HH-XRF 데이터와 상호 비교하여 장곡사 미륵불 괘불탱에 사용된 채색 재료를 동정하였다. 대형불화에 사용된 채색 재료 분석시, 현장에서 주로 휴대용 현미경과 HH-XRF를 이용한다. 하지만 채색 재료가 경원소로 구성되어 있거나 여러 안료가 중첩 또는 혼합 채색된 경우, 비파괴 분석 데이터만으로는 해석에 한계가 있다. 또한 문화유산이라는 특성상 수습할 수 있는 시료의 양은 제한적이어서 XRD, SEM-EDS 및 라만 분광을 이용한 정밀 분석을 수행하는데 어려움이 있다. 따라서 현장 조사 시 HH-XRF 분석 데이터를 보완할 분석기술이 필요하다. 장곡사 미륵불 괘불탱을 대상으로 백색, 적색, 황색, 녹색, 청색 색상별 채색 재료에 대하여 HH-XRF로 성분을 분석하고 휴대용 라만 분광기를 적용하여 분자구조를 확인하였다. 분석결과, 백색은 연백, 적색은 진사, 석간주, 황색은 등황, 석황, 녹색은 염화동, 청색은 쪽이 사용된 것을 확인할 수 있었다. 휴대용 라만 분광기를 적용함으로써 데이터에 대한 교차검증뿐 아니라 HH-XRF로 확인이 어려웠던 혼합 채색된 안료에 대한 식별과 유기안료에 대한 정보를 획득하는데 도움이 되었다. 또한 대형불화 등 회화문화유산의 비파괴 현장 조사에 휴대용 라만이 다양하게 활용될 수 있을 것으로 판단된다.

In situ Er 도핑된 GaN와 Er이 이온 주입된 GaN의 PL과 PLE 비교에 대한 연구 (Comparison of In-situ Er-doped GaN with Er-implanted GaN Using Photoluminescence and Photoluminescence Excitation Spectroscope)

  • 김현석;성만영;김상식
    • 한국전기전자재료학회논문지
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    • 제16권2호
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    • pp.89-96
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    • 2003
  • Photoluminescence (PL) and photoluminescence excitation (PLE) spectroscopy have been performed at 6 K on the 1540 nm $^4$I$\_$(13/2)/\longrightarrow$^4$I$\_$(15/2)/ emission of Er$\^$+3/ in in situ Er-doped GaN The PL and PLE spectra of in situ Er-doped GaN are compared with those of Er-implanted GaN in this study. The lineshapes of the broad PLE absorption bands and the broad PL bands in the spectra of the in situ Er-doped GaN are similar to those in Er-doped glass rather than in the Er-implanted GaN. The PL spectra of this in situ Er-doped GaN are independent of excitation wavelength and their features are significantly different from the site-selective PL spectra of the Er-implanted GaN. These PL and PLE studies reveal that a single type of Er$\^$3+/ sites is present in the in situ Er-doped GaN and these Er sites are different from those observed in the Er-implanted GaN. In addition, the comparison of the PL single strength illustrates that the excitation of Er$\^$3+/ sites through the energy absorption of defects in Er-implanted GaN.

Kinetics of Acrylamide Solution Polymerization Using Potassium Persulfate as an Initiator by in situ IR

  • Kang, Shin-Choon;Park, Yoo-Jeong;Kim, Hyung-Zip;Kyong, Jin-Burm;Kim, Dong-Kook
    • Macromolecular Research
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    • 제12권1호
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    • pp.107-111
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    • 2004
  • We have studied the polymerization kinetics of acrylamide in aqueous solution with potassium persulfate as an initiator by using quantitative real-time in situ IR spectroscopy and monitoring the profiles of peaks in the range 1900-850 cm$\^$-1/. The conversion of acrylamide was calculated from the disappearance of the peak at 988 cm$\^$-1/, which is the out-of-plane bending mode of the=C-H unit, normalized to the C=O stretching peak at 1675 cm$\^$-1/, as an internal standard. For reaction temperatures in the range 40-65$^{\circ}C$ and initiator and monomer concentrations of 0.9-2.6 mmol/L and 0.5-1.1 mol/L, respectively, we deduced that the rate of monomer consumption follows the relation R$\_$p/=k[K$_2$S$_2$O$\_$8/]$\^$0.5/ [Μ]$\^$1.35${\pm}$0.10/. In addition, we obtained activation parameters from an evaluation of the kinetic data.

In-situ Raman Spectroscopy of Amorphous Hydrous $RuO_2$ Thin Films

  • Hyeonsik Cheong;Jung, Bo-Young;Lee, Se-Hee
    • 한국진공학회지
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    • 제12권S1호
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    • pp.49-51
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    • 2003
  • Amorphous hydrous ruthenium oxide thin films have attracted much interest owing to the possibility of using this material in electrochemical supercapacitors. Recently, it was found that this material is also electrochromic: during the charging/discharging cycle, the optical transmittance of the thin film is modulated. The physical and chemical origin of this phenomenon is not fully understood yet. In this work, we performed in-situ Raman spectroscopy measurements on amorphous hydrous ruthenium oxide thin films during the charging/discharging cycles. Unambiguous changes in the Raman spectrum were observed as protons were injected or extracted from the thin film. When the samples were annealed to reduce the water content, there is a consistent trend in the Raman spectrum. The origins of the Raman features and their relation to the electrochromic and/or supercapacitor characteristics is discussed.

Templated Formation of Silver Nanoparticles Using Amphiphilic Poly(epichlorohydrine-g-styrene) Film

  • Park, Jung-Tae;Koh, Joo-Hwan;Seo, Jin-Ah;Roh, Dong-Kyu;Kim, Jong-Hak
    • Macromolecular Research
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    • 제17권5호
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    • pp.301-306
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    • 2009
  • This work has demonstrated that a novel amphiphilic poly(epichlorohydrine)-graft-polystyrene (PECH-g-PS) copolymer at 34:66 wt% was synthesized via atom transfer radical polymerization (ATRP) of styrene using PECH as a macroinitiator. The structure of the graft copolymer was characterized by nuclear magnetic resonance ($^1H$ NMR) and FTIR spectroscopy, demonstrating that the "grafting from" method using ATRP was successful. The self-assembled graft copolymer was used as a template film for the in-situ growth of silver nanoparticles from $AgCF_3SO_3$ precursor under UV irradiation. The in situ formation of silver nanoparticles with 6-8 nm in average size in the solid state template film was confirmed by transmission electron microscopy (TEM), UV-visible spectroscopy and wide angle X-ray scattering (WAXS). Differential scanning calorimetry (DSC) also displayed the selective incorporation and the in situ formation of silver nanoparticles within the hydrophilic PECH domains, probably due to stronger interaction of the silvers with the ether oxygens of PECH backbone than that with hydrophobic PS side chains.