• Journal of Sensor Science and Technology
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• v.14 no.6
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• pp.395-401
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• 2005

A highly stable quartz crystal microbalance (QCM) that showed a stability of frequencies and exhibited a very low noise level has been developed. The long-term drift was <0.05 Hz/h over a period of 10 h, and the short-term rms (root mean square) noise was <0.015 Hz. Our QCM sensor was used as a humidity sensor employing a poly(methyl methacrylate) (PMMA) polymer film as a hygroscopic layer, which showed good characteristics in the relative humidity (RH) range of $2{\sim}90%$ RH. Comparing the characteristics of the QCM sensor with those of other types of humidity sensors employing PMMA film as a hygroscopic layer, and with other QCM sensors employing other hygroscopic layers is represented.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.6
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• pp.388-393
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• 2008

This study has been conducted to select the suitable refrigeration oil for a $CO_2$ refrigeration system. Non-hygroscopic property of refrigeration oils is one of the most important properties for refrigeration oils. PAG and POE oils are considered as test oils in this study. Transient variation of water content of PAG and POE oils was measured for 3 different vessels in the environmental conditions, such as in the range of temperature $25^{\circ}C$ to $40^{\circ}C$ and relative humidity 40% to 85%. The results obtained that water content of both POE and PAG is increased with an increase in the contact area with ambient for 3 different vessels. It is also found that water content of both POE and PAG is increased as the ambient temperature and relative humidity is increased. Non-hygroscopic property of POE oil is found to be much superior than that of PAG oil.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2006.04a
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• pp.55-56
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• 2006

This thesis describes the use of measured aerosol size distributions and size-resolved hygroscopic growth to examine the physical and chemical properties of several particle classes. The primary objective of this work was to investigate the optical and cloud forming properties of a range of ambient aerosol types measured in a number of different locations. The tool used for most of these analyses is a differential mobility analyzer / tandem differential mobility analyzer (DMA / TDMA) system developed in our research group. To collect the data described in two of the chapters of this thesis, an aircraft-based version of the DMA / TDMA was deployed to Japan and California. The data described in two other chapters were conveniently collected during a period when the aerosol of interest came to us. The unique aspect of this analysis is the use of these data to isolate the size distributions of distinct aerosol types in order to quantify their optical and cloud forming properties. I used collected data during the Asian Aerosol Characterization Experiment (ACE-Asia) to examine the composition and homogeneity of a complex aerosol generated in the deserts and urban regions of China and other Asian countries. An aircraft-based tandem differential mobility analyzer was used for the first time during this campaign to examine the size-resolved hygroscopic properties of particles having diameters between 40 and 586 nm. Asian Dust Above Monterey (ADAM-2003) study was designed both to evaluate the degree to which models can predict the long-range transport of Asian dust, and to examine the physical and optical properties of that aged dust upon reaching the California coast. Aerosol size distributions and hygroscopic growth are measured in College Station, TX to investigate the cloud nucleating and optical properties of a biomass burning aerosol generated from fires on the Yucatan Peninsula. Measured aerosol size distributions and size-resolved hygroscopicity and volatility were used to infer critical supersaturation distributions of the distinct particle types that were observed during this period. The predicted CCN concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction coefficients are calculated at a wavelength of 550 nm.

• Asian Journal of Atmospheric Environment
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• v.7 no.3
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• pp.129-138
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• 2013

The water uptake by fine aerosol in the atmosphere has been investigated at Gosan, Korea during ABC-EAREX 2005. The concentration of inorganic ion and carbon components, size distribution, and light scattering coefficients in normal and dry conditions were simultaneously measured for $PM_{2.5}$ by using a parallel integrated monitoring system. The result of this study shows that ambient fine particles collected at Gosan were dominated by water-soluble ionic species (35%) and carbonaceous materials (18%). In addition, it shows the large growth of aerosol in the droplet mode when RH is higher than 70%. Size distribution of the particulate surface area in a wider size range ($0.07-17{\mu}m$) shows that the elevation of RH make ambient aerosol grow to be the droplet mode one around $0.6{\mu}m$ or the coarse mode one, larger than $2.5{\mu}m$. Hygroscopic factor data calculated from the ratio of aerosol scattering coefficients at a given ambient RH and a reference RH (25%) show that water uptake began at the intermediate RH range, from 40% to 60%, with the average hygroscopic factor of 1.10 for 40% RH, 1.11 for 50% RH, and 1.17 for 60% RH, respectively. Finally, average chemical composition and the corresponding growth curves were analyzed in order to investigate the relationship between carbonaceous material fraction and hygroscopicity. As a result, the aerosol growth curve shows that inorganic salts such as sulphate and nitrate as well as carbonaceous materials including OC largely contribute to the aerosol water uptake.

• Journal of the Korean Society of Safety
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• v.11 no.1
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• pp.90-98
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• 1996

In order to investigate the effects on intumescence to fire protective coatings, the characteristics of solubility, hygroscopic nature and X-ray diffration results on soluble silicate were determined. Solubility is depended on the mutual action of each silicate. In the result of hygroscopic characteristics by water absorption under several kinds of relative humidity, lithium silicate is more stable than sodium and potassium silicate over moistures. Eventhough free water is evaporated over $100^{\circ}C$ , physically adsorption water and ionic water are eliminated about $200^{\circ}C$, but evolution of structural water is expected to be emitted between 400~$600^{\circ}C$ range. Those are considered to be contributed intumescence on soluble silicate.

• Journal of Environmental Science International
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• v.16 no.7
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• pp.793-798
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• 2007

During May of 2003, smoke from fires in the Yucatan Peninsula was transported across the Gulf of Mexico and into Texas where it caused significant enhancement in measured aerosol concentrations and reduced visibility. During this event, the formation and growth of aerosol particles has been observed by a differential mobility analyzer (DMA) / tandem differential mobility analyzer (TDMA) system to characterize the size distribution and size-resolved hygroscopicity of the aerosol. The most number concentration is by the particles smaller than 100 nm, but the integrated number concentrations for over 100 nm increased due to the aerosol growth. Hygroscopic growth factor increase from 1.2 to 1.4 for 25, 50, and 100 nm particles during the nucleating period. This distribution and the aerosol properties derived from the TDMA data were used to calculate the growth rate. Particle growth rates were in the range 1-12 nm/hr.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.54 no.1
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• pp.107-110
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• 2021

The goal of this study was to investigate moisture sorption characteristics of Lactobacillus brevis-fermented sea tangle Saccharina japonica, Mekabu fucoidan, and these mixture powders. Moisture sorption isotherms of powders were determined at 37℃ using the static gravimetric technique in a water activity (aw) range of 0.11-0.93. Equilibrium moisture content (Xeq) values of the fermented sea tangle powder were almost 3 times when aw<0.7 and increased upto almost 4 times when aw<0.9 higher than mekabu fucoidan powder. In these reason, to improve strong hygroscopic nature of the fermented sea tangle powder, fermented sea tangle and mekabu fucoidan powders were dissolved as ratios of 7:3, 5:5, and 3:7 (w/w) in a distilled water and then freeze dried. Xeq values of mixture powders were around average value of sum of both powders at all aw ranges. All moisture sorption isotherms of powders exhibited typical J-shaped type III. Xeq of mixture powders increased with increasing aw and decreased as increasing proportion of mekabu fucoidan powder. The Peleg model was found to accurately describe moisture sorption isotherms of powders. The results can be used to understand hygroscopic nature of powders, improve shelf life, and retain quality across postharvest processing.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.05a
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• pp.129-133
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• 1993

$TiO_2-V_2O_5-Nb_2O_5$ humidity sensors have been fabricated in the ceramic type and their physical and hygroscopic characteristics have been investigated. The additives and sintering conditions affect the humidity sensitivity. XRD patterns, SEM photographs were used for the analysis of crystal structures and surface morphology. $TiO_2-V_2O_5-Nb_2O_5$ humidity sensors had good linearity in the range from 20%RH to 90%RH and the sensitivity of sensor sintered at $1,000^{\circ}C$ for 1hr was 73% at operating temperature $60^{\circ}C$.

• Journal of the Korean Chemical Society
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• v.13 no.2
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• pp.149-156
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• 1969

$NaAl(OH)_2CO_3$was synthesized using colloidal earth (Allophane) as the starting material and some of its were studied in detail. It was found that Dawsonite was formed in the pH range (pH 12.5~12.0) that the concentration of $HCO_3^-$ was just begun to increase and the presence of $HCO_3^-$ in the product was clarified from the infrared absorption spectrum. The chemical formular of Dawsonite was therefore presumed as $NaAlO (OH) HCO_3$. From toahhe results of X-ray powder diffraction, both peaks at 5.7 $\AA$ and 2.8 $\AA$ were observed, and fibrous crystalline structure was observed from electron micrograph and also found from the microscopic electron diffraction at 5.7 $\AA.$ Therefore the fibrous axis was considered as =Al=O2=Al=O2=Al=(*image) direction. True specific gravity of Dawsonite was 2.44 and its porosity was 91.4%. It was practically insoluble in water, but decomposed in the boiling water to form Pseudo Boehmite. Stable pH range of Dawsonite was about 4.5~11.5. From the results of D.T.A. and T.G.A., it was observed that $CO_2$was liberated at $350^{\circ}C$, and $H_2O$ at $650^{\circ}C$, and converted into strongly hygroscopic $NaAlO_2$, which was easily decomposed in water into $\beta-Al(OH)_3(Bayerite)$ and NaOH.

• Advances in environmental research
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• v.1 no.1
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• pp.69-82
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• 2012

Based on the measurement data of the particulate matter with an aerodynamic diameter of less than or equal to a nominal 10 ${\mu}m$ (PM10) by the ${\beta}$-ray absorption method (BAM) equipped with an inlet heater and the gravimetric method (GMM) at two coastal sites in Korea, the optimal inlet heater temperature was estimated. By using a gas/particle equilibrium model, Simulating Composition of Atmospheric Particles at Equilibrium 2 (SCAPE2), water content in aerosols was estimated with varying temperature to find the optimal temperature increase to make the PM10 concentration by BAM comparable to that by GMM. It was estimated that the heated air temperature inside the BAM should be increased up to $35{\sim}45^{\circ}C$ at both sites. At this temperature range, evaporation of volatile aerosol components was minor. Similar ($30{\sim}50^{\circ}C$) temperature range was also obtained from the calculation based on the absolute humidity which changed with ambient absolute humidity and chemical composition of hygroscopic species.