• Journal of Hydrogen and New Energy
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• v.31 no.2
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• pp.184-193
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• 2020

One of the technical methods to increase the volumetric energy density of hydrogen is to pressurize the gaseous hydrogen and then contain it in a rigid vessel. Especially for automotive systems, the compressed hydrogen storage can be found in cars as well as at refueling stations. During the charging the pressurized hydrogen into a vessel, the temperature increases with the amount of stored hydrogen in the vessel. The temperature of the vessel should be controlled to be less than a limitation for ensure stability of material. Therefore, the accurate estimation of temperature is of significance for safely storing the hydrogen. In this work, three well-known cubic equations of state (EOSs) were adopted to examine the accuracy in regenerating thermodynamic properties of hydrogen within the temperature and pressure ranges for the compressed hydrogen storage. The formulations representing molar volume, internal energy, enthalpy, and entropy were derived for Redlich-Kwong (RK), Soave-Redlioch-Kwong (SRK), and Peng-Robinson (PR) EOSs. The calculated results using the EOSs were compared with literature data given by NIST. It was revealed that the accuracies of RK and SRK EOSs were satisfactorily compatible and better than the results by PR EOS.

• Transactions of Materials Processing
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• v.28 no.4
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• pp.203-211
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• 2019

In this study, the weight of type IV pressure vessel is optimized through the burst pressure condition using the finite element analysis (FEA) based on the genetic algorithm (GA). The optimization design variables include the thickness of composite layers and the winding angles. The optimized design variables are validated using the numerical simulations for the pressure vessel. Consequently, the weight is decreased by about 6.5% as compared to the previously reported results for Type III pressure vessel. Additionally, a method which reduces the entire optimization time is proposed. In the original method, the population size is constant across all generations. However, the proposed method could reduce the workload through the reduction of the population size by half for every 25 generations. Thus, the proposed method is observed to increase the weight by about 0.1%, however, the working time for the optimization could be decreased by about 46.5%.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.116-122
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• 2023

As the number of hydrogen filling stations for hydrogen supply increases with the progress of low-carbon eco-friendly energy policies, the risk of accidents is also increasing. Actual pressure vessels may have defects such as notches, pores, and inclusions that may occur during the manufacturing process. Therefore, it is necessary to evaluate the integrity of pressure vessels in the case where cracks exist in pressure vessels under internal pressure. In this paper, 3D finite element analysis was used to evaluate the structural safety of hydrogen-filled pressure vessels with surface cracks, and the shape of surface cracks was compared with the commonly used semi-elliptical shape. In the future, these results will be used to predict the remaining life of the pressure vessel in consideration of fracture mechanics.

• Journal of Hydrogen and New Energy
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• v.22 no.3
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• pp.363-371
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• 2011

In this paper, a three-dimensional hydrogen desorption model is developed to precisely study the hydrogen desorption kinetics and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The metal hydride hydrogen desorption model, i.e. governed by the conservation of mass, momentum, and thermal energy is first experimentally validated against the temperature evolution data measured on a cylindrical $LaNi_5$ metal hydride vessel. The equilibrium pressure used for hydrogen desorption simulations is derived as a function of H/M atomic ratio and temperature based on the experimental data in the literature. The numerical simulation results agree well with experimental data and the 3D desorption model successfully captures key experimental trends during hydrogen desorption process. Both the simulation and experiment display an initial sharp decrease in the temperature mainly caused by relatively slow heat supply rate from the vessel external wall. On the other hand, the effect of heat supply becomes influential at the latter stages, leading to smooth increase in the vessel temperature in both simulation and experiment. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen desorption process and further indicates that efficient design of storage vessel and heating system is critical to achieve fast hydrogen discharging performance.

• Journal of the Korean Institute of Gas
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• v.27 no.2
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• pp.95-103
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• 2023

In this paper, in order to evaluate the deformation characteristics of the hydrogen gas storage vessel(Type 1) when considering gas pressure, the VMS generated in the hydrogen gas storage vessel according to the notch shape of ISO 18119 was interpreted as a FEM(Finite Element Method). According to the analysis results, the maximum VMS generated in the longitudinal notch was higher than the transverse notch. In addition, the stress of the storage vessel was analyzed by the stress ratio, which is the yield strength ratio of the material to the VMS generated. According to the analysis results, in the case of a storage vessel with a notch formed in the longitudinal direction, the inside and outside of the storage vessel increased to 0.85 and 0.50 at a gas pressure of 50 MPa, respectively, but were analyzed to be lower than 1.

• Journal of Hydrogen and New Energy
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• v.34 no.1
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• pp.32-37
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• 2023

In this study, in order to propose a integrity evaluation for type IV high aspect ratio hydrogen storage vessel, a numerical analysis of the hoop tensile test and pressure test was performed using FEM software, and the results of the actual physical property test were reviewed. The property test and numerical analysis were compared, and very similar results were obtained with deviations of maximum tensile strength of 4.75% and fiber direction stress of 5.39%.

• Nuclear Engineering and Technology
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• v.45 no.6
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• pp.767-790
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• 2013

MAAP4 is a computer code that can simulate the response of a light water reactor power plant during severe accident sequences, including actions taken as part of accident management. The code quantitatively predicts the evolution of a severe accident starting from full power conditions given a set of system faults and initiating events through events such as core melt, reactor vessel failure, and containment failure. Furthermore, models are included in the code to represent the actions that could mitigate the accident by in-vessel cooling, external cooling of the reactor pressure vessel, or cooling the debris in containment. A key element tied to using a code like MAAP4 is an uncertainty analysis. The purpose of this paper is to present a MAAP4 based analysis to examine the sensitivity of a key parameter, in this case hydrogen production, to a set of model parameters that are related to a Level 2 PRA analysis. The Level 2 analysis examines those sequences that result in core melting and subsequent reactor pressure vessel failure and its impact on the containment. This paper identifies individual contributors and MAAP4 model parameters that statistically influence hydrogen production. Hydrogen generation was chosen because of its direct relationship to oxidation. With greater oxidation, more heat is added to the core region and relocation (core slump) should occur faster. This, in theory, would lead to shorter failure times and subsequent "hotter" debris pool on the containment floor.

• Journal of the Korean Society of Safety
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• v.7 no.3
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• pp.66-72
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• 1992

An experimental study was carried out to analyse the explosion characteristics of flammable gas-air mixtures. Used flammable gases were hydrogen, methane, acethylene, ethylene and pro-pane, explosion Pressure, explosoin pressure rising rate, and flame propagation velocity were measured experimentaly. The maximum explosion pressure and rising rate of flammmalbe gas air mixtures were appeared at the range of slightly higher concentration than the stoichiometric concentration. Initial pressure before explosion was controlled from 0.6 to 2.0kg/cm absolutly. Explosion pressure was increased with increment of the initial pressure, and the relationship between initial pressure and explosion pressure was Pe = KPi. The effect of vessel size on explosion characteristics was also analysed In this experiment. Explosion pressure was increased with in-creasing the vessel size, otherwise explosion pressure rising rate was decreased. When we locate a dummy material in vessel explosion pressure was decreased with increasing the dummy volume but exlosion pressure rising rate was increased.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.193-196
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• 2007

We developed and tested the high pressure hydrogen gas cylinder(type4) for fuel cell vehicle. The working pressure is 350bar. We conducted material tests, production tests and design qualification tests on the developed cylinders according to modified NGV2-2000(hydrogen). The high pressure hydrogen gas cylinder met all the design qualification requirements of ANSI/CSA NGV2-2000 and acquired NGV2 certification from independent inspection agency.

• Composites Research
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• v.29 no.2
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• pp.60-65
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• 2016

In this paper, finite element analysis and real time monitoring experimental work using FBG sensor were carried out for analyzing structural integrity of a Type IV hydrogen pressure vessel under impact loading condition. By using finite element analysis with the ply based modeling technique, sensor insertion points and pressure condition were suggested. Tensile test with an angle ply specimen was conducted for getting the reliability of FBG sensor insertion method. After fabricating the vessel, total five times pressurization fatigue tests were conducted (Non-impact pressurization: 1, After impact pressurization: 4). Experimental results revealed that filling cycle time was gradually increased and filling gradient was decreased when the vessel experienced impact.