• Bulletin of the Korean Chemical Society
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• 제24권6호
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• pp.797-801
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• 2003

One of the largest challenges for quantum chemistry today is to obtain accurate results for large complex molecular systems, and a variety of approaches have been proposed recently toward this goal. We have developed the ONIOM method, an onion skin-like multi-level method, combining different levels of quantum chemical methods as well as molecular mechanics method. We have been applying the method to many different large systems, including thermochemistry, homogeneous catalysis, stereoselectivity in organic synthesis, solution chemistry, fullerenes and nanochemistry, and biomolecular systems. The method has recently been combined with the polarizable continuum model (ONIOM-PCM), and was also extended for molecular dynamics simulation of solution (ONIOM-XS). In the present article the recent progress in various applications of ONIOM and other electronic structure methods to problems of homogeneous catalyses and nanochemistry is reviewed. Topics include 1. bond energies in large molecular systems, 2. organometallic reactions and homogeneous catalysis, 3. structure, reactivity and bond energies of large organic molecules including fullerenes and nanotubes, and 4. biomolecular structure and enzymatic reaction mechanisms.

• 충청수학회지
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• 제21권1호
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• pp.29-48
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• 2008

We deal with the classification problem of real hypersurfaces in a complex hyperbolic space. In order to classify real hypersurfaces in a complex hyperbolic space we characterize a real hypersurface M in $H_n(\mathbb{C})$ whose structure vector field is not principal. We also construct extrinsically homogeneous real hypersurfaces with four distinct curvatures and their structure vector fields are not principal.

• Ocean and Polar Research
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• 제21권2호
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• pp.99-108
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• 1999

With sectional data obtained in September of 1987, 1988 and 1989 by quadrireciprocal ADCP measurement and CTD cast, the current structure, volume transport and vorticity in the Western Channel of the Korea Strait were studied. The characteristics of Tsushima Current water persisted throughout the summer especially in the homogeneous water of temperature $14-16^{\circ}C$ located at the depth of 50-100m below seasonal termocline. Thickness and velocity of the homogeneous layer are about 10-170m and 20-60cm/s. and the relative vorticity for this layer is shown to be nearly constant and it is smaller than the planetary vorticity. Potential vorticity of $2.70-7.10{\times}10^{-6}m^{-1}s^{-1}$ is found to be dependent mainly on planetary rather than on the relative vorticities. The Tsushima Current water represented by the homogeneous layer R14-16^{\circ}C$ may keep the potential vorticity at the area of strong current in the Strait. The ADCP current structure is similar to geostrophic current and the core of the current with the speed of 30-50cm/s is situated in the middle layer over the deep trough. With large tidal fluctuation the volume transport has mean value of 1.17sv which was about 40% larger than that of geostrophic calculation.

• Journal of applied mathematics & informatics
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• 제8권1호
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• pp.71-80
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• 2001

The purpose of this paper is to give the classification of homogeneous integral table algebras of degree 5 containing a faithful real element of which 2. In fact, these algebras are classified to exact isomorphism, that is the sets of structure constants which arise from the given basis are completely determined. This is work towards classifying homogeneous integral table algebras of degree 5. AMS Mathematics Subject Classification : 20C05, 20C99.

• Korean Journal of Mathematics
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• 제30권4호
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• pp.643-652
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• 2022

In this paper, we will describe affine homogeneous domains in the complex plane. For this study, we deal with the Lie algebra of infinitesimal affine transformations, a structure of the hyperbolic metric involved with affine automorphisms. As a consequence, an affine homogeneous domain is affine equivalent to the complex plane, the punctured plane or the half plane.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.64-74
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• 1994

The nonstoichiometric chalcogenides with NaCl-type structure were prepared and the physical and structural properties were studied. The homogeneous range and the structural change were studied based on X-ray powder diffractions using Rietveld-type full-profile fitting technique. Wide homogeneous ranges were observed in Y-S and Y-Se systems, and relatively narrow homogeneous ranges were observed in Yb-S and Yb-Se systems. Both in $Yb_{1-x}S\;and\;Yb_{1-x}Se$, a vacancy ordering transition occurred in (111) plane direction. The ordered superstructure had cubic symmetry(Fm$\bar{3}m) with doubled unit cell "a" parameter compared to the original NaCl-type. The superlattice developed in a continuous second-order transitiion was characterized by the reduced waved vector k= $(a^*+b^*+c^*)/2$. Y-S system had metallic, and YSe, YbSe system had semiconducting properties in their homogeneous ranges. It was observed that the change of electronic transport properties in extended homogeneous range did not depend on the relativeratio of metal to nonmetal, but on the quantities of vacancies.

• Structural Engineering and Mechanics
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• 제24권1호
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• pp.19-29
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• 2006

The evolution process of an initially homogeneous bone structure under axial and transverse loads is investigated in this paper. The external loads include axial and external lateral pressure, electric, magnetic and thermal loads. The theoretical predictions of evolution processes are made based on the adaptive elasticity formulation and coupled thermo-magneto-electro-elastic theory. The adaptive elastic body, which is a model for living bone diaphysis, is assumed to be homogeneous in its anisotropic properties and its density. The principal result of this paper is determination of the evolution process of the initially homogeneous body to a transversely inhomogeneous body under the influence of the inhomogeneous stress state.

• Radiation Oncology Journal
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• 제11권1호
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• pp.183-191
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• 1993

The homogeneous dose planning is one of the most important roles in radiation therapy. But, it is not easy to obtain a homogeneous dose to paranasal sinus region including the ethmoidal sinus with conventional irradiation techniques. In this experimental study, the authors tried to get a homogeneous dose at PNS region, but the nasal cartirage does not exceed the tolerance dose, with anterior-posterior beam and two both lateral wedged beams. Used three fields were shielded with full thickness of blocks to preserve the eye-balls and with blocks of one half value layer to create a homogeneous dose at the whole treatment volume. The dose computations are based on the three dimensonal structure with modified scatter contributions of partial shielders and attenuated beams in 6 MV photon beams. The dose distributions of mid-plane is examined with Kodak verification films and teflon-embedded TLD rod (1 mm diameter and 6 mm length) to confirm the computed dose. In our study, the whole PNS regions have shown within $85{\%}$ of the resultant isodose curves with relatively homogeneous dose distribution. The results of dose computation and measurements are agree well within $5{\%}$ uncertainties.

• Nuclear Engineering and Technology
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• 제52권11호
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• pp.2491-2498
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• 2020

The paper concentrates on an experimental study of the pressure drop in double-layered packed beds formed by glass spheres, having the configuration of horizontal and vertical stratification. Both single-phase and two-phase flow tests are performed. The pressure drop during the test is recorded and the measured data are compared with those of homogeneous beds consisting of mono-size particles. The results show that for the horizontally stratified bed with fine particles atop coarse particles, the pressure drop in top layer is found higher than those of homogenous bed consisting of the same smaller size particles, while the measured pressure drop of bottom part is similar with those of similar homogenous bed. But for the homologous bed with upside-down structure, the stratification has little or no effect on the pressure drop of the horizontally stratified bed, and the pressure drop of each layer is almost same as that of homogeneous bed packed with corresponding spheres. Additionally, in vertically stratified bed, the pressure drops on the left and right side is almost equal and between those in homogeneous beds. It is speculated that vertically stratified structure may lead to lateral flow which redistributes the flow rate in different parts of packed bed.

• 전기전자학회논문지
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• 제7권2호
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• pp.218-222
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• 2003

전자파 방사 및 측정 시험설비로 표준 시험장인 야외시험장을 사용하고 있으나 시험장 구축의 어려움으로 이를 대체할 수 있는 대용시험장을 사용하여 측정시험을 할 수 있도록 하고 있다. 본 논문에서는 최적화된 측정시스템을 구성하기 위한 대용시험시설인 GTEM CELL(Gigahertz Transverse Electro Magnetic Cell)의 구조분석 및 설계를 하기 위하여 내부도체(Septum)의 넓이 및 두께 변화에 따른 내부도체의 특성임피던스 변화를 살펴보았다.