• Journal of the Korean Ceramic Society
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• v.43 no.5 s.288
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• pp.299-303
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• 2006

In this paper, anode supported SOFC with columnar structured YSZ electrolyte was fabricated via Electron Beam Physical Vapor Deposition (EBPVD) method. Liquid condensation process was employed for the preparation of NiO-YSZ substrate and the high power electron beam deposition method was used for the deposition of YSZ electrolyte film. Double layered cathode with LSM-YSZ and LSM was printed on electrolyte via screen-printing method and fired at $1150^{\circ}C$ in air atmosphere for 3 h. The electrochemical performance and the long-term stability of $5{\times}5cm^2$ single cell were investigated with DC current-voltage characteristics and AC-impedance spectroscopy. According to the investigation, $5{\times}5cm^2$ sized unit cell showed the maximum power density of around $0.76W/cm^2$ at $800^{\circ}C$ and maintained the stable performance over 400 h.

• Membrane Journal
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• v.13 no.1
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• pp.54-63
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• 2003

The Preparation and electrochemical characterization of anion-exchange membranes containing pyridinium groups were performed. As a result, the pyridinium membranes showed good electrochemical properties, comparable to those of the commercial membranes, with electrical resistance of less than $3.0 {\Xi}cm^2$ in a 0.5 mol $dm^{-3}$ NaCl and high ionic permselectivity (the transport number of $Cl^-$ ions being 0.97). Moreover, water splitting in the membranes containing pyridinium group was about two or three order of magnitude lower than those in the commercial membranes (ｅ.ｇ. AM-1, Tokuyama Crop., Japan) at the same current density because the resonance effedt in the quaternary aromatic pyridinium group contributed to their molecular stability. In addition, the electrodialytic properties of the pyridinium membranes were evaluated in a semi-pilot scale.

• Journal of the Korean Chemical Society
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• v.43 no.3
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• pp.315-320
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• 1999

Novel electroluminescent materials, polymer material, PU-BCN and low molar mass material, D-BCN with the same chromophores were designed and synthesized. A molecular structure of chromophore was composed of bisstyrylbenzene derivative with cyano groups as electron injection and transport and phenylamine groups as hole injection and transport. Device structures with PU-BCN and D-BCN as an emission layer were fa-bricated, which were a single-layer device(SL), Indium-tin oxide(ITO)/emission layer/MgAg, and two kinds of double-layer devices which were composed of ITO/emission layer/oxadiazole derivative/MgAg as a DL-E device and ITO/triphenylamine derivative/emission layer/MgAg as a DL-H device. The two emission materials, PU-BCN and D-BCN with the same emission-chromophore were evaluated as having excellent performance of charge injection and transport and revealed almost the same emission characteristics in high current density. EL emission maximum peaks of two material were detected at about 640 nm wavelength of red emission region.

• Journal of the Korean Magnetics Society
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• v.22 no.3
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• pp.97-102
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• 2012

In this paper, a non-contact power transferring has been performed. Power Transferring by using an electromagnetic inductive coupling is more suitable for high power transmission than by using a magnetic resonance method. Power transferring system has been designed with Loading Distribution Method to divide the electric and magnetic loading for designing the magnetic core and electric coil. To design optimum shapes of magnetic yoke, 3D finite element analysis has been performed. Experimental results show good agreement with numerical ones. So, it could be adopted in the electric power transferring system for a short-distance wireless electric power transferring machine.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.396-396
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• 2013

The resistive random access memory (ReRAM) has several advantages to apply next generation non-volatile memory device, because of fast switching time, long retentions, and large memory windows. The high mobility of monolayered graphene showed several possibilities for scale down and electrical property enhancement of memory device. In this study, the monolayered graphene grown by chemical vapor deposition was transferred to $SiO_2$ (100 nm)/Si substrate and glass by using PMMA coating method. For formation of metal-oxide nanoparticles, we used a chemical reaction between metal films and polyamic acid layer. The 50-nm thick BPDA-PDA polyamic acid layer was coated on the graphene layer. Through soft baking at $125^{\circ}C$ or 30 min, solvent in polyimide layer was removed. Then, 5-nm-thick indium layer was deposited by using thermal evaporator at room temperature. And then, the second polyimide layer was coated on the indium thin film. After remove solvent and open bottom graphene layer, the samples were annealed at $400^{\circ}C$ or 1 hr by using furnace in $N_2$ ambient. The average diameter and density of nanoparticle were depending on annealing temperature and times. During annealing process, the metal and oxygen ions combined to create $In_2O_3$ nanoparticle in the polyimide layer. The electrical properties of $In_2O_3$ nanoparticle ReRAM such as current-voltage curve, operation speed and retention discussed for applictions of transparent and flexible hybrid ReRAM device.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.15 no.6
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• pp.181-186
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• 2015

With the rapid growth of semiconductor technologies, small-sized devices with powerful computing abilities are becoming a reality. As this environment has a limit on power supply, NVM storage that has a high density and low power consumption is preferred to HDD or SSD. However, legacy software layers optimized for HDDs should be revisited. Specifically, as storage performance approaches DRAM performance, existing I/O mechanisms and software configurations should be reassessed. This paper explores the challenges and implications of using NVM storage with a broad range of experiments. We measure the performance of a system with NVM storage emulated by DRAM with proper timing parameters and compare it with that of HDD storage environments under various configurations. Our experimental results show that even with storage as fast as DRAM, the performance gain is not large for read operations as current I/O mechanisms do a good job hiding the slow performance of HDD. To assess the potential benefit of fast storage media, we change various I/O configurations and perform experiments to quantify the effects of existing I/O mechanisms such as buffer caching, read-ahead, synchronous I/O, direct I/O, block I/O, and byte-addressable I/O on systems with NVM storage.

• Journal of the Korean Electrochemical Society
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• v.1 no.1
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• pp.14-17
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• 1998

Mesophase pitch-based carbon fibers(MPCF) have been investigated as an anode active material for lithium ion secondary battery. Graphitized MPCF gives high discharge capacity and good Ah efficiency. MPCF/Li cell shows an initial discharge capacity of 300 mAh/g and Ah efficiency above $90\%$ at a current density of 25 mA/g at $0\~1$ V. Cylindrical lithium ion secondary battery was fabricated using mixed carbon anode and $LiCoO_2$, cathode. In order to improve the cyclability of lithiun ion secondary battery, other carbons were added to the MPCF up to $10wt\%$. The cycle performance of lithium ion secondary battery using mixed carbons was superior to those using graphitized MPCF.

• Transactions of the Korean hydrogen and new energy society
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• v.14 no.3
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• pp.229-235
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• 2003

A 50W class MCFC stack was operated in order to test a new design of the circular shaped separator. in the new design, the anode gas was supplied into the stack and was exhausted out of the stack after the anode reaction. The exhausted gas was reacted with the cathode gas supplied with excess oxygen in the vessel in which the stack was placed. Then the reacted gas flowed into the cathode side of the stack and was exhausted through the outlet located in the center of the stack. The average voltage of the single cells in the stack was 0.835V under the current density of $150mA/cm^2$, initially, and the degradation rate of the stack voltage was 1.7%/1,000h. High stack voltage with good stability of the present stack was due to the small temperature gradient in the stack. The small temperature gradient as well as the easiness of temperature control was the result of the new configuration of the separator which utilized the heat of the combustion reaction between anode outlet gas and the cathode inlet gas for heating the stack.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.11
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• pp.816-820
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• 2013

We investigated the characteristics of the silicon oxy-nitride and nitride films grown by plasma-enhanced chemical vapor deposition (PECVD) at the low temperature with a varying $NH_3/N_2O$ mixing ratio and a fixed $SiH_4$ flow rate. The deposition temperature was held at $150^{\circ}C$ which was the temperature compatible with the plastic substrate. The composition and bonding structure of the nitride films were investigated using Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Nitrogen richness was confirmed with increasing optical band gap and increasing dielectric constant with the higher $NH_3$ fraction. The leakage current density of the nitride films with a high NH3 fraction decreased from $8{\times}10^{-9}$ to $9{\times}10^{-11}(A/cm^2$ at 1.5 MV/cm). This results showed that the films had improved electrical properties and could be acceptable as a gate insulator for thin film transistors by deposited with variable $NH_3/N_2O$ mixing ratio.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.615-621
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• 2013

Membrane characterization methods for aqueous redox flow batteries aqueous RFBs were modified for non-aqueous RFBs. The modified characterization methods, such as ion exchange capacity, transport number, permeability and single cell test, were carried out to evaluate commercial membranes in non-aqueous electrolyte. It was found that columbic efficiency and energy efficiency in a single cell test were dependent on the ion selectivity of commercial anion exchange membranes. Neosepta AHA anion exchange membrane showed the anion transport number of 0.81, which is a relatively low ion selectivity in non-aqueous electrolyte, however, exhibited 92% of coulombic efficiency and 86% of energy efficiency in a single cell test. It was also found that a porous membrane without ion selectivity is suitable for a non-aqueous redox flow battery at a high current density.