• Title/Summary/Keyword: heavy metal and As

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Feasibility Study on the Applicability of Fly Ash as a Barrier Material in Containment System

  • Myung Dong-Il;Lee Gwang-Hun;Lee Seung-Hak;Park Jun-Boum;Kim Hyung-Suk
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.202-210
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    • 2005
  • In this study, the fly ash was employed as a possible alternative to the bentonite for its high sorption capacity against cationic heavy metal. To consider the constituents of barrier possibly used, the specimens were mixed with different material contents (fly ash : weathered soil : bentonite), then sorption test was performed. Also the specimens were molded on the wet side of optimum moisture contents like mixing ratio of sorption test and their hydraulic conductivities were measured in flexible-wall permeameters. And to confirm the effect of dissolved cations, the hydraulic conductivity tests were repeated by converting the permeant liquids from water to $Cd^{2+}$ solution. Finally, the Cd-concentration at the effluent was analyzed for 500hrs to compare the effectiveness of each specimen in contaminant retardation. Test results showed that the more the ratio of fly ash increase, the more Kd value increase, and the hydraulic conductivity of weathered soil/bentonite (95:5) mixture was the lowest $(2.9*10^{-8}cm/sec)$, and specimens made of fly ash and fly ash/weathered soil mixtures showed similar hydraulic conductivity. Although the permeant liquid was changed from water to $Cd^{2+}$ solution, the hydraulic conductivity of all specimens except for weathered soil maintained similarly like before. Consequently, the initial breakthrough point of Cd in weathered soil specimen was observed at about 5hrs after the test started while that of fly ash specimens was not observed during the whole test period of 500hrs. The results implied that fly ash had a sufficient retardation capacity against contaminant transport possibly by its high sorption capacity although it showed little effect on the reduction of hydraulic conductivity. Based on the test results, it could be concluded that the fly ash can be possibly used as a suitable barrier material in containment system to attenuate the contaminant transport for its high retardation capacity and for the low cost.

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Studies on the Alleviation of Heavy Metal (Cadmium) Damage through Soil Improvement (Extraction of Cadmium and the Damage through Exchangeable Cd++ by the Application of Soil Amendments) (중금속(重金屬)(Cd)의 피해경감(被害輕減)을 위(爲)한 토양개량(土壤改良)에 관(關)한 연구(硏究) I. Cd침출(浸出)과 개량제(改良劑) 시용(施用)으로 인(因)한 치환성(置換性) Cd의 감소(減少))

  • Oh, Wang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.4
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    • pp.242-249
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    • 1982
  • Effects of lime and ameliolating materials on decreasing available soil cadmium were studied, applying the amendments to Cd pre-and post-treated soils. Soil sttreated with Cd were placed in pots and kept under field moisture condition, summer through winter in 1981. The results of soil analysis made 40 to 60 days after the Cd treatment are as follows ; 1. Greater amount of Cd was extracted by 0.1N-HCl or 2% Citric acid than N-AcNH4 solution. More Cd was dissoluted by 0.1-HCl than 2% Citric acid. No Cd was extracted by pure water. Showing a wide variance in the amount of extractable Cd among treatments (amendments), the $N-AcNH_4$ solution seemed to be the most effective extracting solution of available soil cadmium. 2. Calcium hydroxide was the most effective materials in reducing $N-AcNH_4$ extractable Cd, followed by calcium carbonate and calcium silicate. 3. Superphosphate is also effective in reducing exchangeable cadmium. The reduction seemed to be attributed to the precipitation of cadmium phosphate. 4. The exchangeable cadmium by $N-AcNH_4$ was large in the soil pH range of 6.0 and 6.5, and it decreased as the soil pH became far apart from these values. The decrese of exchangeable Cd at low pH seemed to be related to the increase of $Mn^{+{+}}$ and that at the high pH to the precipitation as Cd-hydroxide.

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Physiological and Structural Damages in Acorus calamus var. angustatus as Native Aquatic Plants to Cadmium (카드뮴에 의한 수생식물 창포의 생리적·구조적 장해)

  • Lee, Sung-Chun;Kim, Wan-Soon
    • Horticultural Science & Technology
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    • v.30 no.4
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    • pp.371-377
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    • 2012
  • This study was conducted to investigate the physiological and structural damages to cadmium (Cd) in Acorus calamus var. angustatus as a native aquatic species in Korea. In addition to the physiological responses such as plant growth, photosynthesis, and root activity, the structural damages in leaf and root tissues were observed through light and scanning electronic microscopy. The five-leaf plants were treated with different Cd concentrations 0, 10, 25, and 50 ${\mu}M$ for 15 days. The plant damages to Cd were significant at 10-25 ${\mu}M$ Cd physiologically and at 25-50 ${\mu}M$ Cd structurally. The physiological damages in the shoot part (photosynthesis) started at 10 ${\mu}M$ Cd whereas those in root part (root activity) were serious above 25 ${\mu}M$ Cd. On the other hand, the structural damages began at 25 ${\mu}M$ Cd in the leaf and root tissues similarly, but the plant tissue destruction was more serious in the roots than in leaves. Based on the plant physiological and structural damages, 10 ${\mu}M$ was assumed to be the limited concentration for sustainable growth and landscaping ability in Acorus calamus var. angustatus to Cd.

Investigative Analysis of By-products from Lignocellulosic Biomass Combustion and Their Impact on Mortar Properties (목질계 바이오매스 연소부산물 분석과 모르타르 혼입 평가)

  • Jung, Young-Dong;Kim, Min-Soo;Park, Won-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.663-671
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    • 2023
  • This research experimentally evaluated the recyclability of four varieties of lignocellulosic fly ash(FA), a by-product from three power plants employing lignocellulosic biomass(Bio-SRF, wood pellets) as a fuel source. Comprehensive analyses were conducted on FA, encompassing both physical parameters (particle shape, size distribution, fineness, and density) and chemical properties(chemical composition and heavy metal content). Mortar test specimens, with FA mixing ratios ranging from 5 to 20%, were produced in compliance with KS L 5405 standards, and their flow and compressive strength were subsequently measured. The test results indicated that the four types of FA exhibited particle sizes approximately between 20~30㎛, densities around 2.3~2.5g/cm3, and a fineness range of 2,600~4,900cm2/g. The FA comprised approximately 50~90% of components such as SiO2, Al2O3, Fe2O3, and CaO, displaying characteristics akin to type-II and type-III FA of KS L 5405 standards, albeit with differences in chlorine and SiO2 content. From the mortar tests, it was observed that the compressive strength of the mortar ranged between 34~47MPa when the pellet combustion FA was mixed in proportions of 5~20%. FA, produced exclusively from the combustion of 100% lignocellulosic fuel, is assessed to possess high recyclability potential as a substitute for conventional admixtures.

Removal of Chlorinated Organic Compounds in Flue Gas by Activated Carbon Injection in a Semi-Drying Reactor (반건식 반응기에서의 활성탄 혼합주입에 의한 소각로 배가스중의 유기 염소계 화합물의 제거 공정 연구)

  • Choo, Changupp;Whang, Jaedong;Lee, Joyoung;Cho, Chulhoon;Shin, Byungchul
    • Clean Technology
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    • v.6 no.2
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    • pp.121-127
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    • 2000
  • There are several kinds of hazardous materials in incinerator flue gas, such as particulate matter, acid gas, heavy metal, dioxin, etc. The activated carbon adsorption is considered as one of the methods removing dioxin from flue gas. Without any additional equipment and facilities, the activated carbon was mixed with lime and sprayed in the semi-drying reactor of an incinerator and filtered in the bag filter, and its efficiency of removing hazardous organic material was investigated. 1,2-dichlorobenzene (o-DCB) was used as a precursor material of dioxin and the effects of the activated carbon amount, the operating temperature of the reactor, and the atomizer r.p.m were measured and analyzed. Experimental results showed that the optimum outlet temperature of the reactor was $145^{\circ}C$ considering the performance of the bag filter, and the adsorption performance improved with the increase of the atomizer r.p.m. Also the performance of removing o-DCB in the bag filter is higher than of the semi-drying reactor.

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Analysis of Industrial Linkage Effects for Farm Land Base Development Project -With respect to the Hwangrak Benefited Area with Reservoir - (농업생산기반 정비사업의 산업연관효과분석 -황락 저수지지구를 중심으로-)

  • Lim, Jae Hwan;Han, Seok Ho
    • Korean Journal of Agricultural Science
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    • v.26 no.2
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    • pp.77-93
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    • 1999
  • This study is aiming at identifying the foreward and backward lingkage effects of the farm land base development project. Korean Government has continuously carried out farmland base development projets including the integrated agricultural development projects. large and medium scale irrigation projects and the comprehensive development of the four big river basin including tidal land reclamation and estuary dam construction for the all weather farming since 1962. the starting year of the five year economic development plans. Consequently the irrigation rate of paddy fields in Korea reached to 75% in 1998 and to escalate the irrigation rate, the Government had procured heavy investment fund from IBRD. IMF and OECF etc. To cope with the agricultural problems like trade liberalization in accordance with WTO policy, the government has tried to solve such problems as new farmland base development policy, preservation of the farmland and expansion of farmland to meet self-sufficiency of foods in the future. Especially, farmland base development projects have been challanged to environmental and ecological problems in evaluating economic benefits and costs where the value of non-market goods have not been included in those. Up to data, in evaluating benefits and costs of the projects, farmland base development projects have been confined to direct incremental value of farm products and it's related costs. Therefore the projects'efficiency as a decision making criteria has shown the low level of economic efficiencies. In estimating economic efficiencies including Leontiefs input-output analysis of the projects could not be founded in Korea at present. Accordingly this study is aimed at achieving and identifying the following objectives. (1) To identify the problems related to the financial supports of the Government in implementing the proposed projects. (2) To estimated backward and foreward linkage effects of the proposed project from the view point of national economy as a whole. To achieve the objectives, Hwangrak benefited area with reservoir which is located in Seosan-haemi Disticts, Chungnam Province were selected as a case study. The main results of the study are summarized as follows : a. The present value of investment and O & M cost were amounted to 3,510million won and the present value of the value added in related industries was estimated at 5.913million won for the period of economic life of 70 years. b. The total discounted value of farm products in the concerned industries derived by the project was estimated at 10,495million won and the foreward and backward linkage effects of the project were amounted to 6,760 and 5,126million won respectively. c. The total number of employment opportunities derived from the related industries for the period of project life were 3,136 man/year. d. Farmland base development projects were showed that the backward linkage effects estimated by index of the sensitivity dispersion were larger than the forward linkage effect estimated by index of the power of dispersion. On the other hand, the forward linkage effect of rice production value during project life was larger than the backward linkage effect e. The rate of creation of new job opportunity by means of implementing civil engineering works were shown high in itself rather than any other fields. and the linkage effects of production of the project investment were mainly derived from the metal and non-metal fields. f. According to the industrial linkage effect analysis, farmland base development projects were identified economically feasible from the view point of national economy as a whole even though the economic efficiencies of the project was outstandingly decreased owing to delaying construction period and increasing project costs.

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Engineering Characteristics of CLSM with Regard to the Particle Size of Bottom Ash (저회의 입도변화에 따른 CLSM의 공학적특성)

  • Lee, Yongsoo;Kim, Taeyeon;Lee, Bongjik
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.10
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    • pp.5-10
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    • 2020
  • As the demand for the recycling of industrial by-products increases due to various environmental restrictions including the prohibition of ocean disposal, various studies regarding the recycling of industrial by-products are currently being carried out. One of the industrial by-product, coal ash is produced from thermal power generation; studies on the recycling of fly ash have been actively carried out and it is currently recycled in various fields. In the case of bottom ash, however, only a portion of the total amount generated is primarily processed into a particle size of 2~4mm or less than 2mm to be used for gardening purpose and light weight aggregate and so on. The remaining amount is buried at ash disposal sites. Therefore, various studies are needed to develop measures to use bottom ash. This study aimed at identifying the optimal particle size and mixing ratio of bottom ash to be used as CLSM aggregate. To this end, it evaluated the usability of bottom ash as CLSM aggregate, by investigating the flowability and strength change characteristics of CLSM produced with regard to the mixing ratio of weathered granite soil and bottom ash, particle size of bottom ash to be mixed and soil binder addition rate and conducting a heavy metal leaching test.

Purification and Biochemical Characteristics of Fibrinolytic Enzyme from Streptomyces corcohrussi JK-20 (Streptomyces corcohrussi JK-20 유래 혈전용해효소의 순수분리 및 이의 생화학적 특성 규명)

  • Kim, You-Jung;Park, Jeong-Uck;Seo, Min-Jeong;Kim, Min-Jeong;Lee, Hye-Hyeon;Jin, Se-Hun;Kang, Byoung-Won;Choi, Yung-Hyun;Jeong, Yong-Kee
    • Journal of Life Science
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    • v.20 no.6
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    • pp.838-844
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    • 2010
  • A fibrinolytic enzyme of Streptomyces corcohrussi from soil sediment was purified by chromatography using DEAE-Sephadex A-50 and Sephadex G-50. The analysis of SDS-polyacrylamide gel suggested that the purified enzyme is a homogeneous protein and the molecular mass is approximately 34 kDa. The purified enzyme showed activity of 0.8 U/ml in a plasminogen-rich fibrin plate, while its activity in a plasminogen-free fibrin plate was only 0.36 U/ml. These results suggested that the purified enzyme acts as a plasminogen activator. The fibrinolytic activity of the enzyme under the supplementation of protease inhibitors, $\varepsilon$-ACA, t-AMCHA and mercuric chloride in the enzyme reaction was less than 24%, indicating that it could be modulated by the plasmin and/or fibrinogen inhibitors involved in the fibrinogen-to-fibrin converting process. As time passed, $Zn^{2+}$, a heavy metal ion, inhibited the activity to 34.1%. The optimum temperature of the purified enzyme was approximately $50^{\circ}C$ and over 92% of the enzyme activity was maintained between pH 5.0 and 8.0. Therefore, our results provide a potential fibrinolytic enzyme as a noble thrombolytic agent from S. corcohrussi.

Study on Accumulation of Ni in Seedlings and Growth rate of Salix reichardtii by Hydroponic Culture in Ni Solution (수경재배에 의한 Salix reichardtii 묘의 생장 및 부위별 Ni축적에 관한 연구)

  • Lee, Chang-Heon;Lim, Yu-Mi
    • Journal of Korean Society of Forest Science
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    • v.99 no.3
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    • pp.292-297
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    • 2010
  • This study was carried out to provide preliminary data to purify contaminated sites by nickel (Ni). After rooted cuttings of Salix reichardtii had been grown in Ni solution (hydroponic culture), pH changes in the solution and the accumulated Ni amount in plant parts were measured and analyzed. When the Ni concentration was low enough for S. reichardtii cuttings to grow well, the pH value of the solution decreased considerably. As the Ni concentration got higher, the plant growth got poorer and the pH value decreased slowly. Roots accumulated the highest Ni amount. Leaves and stems followed after. When stems were older, the accumulated Ni amount was lower. more Ni was accumulated in the plant parts which had more flexible tissue and live cells. As the Ni concentration in solution got higher up to 50.0 ${\mu}mol$/L, so did the Ni accumulation in the plant parts. However, the plant individuals nearly died and the Ni accumulation tended to drop when the Ni concentration in solution was 100.0 ${\mu}mol$/L. The rooted cuttings of S. reichardtii grew poorer as the Ni concentration in solution got higher. The plants in solution with 100.0 ${\mu}mol$/L of Ni were practically dead in four weeks.

Complete genome sequence of Marinobacter salarius HL2708#2 isolated from a lava sea water environment on Jeju Island (제주용암 해수 환경에서 분리한 Marinobacter salarius HL2708#2의 유전체 해독)

  • Oh, Hyun-Myung;Kim, Dae-Hyun;Han, Seong-Jeong;Song, Jong-Ho;Kim, Kukhyun;Jang, Dongil
    • Korean Journal of Microbiology
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    • v.55 no.1
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    • pp.69-73
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    • 2019
  • During screening of microbes for compounds having cosmetic benefits, we isolated Marinobacter salarius HL2708#2 from lava seawater on Jeju Island, Republic of Korea. The complete genome sequence was determined. Strain HL27080#2 features a circular chromosome of 4,304,603 bp with 57.21% G+C content and a 244,163 bp plasmid with 53.14% G+C. There were 4,180 protein coding sequences identified, along with 49 transfer RNA and 18 ribosomal RNA noncoding genes. The genome harbored genes for the utilization of alcohol, maltose/starch, and monosaccharide as sole carbon sources. Genes responsible for halophilic characteristics and heavy metal resistance could be annotated, as well as aromatic and alkane hydrocarbons. Contrary to the prior report that M. salarius is negative for nitrate and nitrite reduction, nitrate/nitrite reductase along with nitrate/nitrate transporters and nitronate monooxygenase were evident, suggesting that strain HL2708#2 may be able to denitrify extracellular nitroalkenes to ammonia.