• Title/Summary/Keyword: heavy metal analysis

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Determination of Optimal Toxic Concentration and Accumulation of Cadmium in Broiler Chicks

  • Subhan, Fazli;Khan, Ayaz;Wahid, Fazli;Shehzad, Adeeb;Jan, Amin Ullah
    • Toxicological Research
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    • v.27 no.3
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    • pp.143-147
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    • 2011
  • Cadmium is considered one of the most toxic, non biodegradable heavy metal for the human and animals. The purpose of the present study was to investigate the changes in biochemical parameters of blood and accumulation of cadmium in various tissue caused by various levels of dietary cadmium chloride ($CdCl_2$) in broiler chicks. $CdCl_2$ was administered through drinking water to broiler chicks. In spectral analysis, $CdCl_2$ treatment caused a significant increase in Glutamate pyruvate transaminase (GPT), creatinine and uric acid levels in all treated groups. Intriguingly, the GPT, creatinine, and uric acid levels were significantly higher at 75 mg/kg as compared to the groups treated with high doses (100, 125 and 150 mg/kg) of $CdCl_2$. Atomic Absorption Spectrophotometer (AAS) was used for the determination of Cd accumulation in kidney, liver and Breast muscles. AAS analysis revealed that Cd accumulation is increased in breast muscles as compared to liver and kidney at higher doses of Cd than 75 mg/kg.

Analysis on Attitude and Education Need for Food Safety of High School Students in Gyeongbuk Province (경북지역 고등학생의 식품 안전성에 대한 태도 및 교육요구도 분석)

  • Kim, Eun-Jung;Kim, Hyo-Chung;Kim, Mee-Ra
    • Korean Journal of Human Ecology
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    • v.18 no.6
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    • pp.1323-1336
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    • 2009
  • This study examined the attitude and education need for food safety of high school students. Data were collected from 297 high school students in Gyeongbuk province through a self-administered questionnaire on December, 2008. Frequency, t tests, one-way analysis of variance, Duncan's multiple range tests, and chi-square tests were conducted using SPSS V. 14.0. Many respondents answered that the foods produced and distributed in Korea were not safe enough. Over a third of the respondents replied that the produced and distributed foods were not safe because of unsanitary food processing. They pointed out food additives threatened food safety the most, which was followed by heavy metal contamination, and endocrine disruptors. Most respondents mentioned difficulties in acquiring information concerning food safety, and obtained information from the media, such as TV and radio. The respondents required a high level of education regarding food safety, and preferred movie clips and broadcasting media the most. Finally, they pointed out food-related government organizations to be the most efficient educational institution for food safety.

A Study on the Anionisation of Cotton Fabric (면직물의 음이온화에 관한 연구)

  • Bae, Do Gyu;Lee, Tae Jung
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.29-37
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    • 2018
  • Cotton has no adsorption ability for the cationic dye and heavy metal but, if anionized cotton can be made, it will be possible. In this study, to enable the anionisation of cotton fabric, it was modified using sodium vinylsolfonate(SV) as the anionisation reagent, employing a pad-dry-cure(PDC) technique. The effects of curing time, treatment concentrations of urea, sodium hydroxide and SV on the weight increase were experimented and then, the physical characterizations of sulfoethyl cotton(SEC) depending on the finishing conditions were estimated, thus the application possibility of SV as anionisation reagent was investigated. It was not much changed by anionisation except wrinkle recovery. And the structure of SEC was elucidated by Raman and NMR spectoscopy. The feasibility of using Raman and NMR spectroscopy with the band at $1,043cm^{-1}$, and 50.5ppm, respectively as marker band to determine sulfoethyl group of SEC was reported. The total degree of SV substitution(DSV) was determined via elemental analysis. SEC with diverse total DSV up to 0.066 was obtained. In the thermal decomposition(pyrolysis) by DSC, it can be found that the pyrolysis temperature was about $30^{\circ}C$ lower than that of non-treated cotton fabric.

Studies on the Decomposition of CN ion in the electroplating waste Water and COD Variation of photodeveloping Waste-water (오존에 의한 폐수처리에 관한 연구 -도금폐액의 CN이온 분해와 사진 폐수의 COD 처리-)

  • 김덕묵;이치종
    • Journal of the Korean Professional Engineers Association
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    • v.14 no.1
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    • pp.22-29
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    • 1981
  • This study concernes the decomposition of cyanide ion in electroplating plant wastewater and COD variation of photodeveloping wastewater under various conditions. Determinations of CN- concentration were carried out by AgNO$_3$ titration method. The sample solutions were pretreated by passing ozone and decompositions were checked as a function of time for ozone treatment. Analysis of film developing wastewater was carried out by KMnO$_4$ method. Electroplating plant wastewater was also examined at various pH; decomposition rate of cyanide ion was found to increase at higher pH. Time required for the decomposition could be shortened by removing the heavy metal ions under alkaline condition. The effect of temperature on decomposition was studied at 40$^{\circ}$ and 60$^{\circ}C$. The result was better at 40$^{\circ}C$ although time for decomposition was almost same at both temperatures. Analysis of film developing wastewater revealed that COD decrease was faster during the first 1 to 2 hours. However, further decrease could not be effected. The existence of unknown special organics resistant to the decomposition was believed to be the reason.

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Identification and Characterization of Putative Integron-Like Elements of the Heavy-Metal-Hypertolerant Strains of Pseudomonas spp.

  • Ciok, Anna;Adamczuk, Marcin;Bartosik, Dariusz;Dziewit, Lukasz
    • Journal of Microbiology and Biotechnology
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    • v.26 no.11
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    • pp.1983-1992
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    • 2016
  • Pseudomonas strains isolated from the heavily contaminated Lubin copper mine and Zelazny Most post-flotation waste reservoir in Poland were screened for the presence of integrons. This analysis revealed that two strains carried homologous DNA regions composed of a gene encoding a DNA_BRE_C domain-containing tyrosine recombinase (with no significant sequence similarity to other integrases of integrons) plus a three-component array of putative integron gene cassettes. The predicted gene cassettes encode three putative polypeptides with homology to (i) transmembrane proteins, (ii) GCN5 family acetyltransferases, and (iii) hypothetical proteins of unknown function (homologous proteins are encoded by the gene cassettes of several class 1 integrons). Comparative sequence analyses identified three structural variants of these novel integron-like elements within the sequenced bacterial genomes. Analysis of their distribution revealed that they are found exclusively in strains of the genus Pseudomonas.

Machine learning of LWR spent nuclear fuel assembly decay heat measurements

  • Ebiwonjumi, Bamidele;Cherezov, Alexey;Dzianisau, Siarhei;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3563-3579
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    • 2021
  • Measured decay heat data of light water reactor (LWR) spent nuclear fuel (SNF) assemblies are adopted to train machine learning (ML) models. The measured data is available for fuel assemblies irradiated in commercial reactors operated in the United States and Sweden. The data comes from calorimetric measurements of discharged pressurized water reactor (PWR) and boiling water reactor (BWR) fuel assemblies. 91 and 171 measurements of PWR and BWR assembly decay heat data are used, respectively. Due to the small size of the measurement dataset, we propose: (i) to use the method of multiple runs (ii) to generate and use synthetic data, as large dataset which has similar statistical characteristics as the original dataset. Three ML models are developed based on Gaussian process (GP), support vector machines (SVM) and neural networks (NN), with four inputs including the fuel assembly averaged enrichment, assembly averaged burnup, initial heavy metal mass, and cooling time after discharge. The outcomes of this work are (i) development of ML models which predict LWR fuel assembly decay heat from the four inputs (ii) generation and application of synthetic data which improves the performance of the ML models (iii) uncertainty analysis of the ML models and their predictions.

Lonicera japonica inhibited the oxidative Stress induced by the heavy metal (중금속 유도 산화적 스트레스에 대한 금은화의 세포 보호 효과)

  • Yeom, Seung-Hee;Bak, Seon Been;Park, Sun-Dong;Park, Kwang-Il;Kim, Young Woo
    • Herbal Formula Science
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    • v.30 no.3
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    • pp.155-163
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    • 2022
  • Objectives : Lonicera japonica is known for anti-inflammation and antibiotic effect in Korean medicine. This study aimed for investigating the cytoprotective effect of Lonicera japonica extract (LJE) for HepG2 cells against arachidonic acid (AA)+iron-induced oxidative stress. Methods : The effect of LJE on cell viability was assessed by MTT assay. ROS assay was selected to assess antioxidant effect of LJE. To assess LJE's effect on mitochondrial function, flow cytometric analysis was operated. And immunoblot analysis was used to establish the underlying mechanism of LJE. Results : LJE protected HepG2 cells against AA+iron-induced oxidative stress by phosphorylation of liver kinase B1 and blocked the decline of procaspase 3. Also, LJE preserved the mitochondrial membrane permeability induced by AA+iron. Conclusion : LJE protected the hepatocyte from AA+iron-induced oxidative stress by activation of LKB1 by the preservation of mitochondrial functions.

Assessment of Risk Factors for Dental Developmental Disorders in Pediatric Cancer Survivors

  • Jihyun Lee;Hyung-Jun Choi;Jaeho Lee;Je Seon Song;Chung-Min Kang
    • Journal of the korean academy of Pediatric Dentistry
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    • v.50 no.4
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    • pp.421-433
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    • 2023
  • This study was to examine the developmental dental abnormalities in childhood cancer survivors. Risk factors were assessed for 125 children with radiographic data through a retrospective analysis of medical records and panoramic images. 68.0% of childhood cancer survivors exhibited at least one dental abnormality. The types of abnormalities varied depending on the age at cancer diagnosis and treatment intensity, ranging from microdontia (43.2%), to abnormal root development (39.2%) and tooth agenesis (33.6%). Logistic regression analysis demonstrated that a young age at diagnosis (under 3 years), the use of heavy metal agents, a history of hematopoietic stem cell transplantation (HSCT), and combination treatment of chemotherapy, radiation therapy, and HSCT were associated with a significantly higher risk for overall dental abnormalities. The increased risk ratios were 6.00, 3.06, 3.22, and 7.87, respectively (p < 0.05). The results of this study will predict dental abnormality in permanent dentition according to the diagnosis age and treatment method of childhood cancer.

Monitoring Heavy Metals in Meat and Meat Products (식육 및 그 가공품의 중금속 모니터링)

  • Hwang, Tae-Ik;Ahn, Tae-Hyun;Kim, Eun-Jung;Lee, Jung-Ah;Kang, Myoung-Hee;Jang, Young-Mi;Kim, Mee-Hye
    • Korean Journal of Food Science and Technology
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    • v.43 no.5
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    • pp.525-531
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    • 2011
  • This study was conducted to examine the contents of lead (Pb), cadmium (Cd), arsenic (As), and mercury (Hg) in meat and meat products in Korea. The contents of Pb, Cd, As, and Hg in 466 samples of beef, pork, chicken, duck, ham, and sausage were measured using inductively coupled plasma mass spectrometry or a mercury analyzer. Wet ashing and microwave method were compared, and the recovery and reproducibility of the microwave method were better than those of wet ashing for meat and meat products. The recovery of the microwave method was 98.1% for Pb, 104.6% for Cd, and 103.4% for As, respectively. The best result was obtained through digestion using an acid mixture ($HNO_3$/$H_2O_2$, 6:2). Hg content was measured using a mercury analyzer. As a result, the contents of Hg and Cd in samples were lower than those of Pb and As. The average contents of Pb were 0.009 mg/kg in beef, 0.010 mg/kg in pork, 0.006 mg/kg in chicken, 0.007 mg/kg in duck, 0.005 mg/kg in ham, and 0.009 mg/kg in sausage. The average Cd contents were 0.0004 mg/kg in beef, 0.0004 mg/kg in pork, 0.0005 mg/kg in chicken, 0.0012 mg/kg in duck, 0.0015 mg/kg in ham, and 0.0019 mg/kg in sausage. The average As contents were 0.016 mg/kg in beef, 0.004 mg/kg in pork, 0.021 mg/kg in chicken, 0.010 mg/kg in duck, 0.014 mg/kg in ham, and 0.018 mg/kg in sausage. The average Hg contents were 0.713 ${\mu}g/kg$ in beef, 0.902 ${\mu}g/kg$ in pork, 0.710 ${\mu}g/kg$ in chicken, 0.796 ${\mu}g/kg$ in duck, 1.141 ${\mu}g/kg$ in ham, and 1.052 ${\mu}g/kg$ in sausage. Based on the results of the National Health and Nutrition Survey 2005, the levels of dietary exposure to heavy metal contaminants in meat and meat products were compared with the provisional tolerable weekly intake(PTWI) established by the Joint FAO/WHO Expert Committee on Food Additives. The average dietary exposure of the general population from meat and meat products was 0.03-0.2% of PTWI for Pb, Cd, As, and Hg, which indicates a safe level for public health at present.

Heavy Metal Contents in Soils and Vegetables in the Plastic Film House (시설재배지(施設栽培地) 토양(土壤) 및 채소류중(菜蔬類中) 중금속함량(重金屬含量) 조사(調査))

  • Jung, Goo-Bok;Jung, Ki-Yeol;Cho, Guk-Hyun;Jung, Beung-Gan;Kim, Kyu-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.2
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    • pp.152-160
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    • 1997
  • In order to monitor the content of heavy metals of soil and vegetable in the plastic film house, five hundred and twenty two soil, and 147 vegetable samples grown under plastic film house were collected for the analysis of heavy metals. The average contents of Cd, Cu, Pb, Zn and As in surface soil were 0.208, 3.69, 2.49, 23.3 and 0.65mg/kg, respectively. Cu and Zn contents of the soil were higher than those values measured for upland soils in 1989, however, these contents were lower than "Countermeasure values" (Cd:4, Cu:125, Pb:300, and As:15mg/kg in soil) for soil contamination indicators described in Soil Environmental Conservation Act of Korea(1996). The contents of Cd, Cu and Zn increased with increasing years of cultivation. The contents of Cd, Cu, and Zn in soils received pig manure compost were higher than those received the poultry or barn yard manure compost. The average contents of Cd, Cu, Pb, Zn and As in fresh vegetable plants ranged from 0.015 to 0.047, 0.341 to 0.802, 0.080 to 0.356, 1.08 to 8.04 and 0.021 to 0.059mg/kg, respectively.

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