Browse > Article
http://dx.doi.org/10.5764/TCF.2018.30.1.29

A Study on the Anionisation of Cotton Fabric  

Bae, Do Gyu (Department of Bio-fibers and Materials Science, Kyungpook National University)
Lee, Tae Jung (Department of Bio-fibers and Materials Science, Kyungpook National University)
Publication Information
Textile Coloration and Finishing / v.30, no.1, 2018 , pp. 29-37 More about this Journal
Abstract
Cotton has no adsorption ability for the cationic dye and heavy metal but, if anionized cotton can be made, it will be possible. In this study, to enable the anionisation of cotton fabric, it was modified using sodium vinylsolfonate(SV) as the anionisation reagent, employing a pad-dry-cure(PDC) technique. The effects of curing time, treatment concentrations of urea, sodium hydroxide and SV on the weight increase were experimented and then, the physical characterizations of sulfoethyl cotton(SEC) depending on the finishing conditions were estimated, thus the application possibility of SV as anionisation reagent was investigated. It was not much changed by anionisation except wrinkle recovery. And the structure of SEC was elucidated by Raman and NMR spectoscopy. The feasibility of using Raman and NMR spectroscopy with the band at $1,043cm^{-1}$, and 50.5ppm, respectively as marker band to determine sulfoethyl group of SEC was reported. The total degree of SV substitution(DSV) was determined via elemental analysis. SEC with diverse total DSV up to 0.066 was obtained. In the thermal decomposition(pyrolysis) by DSC, it can be found that the pyrolysis temperature was about $30^{\circ}C$ lower than that of non-treated cotton fabric.
Keywords
cotton fabric; anionisation; sodium vinylsulfonate; sulfoethyl cotton; Raman; NMR; DSC; elemental analysis;
Citations & Related Records
연도 인용수 순위
  • Reference
1 L. Fang, X. Zhang, and D. Sun, Chemical Modification of Cotton Fabrics for Improving Utilizatio of Reactive Dyes, Carbohydrate Polymers, 91, 363(2013).   DOI
2 P. Ghosh and D. Das, Modification of Cotton by Acrylic acid(AA) in the Presence of $Na_{2}H_{2}PO_{4}\;and\;K_{2}S_{2}O_{8}$ as Catalysts under Thermal Treatment, European Polymer J., 36, 2505(2000).   DOI
3 C. Pisuntornsug, N. Yanumet, and E. A. O'Rear, Surface Modification to Improve Dyeing of Cotton Fabric with a Cationic Dye, Coloration Technology, 118, 64(2002).   DOI
4 M. K. Kim, S. H. Yoon, T. K. Kim, and Y. J. Lim, The Adsorption Properties of Heavy Metal Ions on to Cotton Fabrics Treated with Reactive Anionic Agent, Textile Coloration and Finishing, 17(1), 20(2005).
5 H. T. Zhou, H. Xing, B. W. Wu, A. Q. Cao, and J. X. Xiao, Hydrotrope-Induced Enhancement of Room Temperature Surface Activity for High Krafft Point Fluorinated Surfactants, J. of Surface and Detergent, 19, 1199(2016).   DOI
6 D. Myers, "Surfactant Science and Techlogy 3rd. ed.", John Wiley and Sons, Inc., New Jersey, pp. 307-308, 2006.
7 H. G. Houlton and H. V. Tartar, Raman Spectra of Sodium Alkyl Sulfonates and Sulfinates, J. of the American Chemical Society, 60(3), 544(1938).   DOI
8 K. Zhang, E. Brendler, K. Gebauer, M. Grunder, and S. Fischer, Synthesis and Characterization of Low Sulfoethylated Cellulose, Carbohydrate Polymers, 83, 616(2011).   DOI
9 P. Zhu, S. Sui, B. Wang, K. Sun, and G. Sun, A Study of Pyrolysis and Pyrolysis Products of Flame-retardant Cotton Fabrics by DSC, TGA, and PY-GC-MS, J. of Analytical and Applied Pyrolysis, 71, 645(2004).   DOI
10 M. L. Joseph, "Introductory Textile Science", Sauders College Publishing, New York, pp.38-39, 1981.
11 E. R. Trotman, "Dyeing and Chemical Technology of Textile Fibers", Charles Griffin and Company Ltd, London, pp.48-51, 1975.
12 M. Rym, M. Farouk, and E. M. Bechir, Dyeing Properties of Cationized and Noncationized Cotton Fabrics Dyed with Vitis vinifera L. leaves Extract, The J. of the Textile Institute, 107(4), 525(2016).   DOI
13 J. Borsa, V. Ravichandran, and S. K. Obendorf, Distribution of Carboxyl Groups in Carboxymethylated Cotton Fibers, J. of Applied Polymer Science, 72(2), 203(1999).   DOI
14 E. S. Lee and H. J. Kim, Durable Press Finish of Cotton/polyester Fabricswith 1,2,3,4-butanetetracarboxylic Acid and Sodium Propionate, J. of Applied Polymer Science, 81(3), 7(2001).
15 S. Fu, M. J. Farrell, and P. J. Hauser, Optimising the Anionisation of Cottonwith 3-chloro-2-hydroxy-1-propanesulphonic Acid Sodium Salt for Dyeingwith Basic Dyes, Coloration Technology, 133, 194(2017).   DOI
16 C. Chen and C. C. Chen, Crosslinking of Sulfonated Cotton Cellulose Part II: Dyeing Kinetics of a Basic Dye on Crosslinked Fabrics from a Finite Bath, Textile Research J., 70(4), 311(2000).   DOI