• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.335-341
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• 2016

In this study, impurity effects on diffusive-convection flow fields by physical vapor transport under terrestrial and microgravity conditions were numerically analyzed for the mixture of $Hg_2Cl_2-I_2$ system. The numerical analysis provides the essence of diffusive-convection flow as well as heat and mass transfer in the vapor phase during the physical vapor transport through velocity vector flow fields, streamlines, temperature, and concentration profiles. The total molar fluxes at the crystal regions were found to be much more sensitive to both the gravitational acceleration and the partial pressure of component $I_2$ as an impurity. Our results showed that the solutal effect tended to stabilize the diffusive-convection flow with increasing the partial pressure of component $I_2$. Under microgravity conditions below $10^{-3}g_0$, the flow fields showed a one-dimensional parabolic flow structure indicating a diffusion-dominant mode. In other words, at the gravitational levels less than $10^{-3}g_0$, the effects of convection would be negligible.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.629-632
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• 2009

The polymeric desiccant rotor is made from the super absorbent polymer by ion modification. The moisture sorption capacity of the super desiccant polymer(SDP) is 4 to 5 times larger than those of common desiccant meterials such as silica gel or zeolite. It is also known that SDP can be regenerated even at the relatively low temperature. To fabricate the desiccant rotor, firstly the SDP was laminated by coating the SDP on polyethylene sheet. Then corrugated and rolled up into a rotor. The diameter, the depth, the dimensions of the corrugated channel, etc. were pre-determined from numerical simulation on the heat and mass transfer in the desiccant rotor. The dehumidification performance was tested in a climate chamber. The relevant tests were carried out at the process air inlet temperature of $32^{\circ}C$, the regeneration air inlet temperature of $60^{\circ}C$ and the inlet dew-point temperature of both the process air and the regeneration air of $18.5^{\circ}C$, when the rotation period is long, the moisture sorption is not effective. In the desiccant rotor developed in this study, the optimum rotation period is found about 350s at the regeneration temperature of $60^{\circ}C$. It was found from further experiments that the optimum rotation tends to decreases as the regeneration temperature increases. Meanwhile, the outlet temperature of the process air deceases monotonically as the rotation period increases.

• Korean Journal of Food Science and Technology
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• v.18 no.1
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• pp.61-65
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• 1986

This study was performed to examine the drying characteristics of apples at various drying conditions. Air velocity has no effect on the drying rate except the constant rate period. In this experiment the diffusion coefficients of moisture in the apple tissue were in the range of $1.1470-2.2148{\times}10cm^2/sec$. As a result of balance of heat and mass transfer during the falling rate period. an empirical equation based on Fick's law was obtained as follows; $log{\Delta}t\;=\;log\;t_o\;-\;D{\frac{{\pi}^2{\theta}}{4d.}}$ This equation can be used to calculate the temperature of apples during the falling rate period, provided the diffusion coefficients of apple are known. The experimental values of the internal moisture distribution during apple dehydration were nearly in accord with the theoretical values.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.5
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• pp.460-469
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• 2010

To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.

• Journal of the Korean Society of Propulsion Engineers
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• v.27 no.1
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• pp.49-57
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• 2023

The autogenous pressurization has been widely adopted for propulsion systems of next-generation reusable rockets due to its low cost and high reliability. The autogenous pressurization has a simple structure, but an understanding of the heat and mass transfer occurring inside the tank is essential. For this reason, a simulation test of the autogenous pressurization was conceived. The experiment equipment was constructed based on overseas pressurization test facilities cases and expert advice. Unlike the actual autogenous pressurization system, the propellant tank was insulated to exclude external influences. The pressurized gas supply line and the propellant pipe were separated. Using the manufactured autogenous pressure experiment equipment, it is possible to evaluate the condensation phenomenon of pressurants in cryogenic propellants, comparison of the efficiency of pressurization using helium and evaporated gas and the pressurization capacity according to the temperature of pressurant.

• Clean Technology
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• v.20 no.3
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• pp.298-305
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• 2014

Ash included in coal can cause environmental pollution and it can decrease efficiency of mass and heat transfer by getting scorched and stick in the facilities operated at high temperature. To solve this problem, a feasibility study on pulverized coal fired power plant and integrated gasification combined cycle (IGCC) using the AFC (Ash-Free Coal) as well as the development to remove the ash from the coal was conducted. In this research, optimization of operating condition was proposed by using sensitivity analysis of ASPEN $Plus^{(R)}$ to apply the coal containing under the 200 ppm ash for integrated gasification combined cycle. Particularly, the coal gasification process was classified as three parts : pyrolysis process, volatile matter combustion process and char gasification process. The dimension and operating condition of 1.5 ton/day class non-slagging gasifier are reflected in the coal gasification process model.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.5
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• pp.474-480
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• 2011

Space Imaging Sensor operated on LEO is affected from the Earth IR and Albedo as well as the Sun Radiation. The Imaging Sensor exposed to extreme environment needs thermal control subsystem to be maintained in operating/non-operating allowable temperature. Generally, units are periodically dissipated on spacecraft panel, which is designed as radiator. Because thermal design of the imaging sensor inside a spacecraft is isolated, heat pipes connected to radiators on the panel efficiently transfer dissipation of the units. First of all, preliminary thermal design of radiating area and heater power is performed through steady energy balance equation. Based on preliminary thermal design, on-orbit thermal analysis is calculated by SINDA, so calculation for thermal design could be easy and rapid. Radiators are designed to rib-type in order to maintain radiating performance and reduce mass. After on-orbit thermal analysis, thermal requirements for Space Imaging Sensor are verified.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.2
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• pp.288-301
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• 2002

A vacuum freeze drying experiment of skim milk solution in a cylindrical container is conducted to investigate the multi-dimensional drying characteristics of the process during the primary drying stage. Temperature histories at several positions are measured under the same process condition that is carefully controlled. Then the measured temperature histories at different positions are combined to produce instantaneous temperature distribution fields inside the cylindrical container. Along with the temperature measurement, the mass reduction history of the skim milk solution is also measured. From the measured temperature distribution curved configurations of sublimation interfaces and 2-dimensional heat transfer is inferred. The freeze drying under the present experimental setup is simulated with a calculation program that is based on a finite volume method with a moving grid system. Good agreements between the numerical and experimental results are observed. The present experimental results and the numerical approaches can be useful information in developing the analysis tools for practical vacuum freeze drying processes.

• Journal of the Korean Institute of Gas
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• v.27 no.1
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• pp.78-85
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• 2023

Fixed-bed reactor Computational Fluid Dynamics (CFD) simulation of methanol steam reforming reaction was performed using the intrinsic kinetic data of the copper-impregnated hydrotalcite catalyst. The activation energy of the copper hydrotalcite catalyst obtained from the previous study results was 97.4 kJ/mol, and the pre-exponential was 5.904 × 10¹⁰. Process simulation was performed using the calculated values and showed a similar tendency to the experimental results. And the conversion rate according to the change of the reaction temperature (200 - 450 ℃) and the molar ratio of methanol and water was observed using the intrinsic kinetic data. In addition, mass and heat transfer phenomena analysis of a commercial reactor (I.D. 0.05 - 0.1m, Length 1m) was predicted through axial 2D Symmetry simulation using the power law model of the above kinetic constants.

• Solar Energy
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• v.18 no.3
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• pp.185-195
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• 1998

The high viscosity of a LiCl(lithium chloride) solution as an absorbent in a solar energy regenerator causes a channeling phenomenon on the solar powered absorber plate surface when the solution is trickling down for regenerating itself. As this channeling phenomenon affects badly the heat and mass transfer, it is pertinent that this phenomenon be studied. Since regenerating performance of the solar energy regenerator depends on how the solution uniformly flows on the plate surface, an experiment on the structure of the plate surface for a model regenerator was conducted. Various shapes and structures of the plat surface down which the LiCl solution trickled were tested, and it was found that a tiered surface showed the highest water evaporation rate leaving more potential energy concentrating LiCl on the plate. It was also observed that the water evaporation rate depended largely on the pitch and height of the disturbing rods. In addition, the wider the contact area is and the longer the solution's flow time, the better the solar energy regenerator's performance.