• 제목/요약/키워드: hazardous substances

검색결과 519건 처리시간 0.027초

암모니아 누출사고 시 주민대피 및 알림 결정을 위한 피해영향거리 산정식 개발 연구 (A Study on Development of Damage Impact Distance Calculation Formula to Determine Evacuation and Notification of Residents in Case of Ammonia Release Accident)

  • 김현섭;전병한;이명지;윤정현;이현승;정웅열;조정아
    • 한국산학기술학회논문지
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    • 제21권10호
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    • pp.308-316
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    • 2020
  • 본 연구에서는 암모니아 누출사고 발생 시 지방자치단체에서 신속하게 주민대피 및 알림을 결정할 수 있도록 화학물질사고대응정보시스템(CARIS)을 활용한 피해영향거리 산정식을 도출하고자 하였다. 암모니아는 화학물질관리법상 사고대비물질이자 화학물질안전원에서 정한 주민대피 대비물질 16종 중 하나이며, 2014년부터 2019년 기간 동안 화학사고가 58건으로 가장 빈번하게 발생한 화학물질이다. 연구에서는 미국환경보호국(EPA)에서 지정하고, 유아 및 어린이, 노인 등의 취약집단을 포함하며 일반 인구에 적용 가능한 급성노출기준인 AEGL을 기준으로 암모니아의 노출시간에 따른 피해영향거리 산정식을 도출하였다. AEGL-3 농도기준에 따른 위험지역 구분과 AEGL-2 농도기준에 따른 준위험지역을 구분을 할 수 있는 농도별, 노출시간별 산정식을 도출하였으며, 도출된 산정식으로 얻어진 피해영향거리 수치와 화학물질사고대응정보시스템의 피해영향거리 수치간의 상대표준편차를 비교한 결과 0~2 % 범위인 것으로 조사되었다. 따라서 지방자치단체에서는 실제 사고 현장 상황을 고려하고 연구에서 도출된 적합한 피해영향거리 산정식을 적용하여 사고 원점 인근의 주민을 소산하거나 실내대피 알림 등의 보호조치에 활용될 수 있도록 하여야 한다.

한국인 상용 식품 중 수은 함량 데이터베이스 구축 (Development of a mercury database for food commonly consumed by Koreans)

  • 김성아;신상아;이정원;정효지
    • Journal of Nutrition and Health
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    • 제47권5호
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    • pp.364-373
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    • 2014
  • 본 연구는 문헌검색을 통해 우리나라 상용 식품의 수은 함량 데이터베이스를 구축하기 위해 수행하였고, 식품 섭취량의 95%를 포함하는 완성도가 높은 데이터베이스를 구축하였다. 2007~2009년 국민건강영양조사 식품 섭취량 조사 결과를 기반으로 대상 식품을 선정하였고, 국내에서 식품 중 수은 함량을 분석한 문헌을 고찰하여 수은 함량값을 수집하였다. 미국 농무성의 데이터 질적 평가시스템을 적용하여 수집된 문헌의 함량자료를 선택했고, 함량값이 없는 식품은 식재료의 수분함량 차이를 고려하여 대체값을 적용하였다. 구축된 데이터베이스는 총 702개의 식품 중 356개의 식품에 대한 수은 함량값을 포함하였고 (50.7%), 대상자들이 섭취한 식품 섭취량으로는 95.1%에 달하는 식품을 포함하는 것으로, 질적으로 양적으로 완성도가 높은 것으로 평가되었다. 본 연구의 결과는 향후 식품을 통한 수은 노출량 추정 및 위해성 평가에 활용될 수 있으며, 본 연구의 데이터베이스 구축 방법론은 식품을 통해 노출되는 다른 유해물질의 함량데이터베이스를구축하는 데에 적용할 수 있을 것이다.

한방처방의 전탕 전과 후의 위해물질 농도변화 -보양.보음 처방을 중심으로 - (Concentration of Hazardous Substances of before/after a Decoction in Prescription of Herbal Medicine -In Prescription of tonify Yang and tonify Yin-)

  • 서창섭;황대선;이준경;하혜경;천진미;엄영란;장설;신현규
    • 대한한의학방제학회지
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    • 제17권2호
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    • pp.53-63
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    • 2009
  • Objective : To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after a decoction. Methods : The heavy metal contents before/after a decoction were measured by Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and mercury analyzer. In order to analyze pesticides in 4 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide ($SO_2$) were performed by Monier-Williams distillation method. Results: 1. The mean values of heavy metal contents (mg/kg) for the samples were as follows: Jaeumganghwa-tang (before decoction - Pb; 1.190, Cd; 0.184, As; 0.099 and Hg; 0.028, after decoction - Pb; .033, Cd; 0.003, As; 0.005 and Hg; 0.001), Yukmijiwhang-tang (before decoction - Pb; 0.484, Cd; 0.133, As; 0.053 and Hg; 0.009, after decoction - Pb; 0.065, Cd; 0.008, As; 0.007 and Hg; not detected), Bojungikgi-tang (before decoction - Pb; 0.863, Cd; 0.197, As; below 0.016 and Hg; 0.011, after decoction - Pb; 0.071, Cd; 0.009, As; 0.004 and Hg; 0.001) and Ssangwha-tang (before decoction - Pb; 1.511, Cd; 0.212, As; 0.094 and Hg; 0.016, after decoction - Pb; 0.029, Cd; 0.006, As; 0.005 and Hg; 0.0004). 2. Contents (mg/kg) of sulfur dioxide ($SO_2$) before a decoction in Jaeumganghwa-tang, Yukmijiwhang-tang and Ssangwha-tang exhibited 22.7, 107.3 and 5.5, respectively. However, contents of sulfur dioxide after a decoction in all samples were not detected. 3. Contents (mg/kg) of residual pesticides before/after a decoction in all samples were not detected. Conclusion : These results will be used to establish a criterion of heavy metals, residual pesticides and sulfur dioxide.

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성동구내 어린이집 원아 부모의 소아 한방치료에 대한 인식 및 이용에 관한 조사 연구 (A Survey on Parent's Recognition and Utilization Patterns of Oriental Medical Care of Preschool Students in Seong-Dong district)

  • 박유진;이슬지;윤지연;명성민
    • 대한한방소아과학회지
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    • 제25권1호
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    • pp.90-110
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    • 2011
  • Objectives: The purpose of this study is to examine the parental recognition and utilizing patterns of oriental medical care in children who live in Seong-Dong district. Methods 802 day-care center children's parents participated in the survey on recognition and utilizing patterns of oriental medical care, and 702 of the surveys were analyzed. Results: 1. 38.33% has received previous oriental medical treatments and most were received at the children's age under 12-24 months. Majority of the treatments took place in the clinical settings. By recommendation, some also received their treatment at the medical centers. One of the reasons why they receive oriental medical treatments was that they prefer to balance their treatment with the orental medical treatments along with the western's. 2. 53.85% of those who received oriental medical treatments were satisfied with their treatments. The effective treatment results were the major reason for the satisfaction. 3. 49.56% of those who had oriental medical treatments chose specific oriental medical facilities for the children's ailment. Most specific oriental medical facilities were local oriental medical clinics. Reputation fame were the main reason in choosing the clinics. 4. In 2009, 55.26% had received care in the specific oriental medical clinics for the diseases, such as respiratory symptoms, systemic symptoms, gastrointestinal symptoms, skin problems, neurological and psychiatric disease for infants, and respiratory symptoms, gastrointestinal symptoms, systemic symptoms, skin problems, neurological and psychiatric symptoms, urinary symptoms and musculoskeletal symptoms for toddlers. 5. The average duration of herbal treatment were 7-14 days, preferably 4-6 days, and preferred number of medical visits were once a week on Saturdays and preferred day for night cares were on Friday nights. Average treatment fee per treatment was less than 10,000 won which coincided with the preferred treatment fee per visit. 6. The very first medical institutions chosen by parents once their children are ill are the following; Western medical institutions, western medical clinics, pharmacies, oriental medical clinics, health centers, and lastly, oriental medical institutions. The major concerns in receiving oriental medical cares include pesticides in herbs and hazardous substances in heavy metals. Preferred form of oriental medicine was decoction, the negative feedback of oriental medicine was mostly due to the bitter taste of the oriental herbal decoctions. Preferred frequency of intake was twice a day with less than 10cc~20cc per single intake. Conclusions: Taken all together, we conclude that the growing recognition of Oriental Pediatric medicine is needed among parents.

농약등록기준 준수 현황과 수도 및 엽채소류 사용량 조사 (Survey on Compliance of Pesticide Registration Standard and Pesticide Usage of Paddy Rice and Leaf Vegetables in Korea)

  • 김경선;김광호;김남숙;임양빈;이희동;김효경;유오종;오병렬;임건재;류갑희
    • 농약과학회지
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    • 제10권3호
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    • pp.183-188
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    • 2006
  • 농약 등록 후에 농업 생산 현장에서 사용되는 농약에 대한 사용실태 및 작물별 단위면적당 사용량을 조사하기 위하여 2003년부터 2004년까지 작물별 주산단지별, 재배면적을 감안하여 292명의 농가를 선정하여 조사하였다. 농약안전사용기준 준수사항은 벼, 엽채소류 재배농가 모두가 대체적으로 잘 지키고 있었다. 조사농민의 대부분은 농약의 선택정보와 구매결정은 시판상이나 농협판매담당자의 권고에 의하여 결정하고 있었다. 작물별 단위면적당 농약사용량은 벼 5.51 kg $ha^{-1}$, 노지배추 3.91 kg $ha^{-1}$, 시설배추 2.93 kg $ha^{-1}$, 상추 0.76 kg $ha^{-1}$, 시금치 0.55 kg $ha^{-1}$, 잎들깨 1.34 kg $ha^{-1}$, 부추 4.83 kg $ha^{-1}$, 열무 0.42 kg $ha^{-1}$로 조사되었다. 벼, 상추, 시금치, 잎들깨에서는 사용량이 4년 전에 비해 감소하였으나 배추는 농약사용량이 증가하였다.

실내사육조건에서 한국산 물벼룩 종간 life cycle 비교 (Comparison of Life Cycle of Several Korean Native Freshwater Cladocerans in Laboratory Culture Conditions)

  • 김병석;박연기;박경훈;신진섭;김진화;윤성명;안용준
    • 농약과학회지
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    • 제10권3호
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    • pp.196-200
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    • 2006
  • 국내서식 물벼룩종을 이용한 표준생태독성시험법 개발을 위한 기초연구로서 국내환경에서의 대표성, 실내사육가능성 및 독성시험에 적합한 크기 등을 고려하여 선발된 4종의 한국산 물벼룩 Daphnia sp., Daphnia obtusa, Moina macrocopa, S.imocephalus vetulus과 Daphnia magna에 대한 실내사육조건에서의 life cycle을 조사하였다. 국내산 물벼룩 4종과 D. magna에 대한 실내사육조건에서의 전 생애에 걸친 생육특성을 조사한 결과 D. magna가 어미 1마리당 평균 358마리의 새끼를 출산하였고 국내산 물벼룩 중에는 Daphnia sp.가 297마리의 새끼를 출산하여 가장 출산새끼수가 많았으며 그 다음으로는 M. macrocopa, S. vetulus, D. obtusa 순이었다. 평균수명은 D. magna가 50일로 가장 길었으며 국내산 물벼룩 중에는 Daphnia sp.가 39일로 조사되었으며 그 다음으로는 S. vetulus, D. obtusa M. macrocopa, 순이었다. 특히 M. macrocopa의 경우 번식력이 우수하면서도 세대기간이 짧아 기존의 번식독성시험법에서 제시하는 21일보다 짧은 10일 정도의 단기간에 번식영향을 평가할 수 있을 것으로 판단된다.

OECD 대량생산화학물질 위해성평가 및 대책 (Risk Assessment in OECD High Production Volume Chemicals Program and its Countermeasure)

  • 김명진;배희경;최연기;김미경;구현주;송상환;최광수
    • 환경영향평가
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    • 제14권5호
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    • pp.347-353
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    • 2005
  • The risk assessment is the qualitative or quantitative evaluation of the risk posed to human health and the environment by the actual or potential presence or release of hazardous substances, pollutants or contaminants. The environmental impact assessment (EIA) is assessed by the environmental criteria, and risk assessment is assessed by the risk rate. Risk rate based on dose-response values may not be easy to apply on regulatory basis like EIA for uncertainty. Internationally there is an example of OECD program. Risk assessment of High Production Volume (HPV) Chemicals has started since the OECD Program with the 1990 Council Act on the Co-operative Investigation and Risk Reduction of Existing Chemicals. These HPV chemicals include all chemicals produced or imported at levels greater than 1,000 tonnes per year in at least one Member country or in the European Union region. The SIDS called the Screening Information Data Set is regarded as the minimum information needed to assess an HPV chemical to determine whether any further work should be carried out or not. All the data elements of SIDS including assessment for environment and health are prepared as three formats of the full SIDS Dossier, the SIDS Initial Assessment Report (SIAR), and the SIDS Initial Assessment Profile (SIAP) of an HPV chemical. In 1998 the global chemical industry through the International Council of Chemical Associations (ICCA) has joined to work with OECD. The OECD has assessed approximately 1,000 chemicals from 1991 through 2004 with ICCA. Till the February of 2005, 592 chemicals of those chemicals completed SIDS reports. Member countries have been targeted the goal of 1,000 new chemicals from 2005 to 2010 and Korea shared 36 chemicals from the 1,000 new chemicals. Currently Korea has completed SIDS reports of 7 chemicals among sponsored 24 chemicals. In conclusion SIDS project will be linked to national program for outputs application with more reliable production. Both the OECD and industry will carry out their commitment to complete assessments for more and the remaining chemicals assessment. The major outputs will contribute to cope with international chemical management.

반도체 FAB근무에 대한 정량적 노출지표 개발 (Development of Quantitative Exposure Index in Semiconductor Fabrication Work)

  • 신규식;김태훈;정현희;조수헌;이경호
    • 한국산업보건학회지
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    • 제27권3호
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    • pp.187-192
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    • 2017
  • Objectives: It is difficult to identify exposure factors in the semiconductor industry due to low exposure levels to hazardous substances and because various processes take place in fabrication (FAB). Furthermore, a single worker often experiences a variety of job histories, so it is difficult to classify similar exposure groups (SEG) in the semiconductor industry. Therefore, we intend to develop a new exposure index, the period of working in FAB, that is applicable to the semiconductor industry. Methods: First, in specifying the classification of jobs, we clearly distinguished whether they were FAB workers or non-FAB workers. We checked FAB working hours per week through questionnaires administered to FAB workers. We derived an exposure index called FAB-Year that can represent the period of working in FAB. FAB-Year is an index that can quantitatively indicate the period of working in FAB, and one FAB-Year is defined as working in FAB for 40 hours per week for one year. Results: A total of 8,453 persons were surveyed, and male engineers and female operators occupied 90% of the total. The average total years of service of the subjects was 9.7 years, and the average FAB-Year value was 6.8. This means that the FAB-working ratio occupies 70% of total years of service. The average FAB-Year value for female operators was 8.4, for male facility engineers it was 7.7, and for male process engineers it was 3.5. A FAB-Year standardization value according to personal information (gender, job group, entry year, retirement year) for the survey subjects can be calculated, and standardized estimation values can be applied to workers who are not participating in the survey, such as retirees and workers on a leave of absence (LOA). Conclusions: This study suggests an alternative method for overcoming the limitations on epidemiological study of the semiconductor industry where it is difficult to classify exposure groups by developing a new exposure index called FAB-Year. Since FAB-Year is a quantitative index, we expect that various approaches will be possible in future epidemiological studies.

식품오염물질 미래 연구방향 예측 (Forecast of the Field of Research on Food Contaminants in Korea)

  • 성동은;박성국;김미혜;오상석
    • 한국식품위생안전성학회지
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    • 제28권2호
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    • pp.99-107
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    • 2013
  • 식품오염물질에 관련한 연구가 많이 진행되었지만 대부분 단기적 과제이었기에 식품오염물질 관리를 위한 종합적이고 체계적인 연구가 필요하다. 본 연구에서는 식품오염물질 향후 연구방향을 제안하기 위하여 델파이 조사를 실시하였으며, 중요도 및 시급성을 고려하여 우선순위를 설정하였다. 학계, 연구기관, 정부기관, 기업 등 다양한 소속에 있는 50명의 전문가를 대상으로 식품안전과 관련한 개방형 질문을 하였으며, 161개의 필요연구항목을 도출하였다. 이를 분류하여 5개 분야, 42개 항목으로 구성된 설문지를 작성하였다. 5개 분야는 '식품오염물질 통합관리 시스템', '환경유래 식품오염물질 안전관리', '식품 중 오염된 자연독소 안전관리', '조리가공 중 생성된 식품유해물질 안전관리', '국내외 식품오염물질 안전관리 협력체계 구축 및 교육 홍보 방안' 이었다. 전문가들이 답한 설문지(30/50 응답)를 분석하여 필요연구의 우선순위를 설정하였으며, 전문가들의 합의단계를 거쳐(24/30 응답) 이를 확정하였다. 본 설문조사 결과는 식품오염물질 안전관리를 위한 연구방향을 설정하기 위한 기초자료로 사용할 수 있을 것이라 사료된다.

합금철 제조공장 출탕 노동자의 유해인자 노출 (A Study on Exposure to Hazard Factors in Furnace Worker in Ferro-Alloy Manufacturer Factory)

  • 차원석;김부욱;최병순
    • 한국산업보건학회지
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    • 제27권4호
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    • pp.302-312
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    • 2017
  • Objectives: In this study, an evaluation of the working environment of furnace workers was performed and the work-relatedness of the occupational diseases were examined Methods: In this study, two electric furnaces at a single casting business site producing manganese-based iron alloy were selected, and occupational exposures to hazardous substances were evaluated for furnace workers and furnace worker assistants. Results: As a result, total dust concentration were $0.407{\sim}3.001mg/m^3$ and respirable dust concentration were $0.196{\sim}0.584mg/m^3$. The highest concentration of crystalline silica was $0.079mg/m^3$ In the case of Masato and Sosuckwhoi crystalline silica, they contained 90.85% and 4.17% respectively. Manganese concentration was the highest at a $0.205mg/m^3$ maximum. The average of black carbon is $11.56{\mu}g/m^3$ and the maximum concentration is $604.23{\mu}g/m^3$. PAHs concentration was the highest at a $78.301{\mu}g/m^3$ of naphthalene. The concentration of carbon monoxide was 18.82 ppm(total average 3.89 ppm) during pouring, and the maximum is 131 ppm. The formaldehyde concentration was 0.003 to 0.007 ppm. Conclusions: It seems that conditions in the past were worse, since casting has recently been performed only twice per day for about 20 minutes, reducing the amount of pouring, and local exhaust systems have been installed one-by-one. In addition, it was judged that the past exposure levels were higher considering the points measured on the back-side due to the risk of damage to the individual samples. It was found that operators could be exposed to high concentrations of crystalline silica, and that they were also exposed to high concentrations of metal(fume) and carbon monoxide during pouring. Therefore, there is a risk that occupational diseases such as lung cancer and COPD may occur with long-term work in such a process.