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Effects of Ultrasonic Treatment and Particle Size on Mechanical Properties of Waste Polypropylene/WGRT Composites (초음파 처리와 분말 크기가 재생 폴리프로필렌/폐타이어 분말 복합체의 기계적 특성에 미치는 영향)

  • Kim, Donghak;Kim, Seonggil;Lee, Minji;Park, Jong-Moon;Oh, Myung-Hoon;Kim, Bong-Suk;Kim, Jinkuk;Bang, Daesuk
    • Resources Recycling
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    • v.24 no.2
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    • pp.36-45
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    • 2015
  • In this study, various sizes of waste ground rubber tire (WGRT) were devulcanized by a single screw extruder equipped with a sonicator in front of the die, and waste PP and devulcanized waste ground rubber tire (DWGRT) composites were prepared by an intermeshing co-rotating twin screw extruder. The crosslink density and percent devulcanization of WGRT and DWGRT for 40, 80 and 140 meshes were calculated. The mechanical properties of the composites were compared with each other. The effect of SEBS-g-MA as a compatibilizer was investigated on mechanical properties of both waste PP/WGRT and waste PP/DWGRT composites. The crosslink density was decreased with decreasing the WGRT size. On the other hand, the percent devulcanization was increased by adding the smaller size of WGRT. Also, tensile strength, impact strength and elongation at break of the composite with DWGRT were higher than those with WGRT. Especially, mechanical properties of the composites were significantly increased by adding the smaller size of WGRT and DWGRT. Addition of SEBS-g-MA into both waste PP/(D)WGRT composites exhibited better impact strength and elongation at break than the composites themselves.

Development of ultrafine grained silicon carbide by spark plasma sintering (스파크 플라즈마 소결에 의한 초미세 결정립 탄화규소의 개발)

  • 조경식;이광순;백성호;이상진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.4
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    • pp.176-181
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    • 2003
  • Rapid densification of a SiC powder with additive 0.5 wt% $B_4$C was conducted by spark plasma sintering (SPS). The unique features of the process are the possibilities of using very fast heating rate and short holding time to obtain fully dense materials. The heating rate and applied pressure were kept to be $100^{\circ}C$/min and 40 MPa, while sintering temperature and soaking time varied to 1800, 1850, 1900 and $1950^{\circ}C$ and 10, 20 and 30 min, respectively. All of the SPS-sintered specimens at $1950^{\circ}C$ reached near-theoretical density. The XRD found that 3C-to-6H transformation at $1850^{\circ}C$. The microstructures of the rapidly densified SiC ceramics consisted of duplex microstructure with ultrafine equiaxed grains under 2 $\mu\textrm{m}$ and elongated grains of 0.5∼2 $\mu\textrm{m}$ wide, length 3∼10 $\mu\textrm{m}$. The biaxial strength increased with the increase of sintering time. Strength of 392.7 MPa was obtained with the fully densified specimen sintered at $1950^{\circ}C$ for 30 min, in agreement with the general tendency that strength increases with decreases pore. On the other hand, the fracture toughness shows the value of 2.17∼2.34 MPa$.$$m^{1/2}$ which might be due to the transgranular fracture mode.

Studies on the Characteristics of EVA Foam by Solvent Treatment (용매 처리에 의한 EVA foam 표면 특성에 관한 연구)

  • Chun, Jae Hwan;Kim, Gu Ni;Hong, Soon Yeong;Yoo, Chong Sun;Oh, Sang Taek
    • Journal of Adhesion and Interface
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    • v.2 no.3
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    • pp.9-15
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    • 2001
  • To estimate the effect of the surface state of the EVA foam on an adhesion, the surface was treated with solvents having different values of a solubility parameter and a surface tension. The morphology and the contact angle were measured by SEM and contact angle tester, respectively. The value of the critical surface tension(${\gamma}_{c,0}$) of the EVA foam calculated by Zismann plot was 27.08 dyne/cm. The surface state and the ${\gamma}_c$ of the EVA foam were changed by solvent treatment. The swelling ratio of EVA foam was influenced by solubility parameter of a solvent, on the other hand the degree of change in the surface state was dependent on a surface tension of a solvent. When a surface tension of solvent. When a surface tension of solvent is lower than ${\gamma}_{c,0}$ of the EVA foam, the wettability of a solvent was good and the surface state was greatly changed. The adhesion strength of EVA foam was greatly improved to above 600% as compared to that of the untreated one. As the ${\gamma}_c$ of EVA was closed to the surface tension of the primer, the good adhesion strength was obtained.

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R-Curve Behavior and Mechanical Properties of Al2O3 Composites Containing SiC and TiC Particles (SiC와 TiC 입자를 함유하는 Al2O3 입자복합체의 균열저항거동과 기계적 성질)

  • Na, Sang-Woong;Lee, Jae-Hyung
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.413-419
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    • 2002
  • Particulate composites of $Al_2O_3$/TiC/SiC, $Al_2O_3$/TiC and $Al_2O_3$/SiC have been fabricated by hot pressing and their R-curve behaviors and mechanical properties were investigated. $Al_2O_3$ containing 30 vol% TiC particles showed higher toughness by 8% than that for monolithic alumina and its fracture strength was increased significantly by approximately 30%. On the other hand, the addition of 30 vol% SiC of $3{\mu}m$ in $Al_2O_3$ decreased the fracture strength slightly but induced a rising R-curve behavior owing to the strong crack bridging of SiC particles. In case of $Al_2O_3$/TiC/SiC, arising R-curve behavior was also observed and the fracture toughness reached 6.6 MPa${\cdot}\sqrt{m}$ at the crack length of $1000{\mu}m$, which was lower than that of $Al_2O_3$/SiC, however, while the fracture strength was higher by about 20%. The fracture toughness seemed to be decreased as smaller TiC particles roughened the SiC interface and pullout of the SiC particles for crack bridging became less active.

The Effect of Delayed Compaction on Unconfined Compressive Strength of Soil-Cement Mixtures (지연다짐이 Soil-Cement의 압축강도에 미치는 영향)

  • 정일웅;김문기;도덕현
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.28 no.4
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    • pp.66-76
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    • 1986
  • This study was attempted to investigate the effects of delayed compaction on the unconfined compressive strengh and dry density of Soil-cement mixtures. Soil-cement construction is a time-consuming procedure. Time-delay is known as a detrimental factor to lower the quality of soil-cement layer. A laboratory test was performed using coarse and fine weathered granite soils. The soils were mixed with 7% cement at optimum moisture content and excess moisture content in part. Socondary additives such as lime, gypsum-plaster, flyash and sugar were tried to counteract the detri-mental effect of delayed compaction. The specimens were compacted by Harvard Miniature Compaction Apparatus at 0,1,2,4,6 hors after mixing. Two kinds of compactive efforts(9 kgf and 18 kgf tamper) were applied. The results were summarized as follows: 1.With the increase of time delay, the decrease rate of dry density of the specimen compacted by 9 kgf tamper was steeper than that of the specimen compacted by 18kgf tamper. In the same manner, soil-B had steeper decreasing rate of dry density than soil-A. 2.Based on the results of delayed compaction tests, the dry density and unconfined compressive sterngth were rapidly decreased in the early 2 hours delay, while those were slowly decreased during the time delay of 2 to 6 hours. 3.The dry density and unconfined compressive strength were increased by addition of 3% excess water to the optimum moisture content during the time delay of 2 to 6 hours. 4.Without time delay in compaction, the dry densities of soil-A were increased by adding secondary additives such as lime, gypsum-plaster, flyash and sugar, on the other hand, those of soil-B were decreased except for the case of sugar. 5.The use of secondary additives like lime, gypsum-plaster, flyash and sugar could reduce the decrease of unconfined compressive strength due to delayed compaction. Among them, lime was the most effective. 6.From the above mentioned results, several recommendations could be suggested in order to compensate for losses of unconfined compressive strenght and densit v due to delayed compaction. They are a) to use coarse-grained granite soil rather than fined-grained one, b) to add about 3% excess compaction moisture content, c) to increase compactive effort to a certain degree, and d) to use secondary additives like line gypsum-plaster, flyash, and sugar in proper quantity depending on the soil types.

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An Evaluation on the Shear Strength of New Type Shear Connectors for a Simple Steel-Concrete Composite Deck (초간편 강합성 바닥판 신형식 전단연결재의 전단내력 평가)

  • Yoon, Ki Yong;Kim, Sang Seup;Han, Deuk Cheon
    • Journal of Korean Society of Steel Construction
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    • v.20 no.4
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    • pp.519-528
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    • 2008
  • A simple steel-concrete composite deck is developed for preventing the lateral torsional buckling of girders that are under construction and for reducing the term of works using H-shaped rolled beams as bridge girders. A new type of shear connectors is also developed for the composite behavior between a simple steel-concrete composite deck and the rolled beams by the connecting conditions between the deck and the girders. One is a connector bolt that is lengthened and split or tightened with two nuts and the other is an I-shaped rolled beam welded on a steel plate with a number of holes punched through the web. In this study, to estimate the shear strength of those shear connectors the push-out tests are performed and the test results are compared with that of the previous studies and the codes. The result of the push-out tests of the connector bolts showed that the shear performance is similar to that of the stud connector and revealed that the equation for the shear strength in the Korean Specification of Highway Bridge overestimates the shear capacity of the connector bolt whose diameter is larger than 19mm. From the push-out tests of punched I-shaped rolled beams with varying welding amounts, with the small amount of welding, shear capacity is governed by the shear capacity of welding. On the other hand, shear capacity is governed by the size of the punched I-shaped rolled beams, regardless of the amount of welding.

Comparative Study on the Control and Removal of Formaldehyde for the Urea-formaldehyde Resin Bonded Plywood -Adhesive control- (요소수지접착합판(尿素樹脂接着合板)의 유리(遊離)포름알데히드 방산(放散)제거 및 조절방법에 대한 비교연구(比較硏究))

  • Lee, Hwa-Hyoung
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.3
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    • pp.16-23
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    • 1981
  • This study has been carried out to make a comparative study for the adhesive control methods specifically developed for application to formaldehyde. The method for formaldehyde determination used in this report is the improved chromo tropic acid determination. The results are summarized as follows: 1. The soaking treatment in aqueous solution of urea wok the most scavenging effect on the formaldehyde release from a plywood sample glued with a urea formaldehyde adhesive, and other removal treatment such as resorcinol, albumine-, and hardener-treatment gave significant reduction too. 2. In glue shear strength of dry test, 2% of resorcinol treatment and soaking treatment showed the highest strength and all the other treatment met the standard, but in hot water soaking test, 2% of resorcinol treatment gave the best results, on the other hand, adding the hardener showed the lowest strength and failed in meeting the standard. 3. Air dried moisture content of all treated plywood met the standard which calls for 13% or bellow. 4. In this comparative study, we can make a strong combination each other or go into the details of one treatment for the best result through the more study.

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Influence of Na/Al Ratio and Curing Temperature of Geopolymers on Efflorescence Reduction (Na/Al 비와 양생온도가 지오폴리머의 백화억제에 미치는 영향)

  • Kim, Byoungkwan;Heo, Ye-Eun;Chon, Chul-Min;Lee, Sujeong
    • Resources Recycling
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    • v.27 no.6
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    • pp.59-67
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    • 2018
  • Efflorescence is a white deposit of powders in the surface of cement concrete which can also occur in geopolymers. Efflorescence occurs when sodium ions in alkali activator react with atmospheric carbon dioxide to form sodium carbonate components. In this study, we investigated whether the secondary efflorescence can be reduced by controlling the Na/Al mole ratio or by changing the curing temperature and heat curing time in fly ash-based geopolymers. The 28 days compressive strength in geopolymers having Na/Al ratio of 1.0 was higher than geopolymers having Na/Al ratio of 0.8. The strength increased with the increasing curing temperature and longer heat curing time. On the other hand, efflorescence was lower when the curing temperature was high and the heat curing time was longer in the geopolymers having Na/Al ratio of 1.0. The geopolymers having Na/Al ratio of 0.8 showed accelerated efflorescence occurrence than the geopolymers having Na/Al ratio of 1.0. In order to reduce the occurrence of the secondary efflorescence of fly ash-based geopolymers, it will be advantageous to maintain the Na/Al ratio at 1.0, increase the curing temperature, and lengthen the heating curing time.

Mechanical Properties and Impact Resistance Review of Carbon Fiber Reinforced Cement Composites with Different Fiber Contents and Fiber Lengths (섬유혼입률 및 섬유길이 변화에 따른 탄소섬유 보강시멘트 복합재료의 역학적 특성과 내충격성 검토)

  • Heo, Gwang-Hee;Song, Ki-Chang;Park, Jong-Gun;Han, Yoon-Jung;Lim, Cae-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.86-95
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    • 2019
  • Recently, the applications of carbon fiber have been broader than ever when it comes to such industrials as automobiles, ships, aerospace, civil engineering and architecture because of their lightweight-ness and high mechanical properties. This study analyzed mechanical properties and flexural behavior of carbon fiber reinforced cement composites(CFRC) with different fiber contents and fiber lengths, and also impact resistance by natural drop test on mortar specimens was compared and examined. In addition, contents of carbon fiber(CF) were varied by 0.5%, 1.0%, 2.0% and 3.0%. Fiber lengths was used for 6 mm and 12 mm, respectively. As a result of the test, the flow value was very disadvantageous in terms of fluidity due to the carbon fiber ball phenomenon, and the unit weight was slightly reduced. In particular, the compressive strength was decreased with increasing carbon fiber contents. On the other hand, the flexural strength was the highest with 12 mm fiber length and 2% fiber content. As the results of the impact resistance test, the specimens of plain mortar takes about 2~3 times to final fracture, while the specimens of CFRC is somewhat different depending on the increase of the fiber contents. However, when the fiber length is 12 mm and the fiber content is 2%, the impact resistance was the highest.

Structural Behavior of Rib Reinforced Mg-Si Aluminum Alloy lighting Pole (리브보강 Al-Mg-Si계 가로등 등주의 구조적 거동)

  • Nam, Jeong-Hun;Joo, Hyung-Joong;Kim, Young-Ho;Yoon, Soon-Jong
    • Composites Research
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    • v.21 no.6
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    • pp.8-14
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    • 2008
  • Lighting system of road is an essential structure used for the safety of pedestrians and vehicles. Most of the lighting pole is made with steel which is vulnerable under corrosive environment. To overcome such corrosion problems, stainless steel and iron steel are used, but they are usually manufactured by hand which is not efficient. Due to their high strength and stiffness, when there is car collision with the lighting pole structure the safety of driver may not be ensured. Hence, the development of new-type lighting pole system which is easy to adjust the right on the road, lengthen the service life, and reduce the maintenance, is necessary. Lighting pole made with aluminum alloy is high in strength per unit weight, is strong against corrosive environment, and is easy to construct due to flexibility and right weight. But, because the strength and stiffness of the material is lower than that of steel, the structural safety and serviceability of the system can be a problem. To mitigate the structural problem associated with conventional lighting pole system, experimental investigation is conducted on the conventional lighting pole and rib reinforced aluminum alloy lighting pole, respectively. By comparison of results, it was found that the rib reinforced Mg-Si aluminum alloy lighting pole is efficiently applicable to the lighting pole system of road.