• Title/Summary/Keyword: h2 Separation

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Development of Solid/Liquid Separation Technique for Krill (Eupausia superba) (남극 크릴새우의 고액분리 기술개발)

  • Oh, I.H.;Jang, C.H.;Kim, W.G.;Yang, S.Y.
    • Journal of Animal Environmental Science
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    • v.17 no.1
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    • pp.33-38
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    • 2011
  • Economic development involves increase in life expectancy as well as human health care. Consequently, demand for fish meal and fish oil is rapidly growing. In particular, Krill (Eupausia superba) oil product is in high demand due to its rich unsaturated-fatty acid, and thus stable supplies are necessary in the krill oil market. It is required for captured krills to be immediately frozen and stored during ship transport, since proteins of the krill are quickly denatured in natural temperature condition. However, the transportation cost has been sharply increased, which encourages researchers to involve in studies for development of efficient oil extraction process. In this study, a solid/liquid separation technique on boat for the krill oil was developed through triple separation tests using only a separator or using either brush or crusher prior to the separator. The separation tests revealed that the efficiency were 46.2, 60.2 and 60.4 % by the separator, combination with brush, and combination with crusher, respectively. In addition, it was found that byproduct, extracted cake, derived from the separation process could be used as a feed stuff. These results suggest that smashing using the brush or crusher prior to the separator is more efficient than using only the separator.

Development of Pre-treatment for Tin Recovery from Waste Resources (주석 함유 폐자원의 공정부산물 전처리 기술)

  • Jin, Y.H.;Jang, D.H.;Jung, H.C.;Lee, K.W.
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.142-146
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    • 2014
  • Fundamental experiences have been studied for development of pre-treatment process of Sn by-products such as solders. Dry and wet separation/recovery processes were considered by the differences of physical properties. The by-products, which are analyzed by solder metal and oxides. The metal and oxide were simply separated by dry ball-milling process for 12 hours, after that recovery metal powder might be reusable as lead or lead-free solders. In terms of wet separation process, samples were dissolved in $HNO_3+H_2O_2$ and the precipitation were analyzed by $SnO_2$. Overall efficiency of recovery might be increasing via developing simple pre-treatment process.

Chemical Coagulation Treatment Using Alum and PACl in Complex Wastewater (Alum과 PACl을 이용한 응집처리)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.35 no.1
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    • pp.53-57
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    • 2009
  • In order to treat the complex wastewater containing organic compound and solids, pre-treatment system associated with molecular separation process were investigated. The reductions of COD and turbidity were obtained after coagulation processes using Alum (Aluminium sulfate, $Al_2(SO_4)_2{\cdot}18H_{2}O$) and PACl (poly aluminium chloride as 17% $Al_{2}O_{3}$). The results of study were as follows: using variable dosage of Alum, COD removal was highest at 4,000 mg/l, and the reduction of COD and turbidity was 42% and 92%, respectively. The optimum coagulation would be effective at pH 7.3 than pH 9.0 by the addition of alum at a concentration of 6,000 mg/l and PACl was add at 4.25% in raw complex wastewater with 2,000 mg/l alum at pH 7.3, the reduction of COD was reduced by 32%. But coagulation aid experiments indicated that PACl would be more effective in sludge separation ability than COD removal efficiency.

Removal of iron oxide scale from feed-water in thermal power plant using superconducting magnetic separation

  • Nishijima, S.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.22-25
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    • 2019
  • The superconducting magnetic separation system has been developing to separate the iron oxide scale from the feed water of the thermal power plant. The accumulation in the boiler lowers the heat exchange rate or in the worst case damages it. For this reason, in order to prevent scale generation, controlling pH and redox potential is employed. However, these methods are not sufficient and then the chemical cleaning is performed regularly. A superconducting magnetic separation system is investigated for removing iron oxide scale in a feed water system. Water supply conditions of the thermal power plant are as follows, flow rate 400 t / h, flow speed 0.2 m / s, pressure 2 MPa, temperature $160-200^{\circ}C$, amount of scale generation 50 - 120 t / 2 years. The main iron oxide scale is magnetite (ferromagnetic substance) and its particle size is several tens ${\mu}m$. As the first step we are considering to introduce the system to the chemical cleaning process of the thermal power plant instead of the thermal power plant itself. The current status of development will be reported.

A Separation of manganese (II) and cobalt (II) ions by D2EHPA/TBP-immobilized PolyHIPE membrane

  • Chen, Jyh-Herng;Mai, Le Thi Tuyet
    • Membrane and Water Treatment
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    • v.10 no.2
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    • pp.127-137
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    • 2019
  • The D2EHPA/TBP co-extractants immobilized PolyHIPE membrane can be used for the selective separation of Mn (II) from Co (II). By solvent-nonsolvent method, D2EHPA/TBP co-extractants can be effectively immobilized into PolyHIPE membrane. The pore structure of PolyHIPE membrane and the presence of TBP enhance the stability of immobilized co-extractants. The optimal operating conditions for the separation of Mn (II) and Co (II) are feeding phase at pH 5.5, sulfuric acid concentration in the stripping phase of about 50 g/L and stirring speed at 400 rpm. The D2EHPA/TBP co-extractants ratio of 5:1 shows synergetic effect on Mn/Co separation factor about 22.74. The removal rate and recovery rate of Mn (II) is about 98.4 and 97.1%, respectively, while for Co (II) the transport efficiency is insignificant. The kinetic study of Mn (II) transport shows that high initial flux, $J_f^o=80.1({\mu}mol/m^2s)$, and maxima stripping flux, $J_s^{max}=20.8({\mu}mol/m^2s)$, can be achieved with D2EHPA/TBP co-extractants immobilized PolyHIPE membrane. The stability and reusability study shows that the membrane can maintain a long term performance with high efficiency. High purity of Co (II) and Mn (II) can be recovered from the feeding phase and stripping phase, respectively.

Study on the Analysis of Water-Soluble Dyes by Use of the Thin-Layer Chromatography. -1. Separation and Identification of Xanthene Dyes- (Thin-Layer chromatcgraphy에 의한 수용성 색소의 분석에 관한 고찰 -1. Xanthene 계 색소의 분리 및 대안-)

  • 구성회;이성호
    • Journal of Environmental Health Sciences
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    • v.2 no.1
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    • pp.5-9
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    • 1975
  • For analysis of Xanthene dyes according to the developing solvent and adsorbent was applied to Thin-layer chromatography with silicagel and cellulose plate. Silicagel chromato-plate used were prepared under different condition of activation. Using eight developing solvent, the influence of the condition for activation upon the separation of Xanthene dyes was investigated. The results are shown in Table 3. Methyl ethyl ketone+Acetone+$H_2O$ (10:0.1:0.4) mixture and n-butanol+Ammonia water (4:1) mixture gave clear separation for Xanthene dyes, including Fluorescein, Erythrosine Rhodamin B, Eosine, Rose bengale, phloxine and Acid red those Rf values decrease in the described ordor. Methyl ethyl ketone+Acetone+$H_2O$ (10:0.1:0.4) was applied to two adsorbents which were purchased from different manufactures. The results of Chromatograms are obtained Figure 6.

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The Flow Field Characteristics of a Rotating Circular Cylinder near a Plane Wall (벽면에 근접해서 회전하는 원주의 유동장 특성)

  • Kang, Myung-Hun;Kim, Kwang-Seok;Ro, Ki-Deok
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.2
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    • pp.166-172
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    • 2007
  • The flow around a rotating circular cylinder near a plane wall is investigated by the measurement of the lift acting on the cylinder and by the flow visualization using the hydrogen bubble technique in the circulating water tank. The experimental parameters are the rotating direction of the cylinder. the space ratios $H/D(H/D=0.05{\sim}0.5)$ between cylinder and plane wall and the velocity ratios ${\alpha}({\alpha}=0{\sim}{\pm}2.0)$. In the case of clockwise, the lift on the rotating circular cylinder was increased with the reduction of the space ratios and with the velocity ratios, the upper separation point was more shifted in the rotating direction with them. In the case of anticlockwise, the absolute value of the lift on the rotating circular cylinder was increased with increasing the space ratios and the velocity ratios. the lower separation point was more shifted in the rotating direction with them.

Separation of Succinic Acid from Organic Acid Mixture Using Electrodialysis (전기투석에 의한 유기산 혼합물로부터 숙신산의 분리)

  • Kim, Sang-Hun;Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.266-271
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    • 2005
  • This paper studied succinic acid recovery from organic acid mixture by using mono-polar membrane electrodialysis. Current efficiency, solute recovery efficiency, energy consumption, and separation factor were measured at various pHs and concentration ratios. The separation factor of succinic acid could be interpreted in terms of ionization degree, molecular weight, ionic conductance, average charge, and initial feed composition.

The Phase Separation Characteristics of Bunsen Reaction with HIx Solution in Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 제조 공정에서 HIx 용액을 이용한 분젠 반응의 상 분리 특성)

  • Kim, Hyo-Sub;Hong, Dong-Woo;Han, Sang-Jin;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.479-486
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    • 2010
  • In order to confirm the effect of $HI_x$ solution on Bunsen reaction in Sulfur-Iodine thermochemical hydrogen production process, the reaction was investigated using $HI_x$ solution as a reactant. The phase separation characteristics of reaction with $HI_x$ solution were compared with the reaction using $I_2$ and $H_2O$ as reactants. Firstly, saturation points of $I_2$ in $HI_x$ solution at various temperatures were investigated to determine reaction conditions. With increasing temperature, the amounts of unreacted $I_2$ and $H_2O$ in $HI_x$ solution were increased, while impurities (HI in $H_2SO_4$ phase and $H_2SO_4$ in $HI_x$ phase) in each phase were decreased. The volumes of $H_2SO_4$ phase obtained from Bunsen reaction with $HI_x$ solution was relatively less than those obtained from the reaction with $I_2$ and $H_2O$. The difficulty of phase separation in Bunsen reaction using $HI_x$ solution may be due to the insufficient amount of $H_2O$ existed in $HI_x$ phase after reaction. Therefore, we concluded that the supplement amount of $H_2O$ should be calculated on the basis of the moles of HI and $H_2SO_4$ and added to the reaction system for good phase separation.

Cross-Linked PGMA-co-PMMA/DAAB Membranes for Propylene/Nitrogen Separation (프로필렌/질소 분리를 위한 가교 구조의 PGMA-co-PMMA/DAAB 분리막)

  • Kim, Na Un;Park, Byeong Ju;Kim, Jong Hak
    • Membrane Journal
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    • v.30 no.4
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    • pp.252-259
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    • 2020
  • Olefins are industrially important materials used for the synthesis of various petrochemicals. During the polymerization process, unreacted olefin monomers are discharged together with a large amount of nitrogen. For economic benefits, these olefin gases should be efficiently separated from nitrogen. In this study, a poly(glycidyl methacrylate-co-methyl methacrylate) (PGM) comb-like copolymer was synthesized and 4,4'-diaminoazobenzene (DAAB) was introduced to the copolymer to prepare a cross-linked membrane for C3H6/N2 separation. PGM and DAAB were readily reacted at room temperature through an epoxide-amine reaction without additional thermal treatment. PGM-based membrane, which is a glassy polymer, showed a faster permeation of N2 compared to C3H6. The pristine PGM membrane exhibited the N2 permeability of 0.12 barrer and the high N2/C3H6 selectivity of 32.4. As DAAB was introduced as a cross-linker, the thermal stability of the membrane was significantly improved, which was confirmed by TGA result. The N2/C3H6 selectivity was decreased at 1 wt% of DAAB content, but the N2 permeability increased by approximately 4.7 times. We analyzed N2/C3H6 gas separation properties through a glassy polymer-based membrane, which has not been widely studied. Also, we proposed that thermal stability of the membrane can be greatly improved by the cross-linking method.