Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Separation of Succinic Acid from Organic Acid Mixture Using Electrodialysis

전기투석에 의한 유기산 혼합물로부터 숙신산의 분리

  • Kim, Sang-Hun (Department of Chemical System Engineering, Hongik University) ;
  • Lee, Byung-Chul (Department of Chemical System Engineering, Hongik University)
  • 김상헌 (홍익대학교 과학기술대학 화학시스템공학과) ;
  • 이병철 (홍익대학교 과학기술대학 화학시스템공학과)
  • Received : 2004.12.03
  • Accepted : 2005.03.07
  • Published : 2005.04.30
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Abstract

This paper studied succinic acid recovery from organic acid mixture by using mono-polar membrane electrodialysis. Current efficiency, solute recovery efficiency, energy consumption, and separation factor were measured at various pHs and concentration ratios. The separation factor of succinic acid could be interpreted in terms of ionization degree, molecular weight, ionic conductance, average charge, and initial feed composition.

혼합유기산으로부터 숙신산의 분리를 단극 분리막을 사용한 탈염전기투석장치를 이용하여 행하였다. 전류효율, 회수율, 에너지소요량, 분리비 등의 변화를 pH 값과 초기농도비에 따라 측정하였다. 숙신산의 분리는 숙신산과 아세트산의 이온화율, 분자량, 이온전도도, 전자가 크기 그리고 초기농도비 등으로 해석될 수 있었다.

Keywords

Acknowledgement

Supported by : 홍익대학교

References

  1. Kirk and Othmer, D. F., in H.G. Mary(Ed), 'Encyclopedia of Chemical Technology'(J. Wiley & Sons, New York, 3rd edn), 21, 848-864(1983)
  2. Kirk and Othmer, D. F., in Mary, H. G.(Ed), 'Encyclopedia of Chemical Technology,' J. Wiley & Sons, New York, 4th edn, Vol 22, 1074(1997)
  3. Yamada, S., Hidefumi, H., Shoichi, M. and Yoji, A., Japan Patent 0931,011[97 31 011](CI.C07C55/10), 4 February(1997), Appl. 95/181,199,18 July(1995)
  4. Ryuichi, I. and Akira, K., Japan Patent 09 95,464[97 95, 464] (CI.C07C55/10), 8 April(1997), Appl. 95/253, 656, 29 Sep. (1995)
  5. Lee, P. C., Lee, W. G., Kwon, S., Lee, S. Y. and Chang, H. N., 'Succinic Acid Production by Anaerobiospirillum Succiniciproducens: Effects of the $H_2/CO_2$ Supply and Glucose Concentration,' Enzyme Mictobiol. Tech. 24(8-9), 549-554(1999)
  6. Millard, C. S., Chao, Y. P., Liao, J. C. and Donnelly, M. I., 'Enhanced Production of Succinic Acid by Overexpression of Phosphoenolpyruvate Carboxylase in Escherichia Coli,' Applied and Environmental Microbiology, 62(5), 1808(1996)
  7. Lee, P. C., Lee, W. G., Kwon, S., Lee, S. Y. and Chang, H. N., 'Batch and Continuous Fermentation of Succinic Acid From Whey by Anaerobiospirillum Succiniciproducens,' Appl. Microbiol. Biotechnol., 54(1), 23-27(2000) https://doi.org/10.1007/s002530000331
  8. Hong, Y. K. and Hong, W. H., 'Reactive Extraction of Lactic Acid with Mixed Tertiary Amine Extractants,' Biotechnol. Tech., 13(12), 915-918(1999) https://doi.org/10.1023/A:1008903032300
  9. Juang, R. S. and Huang, R. H., 'Comprarison of Extraction Equilubria of Succinic Acid and Tartaric Acids from Aqueous Solutions with tri-n-octylamine,' Ind. Eng.Chem. Res., 35, 1944-1950(1996) https://doi.org/10.1021/ie950652+
  10. Weier, A. J., Glstz, B. A. and Glstz, C. E., 'Recovery of Propionic and Acetic acids from Fermentation Broth byED,' Biotechnol. Prog., 8(6), 479-485(1992) https://doi.org/10.1021/bp00018a002
  11. Hongo, M., Nomura, Y. and Iwahara, M., 'Novel Method of Lactic Acid Production by Electrodialysis Fermentation,' Appl. Environ. Microbiol., 52, 314(1986)
  12. Nomura, Y., Iwahara, M. and Hongo, M., 'Acetic Acid Production by an Electrodialysis Fermentation Method with a Computerized Control System', Appl. Environ. Mictobiol., 54, 137(1988)
  13. Moon, P. J., Parulekar, S. J. and Tsai, S. P., 'Competitive Anion Transport in Desalting of Mixtures of Organic Acids by Batch ED,' J. Membr. Sci., 141(1), 75-89(1998) https://doi.org/10.1016/S0376-7388(97)00292-5
  14. Appl. Environ. Mictobiol. v.54 Acetic Acid Production by an Electrodialysis Fermentation Method with a Computerized Control System Nomura, Y.;Iwahara, M.;Hongo, M.
  15. J. Membr. Sci. v.141 no.1 Competitive Anion Transport in Desalting of Mixtures of Organic Acids by Batch ED Moon, P.J.;Parulekar, S.J.;Tsai, S.P.