• 제목/요약/키워드: green state

검색결과 767건 처리시간 0.032초

졸-겔법으로 제조한 Zn2SiO4:Mn, M(M=Cr, Ti) 녹색 형광체의 발광특성 (Luminescence Properties of Zn2SiO4:Mn, M(M=Cr, Ti) Green Phosphors Prepared by Sol-gel Method)

  • 안중인;한정화;박희동
    • 한국세라믹학회지
    • /
    • 제40권7호
    • /
    • pp.637-643
    • /
    • 2003
  • PDP(Plasma Display Panel)용 녹색 형광체의 발광특성과 결정성을 향상시키기 위해 Zn$_2$SiO$_4$:Mn에 co-dopant로 Cr과 Ti 를 각각 첨가하여 졸-겔법으로 합성하였다. 이렇게 합성된 Zn$_2$SiO$_4$:Mn, M(M=Cr, Ti) 형광체는 고상반응의 경우와 비교하여 상대적으로 낮은 온도인 110$0^{\circ}C$에서 willemite 구조의 단일상이 형성되었다. 제조된 Zn$_2$SiO$_4$:Mn, M(M=Cr, Ti) 형광체에 대하여 진공자외선(Vacuum Ultraviolet, VUV) 영역의 147 nm 여기광원을 사용하여 발광특성을 조사하였다. Co-dopant의 영향을 알아보기 위해 Mn의 농도는 2 ㏖%, $H_2O$/TEOS의 비율은 36.1로 고정하였고, 이때 Cr과 Ti 모두 0.1 ㏖%에서 가장 좋은 발광특성을 나타냈다. Cr이 co-doping된 경우는 농도가 증가할수록 잔광시간은 짧아지나 발광강도는 지속적으로 감소한 반면, Ti를 co-doping했을 때는 오히려 낮은 농도에서 발광강도의 증가를 보이며 2.0 ㏖%에서 급격히 감소하였다.

Blooms of the woloszynskioid dinoflagellate Tovellia diexiensis sp. nov. (Dinophyceae) in Baishihai Lake at the eastern edge of Tibetan Plateau

  • Zhang, Qi;Zhu, Huan;Hu, Zhengyu;Liu, Guoxiang
    • ALGAE
    • /
    • 제31권3호
    • /
    • pp.205-217
    • /
    • 2016
  • Freshwater red tides due to dinoflagellates have caused spectacular and regular “summer reddening” in recent years in Baishihai Lake, a temperate, meromictic, meso- or oligotrophic, high-altitude, landslide-dammed, deep lake located at the eastern edge of Tibetan Plateau in China. Based on morphological and molecular analyses, the causative organism has been identified as a new woloszynskioid dinoflagellate, Tovellia diexiensis Q. Zhang et G. X. Liu sp. nov. The vegetative cells are 20-32 μm long and 16-24 μm wide. They have a hemispherical episome and a broadly rounded hyposome with a short characteristic antapical spine. Usually cells are bright red due to the presence of numerous red-pigmented bodies, which often masked the yellowish green discoid chloroplasts. The amphiesma of motile cells comprise mainly quadrilateral, pentagonal or hexagonal thin plates, arranged in 4-5 latitudinal series on the episome, 1 in the cingulum and 4 on the hyposome. Molecular phylogenies based on small subunit ribosomal DNA and large subunit ribosomal DNA (LSU) indicate T. diexiensis from Baishihai Lake to belong to the family Tovelliaceae, which was monophyletic in our LSU phylogenies. During the bloom-forming period in 2005, cell density of T. diexiensis reached 9.15 × 105 cells L−1. Astaxanthin and its diester were found to be the major pigments in T. diexiensis, resulting in a characteristic blood-red color of the water in Baishihai Lake.

한국 서해안 학암포 해조상 및 군집구조의 장기모니터링 연구 (A Study on Long-term Monitoring of Seaweed Flora and Community Structure at Hakampo, Western Coast of Korea)

  • 허진석;한수진;최한길;남기완
    • 한국수산과학회지
    • /
    • 제48권6호
    • /
    • pp.969-976
    • /
    • 2015
  • Macroalgal community structure was seasonally examined at Hakampo (Taean) in western coast of Korea from February 2007 to October 2010. Also, the effects of "Hebei Spirit" oil spill on the seaweed community structure were evaluated. A total of 101 macroalgal species were identified, comprising 12 green, 18 brown and 71 red algae. Species richness ranged 58-65 species with maximal in 2008 and minimal in 2009. Seaweed biomass ranged $75.81-102.06g\;dry\;wt./m^2$ (mean, $88.78g/m^2$) with maximal in 2008 and minimal in 2010. Vertical distribution from the high to low intertidal zone was Neorhodomela aculeata and Polyopes affinis; Corallina pilulifera and Chondrus ocellatus; Sargassum thunbergii and Ulva australis. Coarsely-branched seaweeds comprised the highest proportion of biomass ($37.17g/m^2$, or 41.86% of the total biomass) and ecological state group I (ESG I) seaweed biomass was between 81.67-85.44%. Also, ephemeral macroalgae including Ulva species sharply increased in species number and biomass within 1-2 year from the "Hebei Sprit" oil spill in the mid and low intertidal zone. Hakampo rocky shore is still good condition as evaluated based on macroalgal species number, biomass, and composition in functional form and ESG I seaweeds.

수송용 바이오연료 정책에 따른 품질기준 영향에 관한 연구 (Effect Study of Fuel Specifications on Biofuels Policy in Transport Sector)

  • 박조용;김재곤;민경일;박천규;하종한
    • 한국응용과학기술학회지
    • /
    • 제32권4호
    • /
    • pp.767-780
    • /
    • 2015
  • 바이오매스로부터 생산되는 수송용 바이오연료는 온실가스 저감과 지속가능하고 친환경적으로 석유제품을 대체할 수 있다. 수송용 바이오연료의 의무혼합과 보급 목표는 유럽연합, 미국 등의 많은 나라에서 발표하였고 정부의 정책에 의해 활성화되었다. 본 논문에서는 각국의 수송용 바이오연료 정책과 품질기준에 대해 논하겠다. 유럽연합의 바이오연료는 온실가스를 저감하는 정책으로 이동하였다. 미국은 RFS2 하에서 바이오연료의 품질기준을 설정하였고 연방 및 주 정부 수준에서 바이오연료를 촉진하는 정책을 펴고 있다. 한국은 휘발유에 산소 함량 기준으로 2.3%를 산화물로 허용하고 있으며 바이오디젤은 2015년 7월 31일부터 B2.5로 의무혼합하고 있다.

Electrochromic Device for the Reflective Type Display Using Reversible Electrodeposition System

  • Kim, Tae-Youb;Cho, Seong M.;Ah, Chil Seong;Suh, Kyung-Soo;Ryu, Hojun;Chu, Hye Yong
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
    • /
    • pp.232.1-232.1
    • /
    • 2014
  • The green displays are the human friendly displays, the nature friendly displays, and the economical displays. Electrochromic displays are low cost and environmental devices because they do have more choice of colours and use much less power. The elements of the electrochromic devices consist of at least two conductors, an electrochromic material and an electrolyte. The optical properties were obtained using the optical contrast between the transparency of the substrate and the coloured state of the electrochromic materials. These devices can be fully flexible and printable. Due to the characteristics of the high coloration efficiency and memory effects, the electrochromic devices have been used in various applications such as information displays, smart windows, light shutters and electronic papers. Among these technical fields switchable mirrors have been received much attention in the applicative point of view of various electronic devices production. We have developed a novel silver (Ag) deposition-based electrochromic device for the reversible electrodeposition (RED) system. The electrochromic device can switch between transparent states and mirror states in response to a change in the applied voltage. The dynamic range of transmittance percent (%) for the fabricated device is about 90% at 550 nm wavelength. Also, we successfully fabricated the large area RED display system using the parted electrochromic cells of the honey comb structure.

  • PDF

반사방지 특성을 통일시킨 실리콘 질화막 간의 패시베이션 특성 비교 (Comparison of Passivation Property on Hydrogenated Silicon Nitrides whose Antireflection Properties are Identical)

  • 김재은;이경동;강윤묵;이해석;김동환
    • 한국재료학회지
    • /
    • 제26권1호
    • /
    • pp.47-53
    • /
    • 2016
  • Silicon nitride ($SiN_x:H$) films made by plasma enhanced chemical vapor deposition (PECVD) are generally used as antireflection layers and passivation layers on solar cells. In this study, we investigated the properties of silicon nitride ($SiN_x:H$) films made by PECVD. The passivation properties of $SiN_x:H$ are focused on by making the antireflection properties identical. To make equivalent optical properties of silicon nitride films, the refractive index and thickness of the films are fixed at 2.0 and 90 nm, respectively. This limit makes it easier to evaluate silicon nitride film as a passivation layer in realistic application situations. Next, the effects of the mixture ratio of the process gases with silane ($SiH_4$) and ammonia ($NH_3$) on the passivation qualities of silicon nitride film are evaluated. The absorption coefficient of each film was evaluated by spectrometric ellipsometry, the minority carrier lifetimes were evaluated by quasi-steady-state photo-conductance (QSSPC) measurement. The optical properties were obtained using a UV-visible spectrophotometer. The interface properties were determined by capacitance-voltage (C-V) measurement and the film components were identified by Fourier transform infrared spectroscopy (FT-IR) and Rutherford backscattering spectroscopy detection (RBS) - elastic recoil detection (ERD). In hydrogen passivation, gas ratios of 1:1 and 1:3 show the best surface passivation property among the samples.

광화학적 방법을 통한 InP계 양자점 표면결함 부동태화 연구 (Study on Surface-defect Passivation of InP System Quantum Dots by Photochemical Method)

  • 김도연;박현수;조혜미;김범성;김우병
    • 한국분말재료학회지
    • /
    • 제24권6호
    • /
    • pp.489-493
    • /
    • 2017
  • In this study, the surface passivation process for InP-based quantum dots (QDs) is investigated. Surface coating is performed with poly(methylmethacrylate) (PMMA) and thioglycolic acid. The quantum yield (QY) of a PMMA-coated sample slightly increases by approximately 1.3% relative to that of the as-synthesized InP/ZnS QDs. The QYs of the uncoated and PMMA-coated samples drastically decrease after 16 days because of the high defect state density of the InP-based QDs. PMMA does not have a significant effect on the defect passivation. Thioglycolic acid is investigated in this study for the effective surface passivation of InP-based QDs. Surface passivation with thioglycolic acid is more effective than that with the PMMA coating, and the QY increases from 1.7% to 11.3%. ZnS formed on the surface of the InP QDs and S in thioglycolic acid show strong bonding property. Additionally, the QY is further increased up to 21.0% by the photochemical reaction. Electron-hole pairs are formed by light irradiation and lead to strong bonding between the inorganic and thioglycolic acid sulfur. The surface of the InP core QDs, which does not emit light, is passivated by the irradiated light and emits green light after the photochemical reaction.

지역식량체계의 구조와 동학에 관한 연구: 미국 미주리주 Food Circle을 중심으로 (The Structure and Dynamics of Community Food Systems with Reference to Food Circle in Missouri, USA)

  • 김종덕
    • 한국지역사회생활과학회지
    • /
    • 제17권2호
    • /
    • pp.125-138
    • /
    • 2006
  • While the global food system prevails in America, the community food system is also spreading rapidly. The former, which is based on industrial agriculture, has negative impacts on family farms, food safety, and community development. In contrast, the latter has positive effects on farmers, consumers, communities, and the environment. Community food systems have been able to grow successfully through the participation of farmers and consumers, support of the federal and state governments, and the initiatives of NGOs. Food Circle, upon which this study focuses, is one of the community food systems based on the regional level. It is the outcome of the green movement in Kansas City, Missouri. The goal of Food Circle in Missouri is to retain and support rural family farms by connecting them with regional consumers. Its main activity is to collect data, including a directory of farmers and their regional products, and distribute this data to regional consumers. It is informally organized and entirely self funded. Although community food systems have several problems, their development is to continue in America. The food system in Korea has become a global one in recent decades, and agricultural problems and food safety issues are being generated as a result. The development of community food systems would be helpful in resolving these problems. In order to activate community food systems in Korea as seen in America's case, it would be necessary to have the imperative participation of both farmers and consumers, the support of the central and provincial governments, and the initiatives of NGOs.

  • PDF

백금계 촉매상에서 산화질소(NO)의 산화반응속도에 관한 실험 및 모델링 연구 (An Experimental and Modeling Study on the Oxidation Kinetics of Nitric Oxide over Platinum-based Catalysts)

  • 김영득;정수진;김우승
    • 한국자동차공학회논문집
    • /
    • 제20권5호
    • /
    • pp.71-80
    • /
    • 2012
  • To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

농촌비오톱 유형분류 및 특성분석 (The Type Classification and Characteristic Analysis of Biotope in Rural Areas)

  • 조현주;나정화;사공정희;류연수
    • 농촌계획
    • /
    • 제15권4호
    • /
    • pp.19-32
    • /
    • 2009
  • This research has a significant meaning to break from the urban ecology-oriented biotope research and realize the importance of rural landscape as a reserve area for systemizing the types of rural biotope. The results are as follows. First of all, items for classification of 16 rural biotope areas are designed and total 9 itmes in slope from spatial structural point of view and 7 items in minute-variety from functional point of view. Also, as the result of on-site research on case areas based on classified items, there are 46 types of rural biotope such as coniferous forest, hedgerow and so on. For example, it is proven that uncultivated stripe showed the most frequent emergence. As a result of cluster analysis of average linkage method between clusters, 12 clusters are classified as a clusters and 13 biotope types are re-corrected and complemented through brainstorming process and then total 12 clusters are selected as final rural biotope type groups. As a rural biotope type cluster and character analysis according to types based on on-site research and documentary survey, for example, it is analyzed that the ratio of transmissible covering ratio is 100%, the ratio of green coverage is 90% in 'woodland in cultivated area biotope type cluster'.