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http://dx.doi.org/10.4191/KCERS.2003.40.7.637

Luminescence Properties of Zn2SiO4:Mn, M(M=Cr, Ti) Green Phosphors Prepared by Sol-gel Method  

안중인 (한국화학연구원 형광물질연구팀)
한정화 (한라대학교 신소재공학과)
박희동 (한국화학연구원 형광물질연구팀)
Publication Information
Abstract
In order to improve the photoluminescent properties and crystallinity, Zn$_2$SiO$_4$:Mn, M(M=Cr, Ti) phosphors were synthesized by the sol-gel method. The willemite single phase was obtained at 110$0^{\circ}C$, which is lower temperature than that of the conventional solid-state reaction (130$0^{\circ}C$). The characteristics of fired samples were obtained by a 147 nm excitation source under VUV (Vacuum Ultraviolet). To investigation the effect of co-dopant, the content of Mn and the ratio of $H_2O$ to TEOS was fixed as 2 ㏖% and 36. 1, respectively. The highest emission intensity was obtained when the concentration of Cr and Ti was 0.1 ㏖% relative to Zn$_2$SiO$_4$:Mn. While the emission intensity decrease continuously the decay time improved as increased the Cr concentration. In the case of Ti added samples, however, the emission intensity increase up to 2 ㏖% concentration.
Keywords
Phosphor; PDP; Sol-gel method; Photoluminescence; Decay time;
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Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 The Phosphor for Plasma Display Panels(PDPs)(in Kor.) /
[ S.I.Mun;Y.Y.Shin;Y.D.Heo;Y.H.Kim;M.S.Kong ] / Chemworld
2 Control of Morphology of Zn₂SiO₄by Hydrothermal Preparation /
[ Q.H.Li;S.Komarneni;R.Roy ] / J. Mat. Sci.   DOI   ScienceOn
3 Effects of Water Content and pH on Gel-derived TiO₂-SiO₂ /
[ H.F.Yu;S.M.Wang ] / J. Non-Cryst. Solids   DOI   ScienceOn
4 Refinement of Zinc Silicate Phosphor Synthesis /
[ I.F.Change;J.W.Brownlow;T.I.Sun;J.S.Wilson ] / J. Electrochem. Soc.   DOI
5 Preparation of Glasses and Bulk Quratz Gel by Sol-gel Method(in Kor.) /
[ W.K.Park ] / Ceramist
6 Brightness and Decay Time of Zn₂SiO₂:Mn Phosphor Particle with Spherical Shape and Fine Size /
[ Y.C.Kang;H.D.Park ] / Appl. Phys. A Mater. Sci. & Proc.
7 Green Phosphors for Large Plasma TV screens /
[ A.Morell;N.E.Khiati ] / J. Electrochem. Soc.   DOI   ScienceOn
8 Optimised Co-activated Willemite Phosphors for Application in Plasma Display Panels /
[ E. van der Kolk;P.Dorenbos;C.W.E.van Rijk;H.Bechtel;T.Justel;H.Nikol;C.R.Ronda;D.U.Wiechert ] / J. Lumin   DOI   ScienceOn
9 High Luminance Zn₂SiO₄:Mn Phosphors Prepared by Homogeneous Precipitaion Method /
[ H.K.Jung;K.S.Sohn;B.Y.Sung;H.D.Park ] / J. Information Display
10 Effect of Co-doping on the Photolumnescence Behavior of Zn₂SiO₄:Mn Phosphors /
[ K.S.Sohn;B.H.Cho;H.J.Chang;H.D.Park ] / J. Electrochem. Soc.   DOI   ScienceOn
11 The Photoluminescence and Decay Time of the Green Phosphor Zn₂SiO₄:Mn, Mg /
[ B.H.Cho;T.S.Hwang;K.S.Sohn;H.D.Park;H.J.Chang ] / J. Kor. Ceram. Soc.   과학기술학회마을
12 Mn Concentration Effect on the Optical Properies of Zn₂SiO₄: Mn Phosphors /
[ C.Barthou;J.Benoit;P.Benalloul;A.Morell ] / J. Electrochem. Soc.   DOI   ScienceOn
13 Synthesis of Ceramic Materials via Sol-gel Processing (Mechanistic Viewpoint) /
[ D.G.Park ] / Polmy. Sci. Tech.
14 Preparation and Luminescence Properties of Zn₂SiO₄:Mn, Al Green Phosphor by Sol-gel Technique /
[ B.Y.Seong; J.H.Han;H.D.Park;D.S.Kim ] / J. Kor. Ceram. Soc.   과학기술학회마을