• 제목/요약/키워드: green state

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Structural Isomers and Excited States of HN3

  • Cho, Ji-Eun;Lee, Hee-Soon;Choi, Cheol-Ho
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3641-3643
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    • 2011
  • Multiconfigurational wavefunctions were adopted to study structural isomers, their isomerization reactions and excited states of $HN_3$. In addition to the known linear isomer, two new structural isomers were found. The three isomers can be classified as sp, $sp^2$ and $sp^3$ hybridized species, respectively. The sp3 hybridized species turned out to be the second most stable. Large reaction barriers among these species prevent thermal isomerizations. A low-lying $^3A'$ exists with a relative energy of 13.5 kcal/mol. Dramatic re-hybridization and bond elongation was found in the first excited $^1A"$.

Wide bandgap III-nitride semiconductors: opportunities for future optoelectronics

  • Park, Yoon-Soo
    • 한국결정성장학회지
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    • 제12권1호
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    • pp.11-20
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    • 2002
  • The world at the end of the $20^{th}$ Century has become "blue" Indeed, this past decade has witnessed a "blue rush" towards the development of violet-blue-green light emitting diodes (LEDs) and laser diodes (LDs) based on wide bandgap III-Nitride semiconductors. And the hard work has culminated with, first, the demonstration of commercial high brightness blue and green LEDs and of commercial violet LDs, at the very end of this decade. Thanks to their extraordinary properties, these semiconductor materials have generated a plethora of activity in semiconductor science and technology. Novel approaches are explored daily to improve the current optoelectronics state-of-the-art. Such improvements will extend the usage and the efficiency of new light sources (e.g. white LEDs), support the rising information technology age (e.g. high density optical data storage), and enhance the environmental awareness capabilities of humans (ultraviolet and visible photon detectors and sensors). Such opportunities and many others will be reviewed in this presentation.

Zn2SiO4:Mn,Al 녹색 형광체의 제조와 발광특성 (Preparation and Luminescent Properties of Zn2SiO4:Mn,Al Green Phosphors)

  • 이지영;유일
    • 한국전기전자재료학회논문지
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    • 제20권4호
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    • pp.363-366
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    • 2007
  • [ $Zn_2SiO_4:Mn$ ] green phosphors doped with $NH_4Cl$ and Al for PDP were synthesized by solid state reaction method. The luminescence of 532 nm in $Zn_2SiO_4:Mn$ phosphors was associated with $^4T_1{\to}^6A_1$ transition. Photoluminescence intensity of $Zn_2SiO_4:Mn$ doped with $NH_4Cl$ 15 mol% increased about two times as compared with that of $NH_4Cl$ non-doped sample. The color of the emission of Al-doped $Zn_2SiO_4:Mn$ phosphors changed to yellowish green.

Zn2SiO\4:Mn, Ga 형광체의 제조와 발광특성 (Preparation and Luminescent Properties of Zn2SiO4:Mn, Ga Phosphors)

  • 이지영;유윤식;유일
    • 한국전기전자재료학회논문지
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    • 제22권2호
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    • pp.158-162
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    • 2009
  • $Zn_2SiO_4$:Mn green phosphors doped with Ga for PDP were synthesized by solid state reaction method. Photoluminescence measurements showed a new emission peak at around 600 nm for $Zn_2SiO_4$:Mn phosphors doped with Ga. Also, the luminescent color with doping $Ga^{3+}$ in the $Zn_2SiO_4$:Mn phosphors changed to green from yellowish green. Consequently, the new peak and charge of the luminescent color in the $Zn_2SiO_4$:Mn, Ga phosphors were attributed to $^2E{\rightarrow}^6A_2$ transition of $Mn^{4+}$.

Study on the Excited Energy Transfer in Light-harvesting Complex (LH2) of Rhodobacter sphaeroides

  • Liu, Yuan;Guo, Lijun;Qian, Shixiong;Xu, Chunhe
    • Journal of Photoscience
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    • 제9권2호
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    • pp.359-361
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    • 2002
  • A green mutant of Rhodobacter sphaeroides 60I was acquired by chemical induction. The blue-shifted of the carotenoid absorption was found in the Light-harvesting complex II (LH2) of the mutant. With the excitation at different wavelength, we observed that the evolution of excited-state dynamics in LH2 of Rhodobacter sphaeroides 60I. The dynamical traces demonstrate a dominant absorption followed concomitantly by an ultrafast transmission increase and decay with 818nm excitation.

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SOME GENERALIZED GAMMA DISTRIBUTION

  • Nadarajah Saralees;Gupta Arjun K.
    • Journal of the Korean Statistical Society
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    • 제36권1호
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    • pp.93-109
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    • 2007
  • Gamma distributions are some of the most popular models for hydrological processes. In this paper, a very flexible family which contains the gamma distribution as a particular case is introduced. Evidence of flexibility is shown by examining the shape of its pdf and the associated hazard rate function. A comprehensive treatment of the mathematical properties is provided by deriving expressions for the nth moment, moment generating function, characteristic function, Renyi entropy and the asymptotic distribution of the extreme order statistics. Estimation and simulation issues are also considered. Finally, a detailed application to drought data from the State of Nebraska is illustrated.

Ecological Green Roofs in Germany

  • Kohler, Manfred
    • 한국환경복원기술학회지
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    • 제7권4호
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    • pp.8-16
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    • 2004
  • The industrialization of central Europe more than 100 ago marked the beginning of densely concentrated buildings in quickly growing cities. A cheap type of roofing material of that time was tar. But it was dangerous because it was high inflammable. Then some roofer had a splendid idea. They used sandy material as a final layer atop the impermeable tar layer. These roofs were much more fire resistant than the typical roofs. In this sandy layer some plant species began to grow spontaneously. This was the beginning of the green roof history of modern Europe. A number of these green roofs survived both world wars. In the early 80's in Berlin alone, 50 such buildings existed and they continued to be waterproof until the present day. Since the 1992 Earth Summit of 1992 in Rio de Janeiro(http://www.johannesburgsummit.org/html/basic_info/unced.html) the term "sustainable development" became of central interest of urban designers. In city regions green roofs had become synonymous with this term. With a small investment, long-lasting roofs can be created. Further back in history, more exciting examples of green roofs can be found. The hanging gardens of antiquity are well-known. There are also green roofs built as insulation against cold and heat all over the world. For over 20 years, roof greening in central Europe has been closely examined for various reasons. Roof greening touches several different disciplines. Of primary interest is the durability of the roofs. But ecologists are also interested in green roofs, for instance in biodiversity research. The beneficial effect of greening on water proofing was also proven. For some time, the issue of fire protection was investigated. According to tests, green roofs received a harsh careful rating. Their fire protective property is considered similar to that of tile roofs. Another recent impulse for the green roof movement in Germany has come from the evident improvement of storm water retention and the reduced burden on the sewer system. The question of whether and how much energy green roofs can save has become an urgent question. The state of the research and also various open questions from a central European point of view will be discussed in the context of international collaboration. Apart from academic considerations, those who involve themselves in this issue take a predominantly positive view of the numerous existing green roofs in Germany. In some cities, green roofs are the typical construction technique for new buildings. A few outstanding examples will conclude this review. In Germany, about 20 companies, some of which operate internationally, specialize in green roof consulting. Learning from each other in an open-ended way with respect to different construction techniques and applications in various climatic regions can only be accomplished through such international collaboration as is taking place here.

저장 조건이 녹차 음료의 품질에 미치는 영향 (Effect of Storage Conditions on the Quality of Green Tea Beverage)

  • 이정민;임상욱;조성환;최성길;허호진;이승철
    • 농업생명과학연구
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    • 제43권3호
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    • pp.27-34
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    • 2009
  • 녹차 잎 1.5 g에 증류수 100 mL을 가하여 $75^{\circ}C$에서 5분 동안 추출하여 녹차 음료를 제조하였다. 저장 조건을 달리하여 A 녹차 음료 (빛을 인위적으로 차단하지 않음, 자연 상태의 대기 조건, 비타민 C 무첨가), B 녹차 음료 (빛을 알루미늄 호일로 감싸서 차단함, 질소를 불어넣어 자연 대기를 질소로 치환하였음, 비타민 C 30 mg/100 mL 첨가), C 녹차 음료 (빛을 알루미늄 호일로 감싸서 차단함, 질소를 불어넣어 자연 대기를 질소로 치환하였음, 비타민 C 무첨가)로 구분하여 $4^{\circ}C$에서 28일간 저장한 후, 유용 성분을 분석하였다. 총페놀 함량의 경우 저장 초기에 비하여 저장 28일 후 A 녹차 음료는 71.50%, B 녹차 음료는 73.88%, C 녹차 음료는 75.07%로 감소하였다. DPPH 라디컬 소거능은 저장 초기에 비하여 A 녹차 음료는 87.87%, B 녹차 음료는 92.93%, C 녹차 음료는 88.39%이었다. 녹차의 유용 카테킨인 epigallocatechin gallate (EGCG)는 28일간 저장 후에 A 녹차 음료는 130.61%, B 녹차 음료는 136.47%, C 녹차 음료는 4.34%이었다. 이상의 결과는 녹차의 저장 조건이 녹차 음료의 성분에 영향을 미치며, 빛, 질소 치환, 비타민 C가 매우 중요함을 시사하였다.

Influence of Air-tightness on Heat Energy Performance in Post and Beam Building with Exposed Wood Frame

  • Kim, Hyun-Bae;Kim, Se-Jong;Oh, Jung-Kwon;Park, Joo-Saeng;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • 제40권5호
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    • pp.319-326
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    • 2012
  • Han-green building is one of the modernized Korean traditional buildings developed by Korea Forest Research Institute. This building was developed to increase the competitiveness of Korean traditional building using state-of-art technologies; hence Han-green building has the inherent characteristics of traditional building such as exposed wood frame in wall. Because of discontinuity in wall by the exposed wood frame, there is a concern on heat-air leaking in terms of energy performance. In this study, air-tightness of Han-green building was evaluated to investigate the influence of gaps between frames and in-fill walls. Blower door test was carried out to evaluate the air-tightness, and air-change rate (ACH50) was evaluated by averaging four set of pressurization and depressurization test. The air-change rate of Han-green house was 5.91 $h^{-1}$. To improve energy performance of Han-green house, thermal infrared images of Han-green house were taken in winter with heating to find out where the heat loss occurred. It was found that the building lost more heat through gaps between frames and in-fill walls rather than through other parts of this building. After covering all the gaps by taping, the blower door test was performed again, and the air-change rate was improved to 5.25 $h^{-1}$. From this analysis, it was concluded that the heated air can leak through the gaps between frames and walls. Therefore, when one designs the post and beam building with exposed frame, the detail design between frame and wall needs to be carefully dealt. However, Han-green building showed relatively high air-tightness comparing with other country research results.

신자유주의적 에너지정책과 '녹색성장'의 한계 (Neoliberal Energy Policy and the Limits to 'Green Growth')

  • 최병두
    • 대한지리학회지
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    • 제45권1호
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    • pp.26-48
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    • 2010
  • 최근 정부는 '녹색성장'의 기치 아래 일련의 에너지관련 계획과 전략들을 추진하고자 한다. 이러한 정부의 에너지 정책에 대해 여러 측면에서 비판적 검토가 있었지만 이러한 정책이 추동되는 구조적 배경에 대해서는 제대로 고찰되지 않았다. 이 논문은 현정부의 '녹색성장' 전략과 그 일환으로 추진되는 에너지정책을 신자유주의화과정으로 이해한다. 특히 정부의 에너지 정책은 에너지의 산업화, 시장화, 기술화, 금융화를 기본적 특성으로 하고 있으며 이로 인해 많은 세부 문제들을 유발하고 있다. 이러한 '녹색성장' 전략은 지속가능한 발전 모형과는 거리가 멀고 하비가 신자유주의화의 전형으로 제시한 '탈취에 의한 축적'의 개념으로 해석된다. 정부의 '녹색성장' 전략과 에너지 정책은 환경보전과 경제성장 간 모순 시장 메커니즘과 국가 개입 간 갈등을 중재할 수 있는 시민(사회)의 역할을 부정한다는 점에서 '녹색성장' 전략에 대한 대안은 시민이 참여하는 시민사회 주도형 에너지 정책을 지향해야 할 것이다.