• Journal of the Korean Society of Manufacturing Process Engineers
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• v.12 no.6
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• pp.3-9
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• 2013

Aluminum Oxide($Al_2O_3$) ceramics are excellent candidates for such applications due to their outstanding mechanical, thermal, and tribological properties. However, they are difficult to machine using conventional mechanical methods. Carbon fillers, such as carbon nanotubes(CNT) and graphene nanoplatelets(GNP)can be dispersed in a ceramic matrix to improve the mechanical and electrical properties. In this study, CNT and Graphene reinforced hybrid ceramic composites were fabricated using the spark plasma sintering method at a temperature of $1,500^{\circ}C$, pressure of 40 MPa, and soaking time of 10min. Besides this, the material properties such as microstructure, crystal structure, hardness, and electrical conductivity were analyzed using FE-SEM, XRD, Vickers, and the 4-point probe method. A micro machining test was carried out to compare the effects of the material properties and the machining performance for CNT and Graphene reinforced ceramic composites.

• Composites Research
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• v.28 no.5
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• pp.265-269
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• 2015

Development of simple and efficient method for large-scale production of mechanically strong and electrically conductive graphene fiber is highly desirable for practical applications, such as fiber-reinforced composites, wearable electronics, and electromagnetic irradiation shielding. Here, we present a facile approach for the preparation of amine-functionalized graphene fibers by simple wet-spinning of diamine-functionalized graphene oxide (GO-$NH_2$), which is used because of its synthetic convenience, good dispersity, and scalable production with low cost. The amine-functionalized graphene fiber shows high electrical and mechanical properties compared to pristine graphene oxide fiber due to the electrostatic interaction between amine groups and electronegative functional groups of graphene oxide.

• Journal of Powder Materials
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• v.26 no.5
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• pp.383-388
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• 2019

To improve the mechanical properties of aluminum, graphene has been used as a reinforcing material, yielding graphene-reinforced aluminum matrix composites (GRAMCs). Dispersion of graphene materials is an important factor that affects the properties of GRAMCs, which are mainly manufactured by mechanical mixing methods such as ball milling. However, the use of only mechanical mixing process is limited to achieve homogeneous dispersion of graphene. To overcome this problem, in this study, we have prepared composite materials by coating aluminum particles with graphene by a self-assembly reaction using poly vinylalcohol and ethylene diamine as coupling agents. The scanning electron microscopy and Fourier-transform infrared spectroscopy results confirm the coating of graphene on the Al surface. Bulk density of the sintered composites by spark plasma sintering achieved a relative density of over 99% up to 0.5 wt.% graphene oxide content.

• Advances in aircraft and spacecraft science
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• v.9 no.1
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• pp.69-93
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• 2022

Reduced graphene oxide (rGO) is one of the derivatives of graphene, which has drawn some experimental research interests in recent years however, numerical research studying the mechanical behaviors of composites made of rGO has not been taken into consideration yet. The objective of this research is to investigate the buckling, and free vibration of functionally graded reduced graphene oxide reinforced nanocomposite (FG rGORC) plates employing isogeometric analysis (IGA). The effective Young's modulus of rGORC is determined based onthe Halpin-Tsai model. Four different FG distribution types of rGO are considered varying across plate thickness. Besides, the refined plate theory is used based on Reddy's third-order function. To capture the size effect, modified couple stress theory (MCST) is employed. A comprehensive study is provided examining the effect of various parameters including rGO weight fraction, FG distribution types, boundary conditions, material length scale parameter, etc. Our obtained results show that the addition of only 1% of uniformly distributed rGO into epoxy plates leads to the fundamental frequency and critical buckling load 18% and 39% higher than those of pure epoxy plates, respectively.

• Structural Engineering and Mechanics
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• v.73 no.6
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• pp.685-698
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• 2020

The dynamic stability of a functionally graded polymer microbeam reinforced by graphene oxides subjected to a periodic axial force is investigated. The microbeam is assumed to rest on an elastic substrate and is subjected to various immovable boundary restraints. The weight fraction of graphene oxides nanofillers is graded across the beam thickness. The effective Young's modulus of the functionally graded graphene oxides reinforced composite (FG-GORC) was determined using modified Halpin-Tsai model, with the mixture rule used to evaluate the effective Poisson's ratio and the mass density. An improved third order shear deformation theory (TSDT) is used in conjunction with the Chebyshev polynomial-based Ritz method to derive the Mathieu-Hill equations for dynamic stability of the FG-GORC microbeam, in which the scale effect is taken into account based on modified couple stress theory. Then, the Mathieu-Hill equation was solved using Bolotin's method to predict the principle unstable regions of the FG-GORC microbeams. The numerical results show the effects of the small scale, the graphene oxides nanofillers as well as the elastic substrate on the dynamic stability behaviors of the FG-GORC microbeams.

• Carbon letters
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• v.21
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• pp.1-7
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• 2017

The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

• Computers and Concrete
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• v.26 no.1
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• pp.21-30
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• 2020

Buckling and post-buckling behaviors of geometrically imperfect annular sector plates made from nanoparticle reinforced composites have been investigated. Two types of nanoparticles are considered including graphene oxide powders (GOPs) and silicone oxide (SiO₂). Nanoparticles are considered to have uniform and functionally graded distributions within the matrix and the material properties are derived using Halpin-Tsai procedure. Annular sector plate is formulated based upon thin shell theory considering geometric nonlinearity and imperfectness. After solving the governing equations via Galerkin's technique, it is showed that the post-buckling curves of annular sector plates rely on the geometric imperfection, nanoparticle type, amount of nanoparticles, sector inner/outer radius and sector open angle.

• Structural Engineering and Mechanics
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• v.84 no.6
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• pp.823-829
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• 2022

This study considered the experimental parameters (Nano-graphene oxide reinforced polycarbonate, GFRP) under low-velocity impact load and vibration analysis. The effect of nano-graphene oxide (NGO) on a polycarbonate-based composite was studied. Two test procedures were adopted to obtain experimental results, vibration analysis. The mechanical tests were performed on damaged and non-damaged specimens to determine the damaging effect on the composite specimens. After the test was carried out, the effect of NGO was measured and damping factors were ascertained experimentally. 0. 2 wt% NGO was determined as the optimum amount that best affected the Vibration Analysis. The experiments revealed that the composite's damping properties were increased by adding the nanoparticles to 0.25 wt% and decreased slightly for the specimens with the highest nanoparticles content. Cyclic sinus loading was applied at a frequency of 3.5 Hz. This paper study the frequency effect of 3.5khz frequency damage on mechanical results. Found that high frequency will worthlessly affect the fatigue life in NGO/polycarbonate composite. In 3.5 Hz frequency, it was chosen to decrease the heat by frequency. Transmission electron microscopy (TEM) micrographs were used to investigate the distribution of NGO on the polycarbonate matrix and revealed a homogeneous mixture of nano-composites and strong bonding between NGO and the polycarbonate which increased the damping properties and decreased vibration. Finally, experimental modal analysis was conducted after the high-velocity impact damage process to investigate the defect on the NGO polycarbonate composites.

• Composites Research
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• v.28 no.3
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• pp.130-135
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• 2015

This study investigates the property of graphene filled polymer nanocomposites in LEO(Low Earth orbit) environment conditions. In order to improve compatibility with polymer matrices and resistance of carbon material against AO(Atomic oxygen) attack, silanization of graphene oxide with organosilane was carried out. The corresponding moieties were characterized through X-ray photoelectron spectroscopy (XPS). Graphene oxide filled nanocomposites were prepared using solution based processing methods. The sets of specimen series were tested in an accelerated LEO simulated space environment facility. Graphene oxide and silane treated graphene oxide reinforced nanocomposites were compared with neat epoxy. The comparison revealed that the silane treated graphene filled polymer composite shows inherent resistance against atomic oxygen attack while the lack of silane treatment resulted in a reduction in performance.

• Korean Journal of Materials Research
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• v.26 no.6
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• pp.298-305
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• 2016

In this work, recent progress on graphene/metal oxide composites as advanced materials for $HgCl_2$ and $CO_2$ capture was investigated. Density Functional Theory calculations were used to understand the effects of temperature on the adsorption ability of $HgCl_2$ and water vapor on $CO_2$ adsorption on CaO (001) with reinforced carbon-based nanostructures using B3LYP functional. Understanding the mechanism by which mercury and $CO_2$ adsorb on graphene/CaO (g-CaO) is crucial to the design and fabrication of effective capture technologies. The results obtained from the optimized geometries and frequencies of the proposed cluster site structures predicted that with respect to molecular binding the system possesses unusually large $HgCl_2$ ($0.1-0.4HgCl_2g/g$ sorbent) and $CO_2$ ($0.2-0.6CO_2g/g$ sorbent) uptake capacities. The $HgCl_2$ and $CO_2$ were found to be stable on the surface as a result of the topology and a strong interaction with the g-CaO system; these results strongly suggest the potential of CaO-doped carbon materials for $HgCl_2$ and $CO_2$ capture applications, the functional gives reliable answers compared to available experimental data.