• Journal of the Korea Concrete Institute
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• v.27 no.5
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• pp.559-568
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• 2015

In this study, multi-component blended concrete mix with fly ash and ground granulated blast furnace slag according to 3 level of type of warter reduction agent (type of 0%, 8% and 16%) and 3 level of water-binder ratio (40%, 45% and 50%) was prepared for evaluation of effect of physical characteristics of concrete using multi-component blended binder according to warter reduction efficiency of warter reduction agent. In addition, concrete mix was carried out repetition test of three times in order to secure the reliability. As a result, compressive strength according to type of warter reduction agent was found that difference of strength was about 20% occurred, warter reduction efficiency of warter reduction agent was showed that a great influence on qualities of concrete. Therefore, reflected the effect of warter reduction efficiency of warter reduction agent, prediction model equations of compressive strength for multi-component blended concrete was proposed, it was found that more than 90% of the high correlation.

• Journal of the Korea Concrete Institute
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• v.27 no.4
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• pp.435-441
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• 2015

Concrete, as a porous media, has permeability and it is considered as a major parameter for durability evaluation. Cold joint caused by delayed placing of concrete accelerates water permeation and intrusion of harmful ions. In the paper, concrete specimens containing GGBFS (Ground Granulated Blast Furnace Slag) and OPC (Ordinary Portland Cement) are prepared with cold joint section, and water permeability and water flow at the age of 91 days are measured for 2 weeks. Sound concrete with GGBFS shows decreased permeability to 89% for sound concrete with OPC and 0.86 of decreasing ratio is evaluated in GGBFS concrete with cold joint. Through WPT (Water Penetration Test), the effects of mineral admixture and cold joint on water permeability are evaluated, and variation in water behavior via cold joint is analyzed through probabilistic method as well.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.1-7
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• 2018

This study examined the effect of binder-to-soil ratio(B/S) and water-to-binder ratio(W/B) on the flow and compressive strength development of soil concrete using high-volume supplementary cementitious materials. As a partial replacement of ordinary portland cement, 10% by-pass dust, 40% ground granulated blast-furnace slag, and 25% circulating fluidized bed combustion fly ash were determined in the preliminary tests. Using the low-cement binder incorporated with clay soil or sandy soil, a total of 18 soil concrete mixtures was prepared. The flow of the soil concrete tended to increase with the increase in W/B and B/S, regardless of the type of soils. The compressive strength was commonly higher in sandy soil concrete than in clay soil concrete with the same mixture condition. Considering the high-workability and compressive strength development, it could be recommended for low-cement soil concrete to be mixed under the following condition: B/S of 0.35 and W/B of 175%.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.135-145
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• 2016

MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.

• Advances in materials Research
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• v.4 no.3
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• pp.133-144
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• 2015

The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoWdecreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACWmixes containing GGBFS (MCS10 and MCS30) were higher than those of AACWwith no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoWcontent increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).

• Corrosion Science and Technology
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• v.8 no.3
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• pp.110-115
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• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• Structural Monitoring and Maintenance
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• v.2 no.1
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• pp.35-48
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• 2015

The main objective of this study is to evaluate the long-term performance of various concrete composites in natural marine environment prevailing in the Gulf region. Durability assessment studies of such nature are usually carried out under aggressive environments that constitute seawater, chloride and sulfate laden soils and wind, and groundwater conditions. These studies are very vital for sustainable development of marine and off shore reinforced concrete structures of industrial design such as petroleum installations. First round of testing and evaluation, which is presented in this paper, were performed by standard tests under laboratory conditions. Laboratory results presented in this paper will be corroborated with test outcome of ongoing three years field exposure conditions. The field study will include different parameters of investigation for high performance concrete including corrosion inhibitors, type of reinforcement, natural and industrial pozzolanic additives, water to cement ratio, water type, cover thickness, curing conditions, and concrete coatings. Like the laboratory specimens, samples in the field will be monitored for corrosion induced deterioration signs and for any signs of failureover initial period ofthree years. In this paper, laboratory results pertaining to microsilica (SF), ground granulated blast furnace slag (GGBS), epoxy coated rebars and calcium nitrite corrosion inhibitor are very conclusive. Results affirmed that the supplementary cementing materials such as GGBS and SF significantly impacted and enhanced concrete resistivity to chloride ions penetration and hence decrease the corrosion activities on steel bars protected by such concretes. As for epoxy coated rebars applications under high chloride laden conditions, results showed great concern to integrity of the epoxy coating layer on the bar and its stability. On the other hand corrosion inhibiting admixtures such as calcium nitrite proved to be more effective when used in combination with the pozzolanic additives such as GGBS and microsilica.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.793-800
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• 2006

This paper reports test results to assess the influence of superplasticizers and different admixture on the flow and compressive strength development of cementless mortar using developed hwangtoh binder. Test specimens were classified into four groups: series for I the mixing ratio of superplasticizers, series II for a kind and replacement level of admixtures according to the variation of water/hwangtoh binder ratio, series III for the specific surface area and replacement level of ground granulated blast-furnace slag and series IV for the replacement level of powered superplasticizer agent developed to improve slump loss of concrete. The proper replacement level of each admixture is proposed for enhancement the flow and compressive strength of the hwangtoh binder mortar.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.466-473
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• 2017

RC (Reinforced Concrete) member has varying service life due to varying diffusion characteristics with loading conditions even if it is exposed to constant exterior conditions. In the paper, quantitative parameters are obtained through adopting the previous results for effects of compressive, tensile, and cold joint on chloride diffusion in OPC (Ordinary Portland Cement) and GGBFS (Ground Granulated Blast Furnace Slag) concrete. Service life is evaluated in RC simple beam with 10.0m of span through increasing loading from self weight (2.5kN/m) to the loading to cracking moment (5.5kN/m). In OPC concrete without cold joint, service life changes to 89.4% for tensile region and 101% for compressive region with loadings while GGBFS concrete has 80.0% and 106%, respectively. For cold joint area, GGBFS concrete shows much reduced service life to 82~80% in compressive region and 69~61% in tensile region, which is caused by the lower diffusion in normal condition but relatively higher increasing cold joint effect than OPC concrete.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6A
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• pp.427-435
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• 2012

In order to evaluate the effects of exposure conditions on the resistance to sulfate attack of normal and blended cement mortars, several mechanical characteristics of the mortars such as expansion, strength and bulk density were regularly monitored for 52 cycles under sodium sulfate attack. The mortar specimens were exposed to 3 different types of exposure conditions; 1) continuous full immersion(Exposure A), continuous half-immersion(Exposure B) and cyclic wetting-drying(Exposure C). Experimental results indicated that the maximum deterioration was noted in OPC mortar specimens subjected to Exposure B, showing the wide cracks in the portions where attacking solution is adjacent to air. Additionally, the beneficial effect of ground granulated blast-furnace slag and silica fume was clearly observed showing a superior resistance against sodium sulfate attack, because of its lower permeability and densified structure. Thus, it is suggested that when concrete made with normal cement is exposed to sulfate environment, proper considerations on the exposure conditions should be taken.