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Enhancement of the Strength of MgO-Based Binder by Accelerated Carbonation

촉진탄산염화에 의한 마그네슘계 고화제의 강도 향상 특성

  • Yun, Do Youn (School of Civil & Environmental Engineering, Pusan National University) ;
  • Ahn, Jun-Young (School of Civil & Environmental Engineering, Pusan National University) ;
  • Kim, Cheolyong (School of Civil & Environmental Engineering, Pusan National University) ;
  • Kim, Tae Yoo (School of Civil & Environmental Engineering, Pusan National University) ;
  • Hwang, Inseong (School of Civil & Environmental Engineering, Pusan National University)
  • 윤도윤 (부산대학교 사회환경시스템공학과) ;
  • 안준영 (부산대학교 사회환경시스템공학과) ;
  • 김철용 (부산대학교 사회환경시스템공학과) ;
  • 김태유 (부산대학교 사회환경시스템공학과) ;
  • 황인성 (부산대학교 사회환경시스템공학과)
  • Received : 2016.11.15
  • Accepted : 2016.12.08
  • Published : 2016.12.31

Abstract

MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.

Keywords

References

  1. Alhozaimy, A., Al-Negheimish, A., Alawad, O. A., Jaafar, M. S., and Noorzaei, J., 2012, Binary and ternary effects of ground dune sand and blast furnace slag on the compressive strength mortar, J. Cem. Concr. Compos., 34, 734-738. https://doi.org/10.1016/j.cemconcomp.2012.03.002
  2. Ali, M.B., Saidur, R., and Hossain, M. S., 2011, A review on emission analysis in cement industries, J. Renewable and Sustainable Energy, 15, 2252-2261. https://doi.org/10.1016/j.rser.2011.02.014
  3. Atis, C.D., 2003, Accelerated carbonation and testing of concrete made with fly ash, J. Constr. Build. Mater., 17, 147-152. https://doi.org/10.1016/S0950-0618(02)00116-2
  4. Benhelal, E., Zahedi, G., Shamsaei, E., and Bahadori, A., 2013, Global strategies and potentials to curb $CO_2$ emissions in cement industry, J. Cleaner Prod., 51, 142-161. https://doi.org/10.1016/j.jclepro.2012.10.049
  5. Choate, W.T., 2003, Energy and Emission Reduction Opportunities for the Cement Industry. U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy, Industrial Technologies Program. p.55.
  6. Duxson, P., Provis, J.L., Lukey, G.C., and van Deventer, J.S., 2007, The role of inorganic polymer technology in the development of 'green concrete', J. Cem. Concr. Res., 37, 1590-1597. https://doi.org/10.1016/j.cemconres.2007.08.018
  7. Du, C., 2005, A review of magnesium oxide in concrete, Concr. Int., 45-50.
  8. Gao, P., W, S., Lu, X., D, Min., Lin, P., Wu, Z., and Tang, M., 2007, Soundness evaluation of concrete with MgO, J. Constr. Build. Mater., 21, 132-138. https://doi.org/10.1016/j.conbuildmat.2005.06.033
  9. Gao, P., Lu, X., Geng, F., Li, X., Hou, J., Lin, H., and Shi, N., 2008, Production of MgO-type expansive agent in dam concrete by use of industrial by-products, Build. Environ., 43, 453-457. https://doi.org/10.1016/j.buildenv.2007.01.037
  10. Haha, M, B., Lothenbach, B., and Saout, G. L., and Winnefeld, F., 2011, Influence of slag chemistry on the hydration of alkaliactivated blast-furnace slag-Part I: Effect of MgO, J. Cem. Concr. Res., 41, 955-963. https://doi.org/10.1016/j.cemconres.2011.05.002
  11. Hwang, K.-Y., Seo, J.-Y., Phan, Hoang Q. H., Ahn, J,-Y., and Hwang, I., 2013, MgO-Based Binder for Treating Contaminated Sediments: Characteristics of Metal Stabilization and Mineral Carbonation, CLEAN SOIL AIR WATER, 42(3), 355-363.
  12. Iwasaki and Tada, S., 1985, Carbonation of Aerated Concrete, Beijing Int. Symp. Cem. Concr., 3, 414-423.
  13. Jang, B., Kwon, Y., Choi, S., and Lee, K., 2011, Fundamental Properties of Cement Composites Containing Lightly Burnt MgO Powders, J. Korea Concrete Institute, 23(2), 225-233. https://doi.org/10.4334/JKCI.2011.23.2.225
  14. Jin, F., Gu, K., and Al-Tabbaa, a., 2014, Strength and drying shrinkage of reactive MgO modified alkali-activated slag paste, J. Constr. Build. Mater., 51, 395-404. https://doi.org/10.1016/j.conbuildmat.2013.10.081
  15. Jin, F. and Al-Tabbaa, b., 2014, Evaluation of novel reactive MgO activated slag binder for the immobilisation of lead and zinc, Chemosphere, 117, 285-294. https://doi.org/10.1016/j.chemosphere.2014.07.027
  16. Kim J.Y., 2014, Characteristics of heavy metals immobilization and carbonation of MgO-based binder depending on $CO_2$ con centration, Master dissertation, Pusan National University, Korea
  17. Kim, T. and Jun, Y., 2015, The Strength and Drying Shrinkage Properties of Alkali-activated Slag using Hard-burned MgO, J. the Korea Institute for Structural Maintenance and Inspection, 19(3), 39-47. https://doi.org/10.11112/jksmi.2015.19.3.039
  18. Kwon, Y.H., Kwon, Y.H., and Lee, D.G., 2013, A Study on the Quality Properties of Alkali-activated cement free Mortar using Industrial by-products, J. Rec Const Resources, 1(1), 58-66.
  19. Li, X., Ma, X., Zhang, S., and Zheng, E., 2013, Mechanical Properties and Microstructure of Class C Fly Ash-Based Geopolymer Paste and Mortar, J. Mater., 6, 1485-1495. https://doi.org/10.3390/ma6041485
  20. Lui, Z., Cui X., and Tang, M., 1992, Hydration and Setting Time of MgO-type Expansive Cement, Cement and Concrete Research, 22(1), 1-5. https://doi.org/10.1016/0008-8846(92)90129-J
  21. Maria, S.K. and Suurenda, P.S., 2003, Hydration and properties of novel blended cements based on cement kiln dust and blast furnace slag, J. Cem. Concr. Res., 33, 1269-1267. https://doi.org/10.1016/S0008-8846(03)00061-9
  22. Maroto-Valer, M.M., Fauth, D.J., Kuchta, M.E., Zhang, Y., and Andresen, J.M., 2005, Activation of magnesium rich minerals as carbonation feedstock materials for $CO_2$ sequestration, Fuel Process. Technol., 86, 1627-1645. https://doi.org/10.1016/j.fuproc.2005.01.017
  23. McCarthy, M.J. and Dhir, R.K., 2005, Development of high volume fly ash cements for use in concrete construction, Fuel, 84, 1423-1432. https://doi.org/10.1016/j.fuel.2004.08.029
  24. Mo, L., Deng, M and Tang, M., 2010, Potential Approach to Evaluating Soundness of Concrete Containing MgO-Based Expansive Agent, J. Mater., 107(2), 99-105.
  25. Mo, L. and Panesar, D.K., 2012, Effects of accelerated carbonation on the microstructure of Portland cement pastes containing reactive MgO, J. Cem. Concr. Res., 42, 769-777. https://doi.org/10.1016/j.cemconres.2012.02.017
  26. Mo, L., Deng, M., Tang, M., and Al-Tabbaa, A., 2014, MgO expansive cement and concrete in China: Past, present and future, J. Cem. Concr. Res., 57, 1-12. https://doi.org/10.1016/j.cemconres.2013.12.007
  27. Morandeau, A., Thiery, M., and Dangla, P., 2015, Impact of accelerated carbonation on OPC cement paste blended with fly ash, J. Cem. Concr. Res., 67, 226-236. https://doi.org/10.1016/j.cemconres.2014.10.003
  28. Panesar, D.K. and Mo, L., 2013, Properties of binary and ternary reactive MgO mortar blends subjected to $CO_2$ curing, J. Cem. Concr. Compos., 38, 40-49. https://doi.org/10.1016/j.cemconcomp.2013.03.009
  29. Palacios, M. and Puertas, F., 2006, Effect of Carbonation on Alkali-Activated Slag Paste, J. Am. Ceram. Soc., 89(10), 3211-3221. https://doi.org/10.1111/j.1551-2916.2006.01214.x
  30. Sung, M., Cho, H., and Lee, H., 2015, Properties of Cement Paste Containing High Volume ${\gamma}$-C2S and MgO Subjected to $CO_2$ Curing, Korea Institute of Building and Construction, 15(3), 281-289. https://doi.org/10.5345/JKIBC.2015.15.3.281
  31. Unluer, C. and Al-Tabbaa, A., 2013, Impact of hydrated magnesium carbonate additives on the carbonation of reactive MgO cements, J. Cem. Concr. Res., 54, 87-97. https://doi.org/10.1016/j.cemconres.2013.08.009
  32. Vahid, R,, Yixin, S., and Andrew, J.B., 2012, Carbonation curing versus steam curing for precast concrete production, J. Mater. Civ. Eng., 10, 1221-1229.
  33. Vandeperre, L.J. and Al-Tabbaa, A., 2007, Accelerated Carbonation of Reactive MgO Cement, Adv. Cem. Res., 38, 40-49
  34. Yi, Y., Liska, M., Unluer, C., and Al-Tabbaa, A., 2013, Carbonating magnesia for soil stabilization, Can. Geotech. J., 50(8), 899-905. https://doi.org/10.1139/cgj-2012-0364