• Title/Summary/Keyword: gap opening

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Kinetic Study on the Cationic Polymerization of Glycidyl Azide Monomer(GAM) by Real-Time In-suti IR (실시간 In-situ IR을 이용한 Glycidyl Azide Monomer(GAM)의 양이온중합 반응속도 연구)

  • Kim, Hyoung-Sug;Kim, Kwan-Yung;Kang, Shin-Choon;Noh, Si-Tae;Kim, Jin-Seuk;Yu, Jae-Chul;Choi, Keun-Bae
    • Journal of the Korea Institute of Military Science and Technology
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    • v.12 no.2
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    • pp.228-235
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    • 2009
  • We synthesized glycidyl azide monomer(GAM) as a monomer for polymerization of glycidy azide polymer(GAP) which is a promising energetic prepolymer for a plastic-bonded explosive. Using quantitative real-tim in-situ infrared(in-situ IR) spectroscopy, kinetic study on the cationic ring opening polymerization of GAM was carried out. The reaction rate was obtained from monitoring the change of ether C-O stretching band($1050cm^{-1}$) in series IR spectra. The reaction was in accordance with the first-order reaction law for each of reaction temperature at 100/1 mole ratio of [GAM]/[$BF_3*etherate$]. In the ring opening polymerization of GAM, with ratio of [GAM]/[$BF_3*etherate$] to equal 100/1 at various temperature, the activation parameters obtained from the evaluation of kinetic data were ${\Delta}H^*$=14.34kcal/mol, ${\Delta}S^*=-12.31cal/mol{\cdot}K$ and $E_a$=14.89kcal/mol.

Variations in subtidal surface currents observed with HF radar in the costal waters off the Saemangeum areas (새만금 연안역에서 HF radar에 의해 관측된 조하주기 표층해류의 변화)

  • Kim, Chang-Soo;Lee, Sang-Ho;Son, Young-Tae;Kwon, Hyo-Keun;Lee, Kwang-Hee;Choi, Byoung-Hy
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.1
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    • pp.56-66
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    • 2008
  • Subtidal surface currents are derived from HF radar measurements in the Saemangeum coastal ocean of the Yellow sea in July 2002 and from September to November 2004. The surface current field is analyzed to examine the effect of wind, river plume and coastline change on the spatial distribution and temporal variation of the surface currents. In July 2002, average wind speed was 0.5 m/s and freshwater discharge from the Keum River was $0.88{\times}10^7\;ton/day$. Temporal mean currents ($\overline{U}$) flow to the northwest with speed of $7{\sim}10\;cm/s$ near the Keum River estuary, to the west as fast as 13 cm/s near the opening gap of the Saemangeum $4^{th}$ dyke, and to the northwest off the Gogunsan-archipelago. This flow pattern is a result of the Keum River plume dispersal and tide-residual currents from the opening gap of the Saemangeum $4^{th}$ dyke. Time series of spatially-averaged current (<$U-\overline{U}$>) direction is highly (r=0.98) correlated with wind direction. From September to November 2004, the opening gap of the Saemangeum $4^{th}$ dyke was closed, northwesterly wind blew with speed of 2.5 m/s on average and the Keum River discharge was $1.19{\times}10^7\;ton/day$. Temporal mean current field ($\overline{U}$) has weak surface flow in most of the coastal ocean and relatively strong currents flow to the southwest with speed of 10 cm/s along the shape coastline of the Gogunsan-archipelago and the Saemangeum $4^{th}$ dyke. The strong flow is generated by the prevailing northwesterly wind which pushes the Keum River plume toward the Saemangeum $4^{th}$ dyke. The residual currents from the opening gap of the Saemangeum $4^{th}$ dyke disappeared and correlation coefficient between time series of spatially-averaged current () direction and the wind direction is 0.69.

Effect of Orientation on Pool Boiling Heat Transfer in Annulus with Small Gap (경사각이 좁은 틈새를 가지는 환상공간 내부 풀비등 열전달에 미치는 영향)

  • Kang, Myeong-Gie
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.3
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    • pp.237-244
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    • 2011
  • An experimental study was carried out to investigate the effect of the inclination angle on the nucleate pool boiling of saturated water at atmospheric pressure. We considered an annulus with a gap of 5 mm and a bottom opening. The inner tube of the annulus was heated, and the outer diameter and the length of the tube were 25.4 mm and 500 mm, respectively. The inclination angle was varied from horizontal to vertical. The results were compared to those for an annulus with a larger gap and a single tube. In the small-gap annulus, the effect of the inclination angle on the heat transfer was not significant. However, an early onset of the critical heat flux was observed at 80 kW/$m^2$ when the annulus was horizontal. Liquid agitation and bubble coalescence were considered to be the major heat-transfer mechanisms.

Gap comparison between single crown and three-unit bridge zirconia substructures

  • Anunmana, Chuchai;Charoenchitt, Masnisa;Asvanund, Chanavut
    • The Journal of Advanced Prosthodontics
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    • v.6 no.4
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    • pp.253-258
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    • 2014
  • PURPOSE. To compare marginal and internal gaps of zirconia substructure of single crowns with those of three-unit fixed dental prostheses. MATERIALS AND METHODS. Standardized Co-Cr alloy simulated second premolar and second molar abutments were fabricated and subsequently duplicated into type-III dental stone for working casts. After that, all zirconia substructures were made using $Lava^{TM}$ system. Marginal and internal gaps were measured in 2 planes (mesial-distal plane and buccal-palatal plane) at 5 locations: marginal opening (MO), chamfer area (CA), axial wall (AW), cusp tip (CT) and mid-occlusal (OA) using Replica technique. RESULTS. There were significant differences between gaps at all locations. The $mean{\pm}SD$ of marginal gap in premolar was $43.6{\pm}0.4{\mu}m$ and $46.5{\pm}0.5{\mu}m$ for single crown and 3-unit bridge substructure respectively. For molar substructure the $mean{\pm}SD$ of marginal gap was $48.5{\pm}0.4{\mu}m$ and $52.6{\pm}0.4{\mu}m$ for single crown and 3-unit bridge respectively. The largest gaps were found at the occlusal area, which was $150.5{\pm}0.5{\mu}m$ and $154.5{\pm}0.4{\mu}m$ for single and 3-unit bridge premolar substructures respectively and $146.5{\pm}0.4{\mu}m$ and $211.5{\pm}0.4{\mu}m$ for single and 3-unit bridge molar substructure respectively. CONCLUSION. Independent-samples t-test showed significant differences of gap in zirconia substructure between single crowns and three-unit bridge (P<.001). Therefore, the span length has the effect on the fit of zirconia substructure that is fabricated using CAD/CAM technique especially at the occlusal area.

An Analysis of the Meaning of Laughter by Comedians Hee-Gap Kim, Bong-Seo Koo and Young-Chun Seo : focusing on Korean Comedy Movies in the late 1960s (코미디언 김희갑, 구봉서, 서영춘의 웃음 의미작용 분석 : 1960년대 후반기 한국 코미디영화를 중심으로)

  • Seo, Kok-Suk
    • Journal of Korea Entertainment Industry Association
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    • v.15 no.8
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    • pp.75-89
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    • 2021
  • In this paper, the results of analyzing the meaning of laughter in comedy movies of the late 1960s, focusing on comedians, Hee-Gap Kim, Bong-Seo Koo and Young-Chun Seo, are as follows. First, the narrative laughter of the comedians represents the generational conflict between the lower class and the upper class, the gender conflict between men and women, and the frustration of reality. Second the mechanism of creating laughter of the comedians shows ridicule of the conservative older generation, revelation of the immoral upper class, and caricature of the frustrated lower class. Third, the practical aspect of the comedians' laughter reveals cracks in tradition and modern, gaps in economic inequality, and expression of prohibited desires. Therefore, comedians Hee-Gap Kim, Bong-Seo Koo and Young-Chun Seo in comedy movies of the late 1960s show the semantic effect of laughter of internal/external boundaries and optimistic world views through the closed opening of informal culture and the conflict of characters/performers.

The effect of mechanical inhomogeneity in microzones of welded joints on CTOD fracture toughness of nuclear thick-walled steel

  • Long Tan;Songyang Li;Liangyin Zhao;Lulu Wang;Xiuxiu Zhao
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4112-4119
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    • 2023
  • This study employs the microshear test method to examine the local mechanical properties of narrow-gap welded joints, revealing the mechanical inhomogeneity by evaluating the microshear strength, stress-strain curves, and failure strain. On this basis, the influence of weld joints micromechanical inhomogeneity on the crack tip opening displacement (CTOD) fracture toughness is investigated. From the root weld layer to the cover weld layer, the fracture toughness at the center of the weld seam demonstrates an increasing trend, with the experimental and calculated CTOD values showing a good correspondence. The microproperties of the welded joints significantly impact the load-bearing capacity and fracture toughness. During the deformation process of the "low-matching" microregions, the plastic zone expansion is hindered by the surrounding microregion strength constraints, thus reducing the fracture toughness. In contrast, during the deformation of the "high-matching" microregions, the surrounding microregions absorb some of the loading energy, partially releasing the concentrated stress at the crack tip, which in turn increases the fracture toughness.

The Analysis of e-Learning Gap among Regions in the Context of Adult Learning (성인 인적자원개발 영역에서의 지역 간 교육격차 및 e-Learning 인식 수준 연구)

  • Cho, Jae-Jeong;Lee, Sook-Young
    • Journal of Digital Contents Society
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    • v.11 no.2
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    • pp.265-276
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    • 2010
  • The purpose of this study was to investigate the Korean Local Government's recognition on the educational gap among regions in the filed of adult learning including vocational education and life long-learning. The study also tried to figure out the local government's recognition and infrastructure of e-Learning which is suggested as one of the solutions on the regional gap of educational opportunities and quality. This study took 12 HRD(Human Resources Development) centers funded and operated by the Korean Local Governments except Seoul and Kyong-Gi classified by the metropolitan areas in Korea. As a result, firstly it was found that the local governments had perception on the difference and gap of educational opportunities and quality among regions in the area of adult education. Especially, the perception was relatively more serious on quality than quantity. Secondly, the result showed the large gap among regions on the area of opening educational and training programs, the quality of teachers and tutors, the effectiveness and outcomes of educational programs. Thirdly, they perceived more serious educational gap on face-to-face classes rather than e-Learning in the context of educational methodology. It also revealed that the local governments had relatively better foundations on physical systems than other infrastructures and resources such as human-ware, culture-ware and soft-ware(contents, programs etc.). It was recommended to consider these findings in developing and implementing future educational policies to solve the problem of regional gap on education.

CLINICAL STUDY OF TEMPOROMANDIBULAR JOINT ANKYLOSIS (악관절 강직증에 관한 임상적 연구)

  • Song, Min-Seok;Min, Byong-Il
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.17 no.1
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    • pp.60-72
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    • 1995
  • Temporomandibular joint ankylosis is the movemental obstacle of mandible which depend on proliferation of bony or fibrous tissue in temporomandibular joint structure by various causes. In order to treat this, various surgical methods have been performed, but no operative methods have been produced consistently successful results. This research has been performed to the patients who had been operated due to temporomandibular joint ankylosis by studying classification, cause, onset, duration, anesthesia and treatment method, symptom, change of mouth opening, complication through medical record, X-ray, follow-up for being a help to proper selection of treatment method and evaluation of prognosis. The author obtained the following results by analyzing 44 cases among patients who had been operated due to temporomandibular joint ankylosis during 8 year hospitalization from 1986 to 1993 in Dept. of Oral & Maxillofacial Surgery of Seoul National University Hospital. 1. The occurrence was in the order of below 10, 20's, 10's, 30's. The average of occurrence was 12.95. Illness period was 50.0% within 10 years and 50% beyond 10 years. The average period of illness was 13.33 years. 2. Trauma occupied 54.5% of causes and inflammation occupied 45.5%. Men had more occurrences due to trauma and there was no difference in case of inflammation. 3. In nasotracheal intubations for general anesthesia, the cases of using fiberoptic laryngoscope occupied 40.9%, direct or blind nasotracheal intubation occupied 40.9% and the cases of using tracheostomy occupied 18.2%. 4. In operative approaching methods, submandibular & preauricular approach were mainly applied, and in operative methods, high condylectomy(Group I) occupied 11.4%, arthroplasty without interpositional material following condylectomy or gap ostectomy(Group II) occupied 11.4%, with interpositional material following high condylectomy (Group III) occupied 40.9%, and using condylar reconstruction following condylectomy or gap ostectomy(Group IV) occupied 36.6%. 5. In change of mouth opening reformed after surgery, Group III showed the best result of average 23.5mm, Group IV showed 16.3mm, Group I showed 14.9mm and Group II showed 10.2mm of reformation. Summarizing the results as written above, it is considered that early treatment is important as soon as possible in Temporomandibular joint ankylosis. It is recommended in surgical method what can lead to postoperative early movement maintaining anatomaical & functional form, and then the development of various surgical methods will be requested.

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Clinical Application of Great Saphenous Vein Graft in the Oral and Maxillofacial Reconstruction (구강악안면 재건을 위한 대복재정맥의 유용성)

  • Park, Jung-Min;Kim, Soung-Min;Seo, Mi-Hyun;Kang, Ji-Young;Myoung, Hoon;Lee, Jong-Ho
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.34 no.2
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    • pp.140-147
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    • 2012
  • Microvascular reconstruction, in the oral and maxillofacial regions, is a widely accepted as the best way to overcome the complex oral cavity defects. Many patients requiring composite reconstructions have been treated previously with radiation therapy, chemotherapy, selective and/or functional neck dissection or any of these combinations. In many cases of these patients, inadequate neck vessels for the microanastomosis of free flap are available, due to a lack of recipient vessels in the neck, poor vessel quality or vessel caliber mismatch. To achieve a tension-free anastomosis, vein grafting must be considered to span the vessel gap between the free flap pedicle and the recipient neck vessels. Although most microsurgeons believed that interpositional grafts are to be avoided due to vessel thrombosis and increased number of necessary microanastomosis, we, authors have some confidence of equivalency between reconstruction with and without interpositional saphenous vein graft. The great saphenous vein, also known as the long saphenous vein, is the large subcutaneous superficial vein of the leg and thigh. It joins with the femoral vein in the region of femoral triangle at the saphenofemoral junction, and coursed medially to lie on the anterior surface of the thigh before entering an opening in the fascia lata, called the saphenous opening. For a better understanding of the great saphenous vein graft for the interpositional vessel graft in the oral cavity reconstructions, and an avoidance of any uneventful complications during these procedures, the related surgical anatomies with their harvesting tips are summarized in this review article in the Korean language.

Three-Dimensional Flow and Aerodynamic Loss Downstream of Turbine Rotor Blade with a Cutback Cavity Squealer Tip (터빈 동익 컷백스퀼러팁 하류에서의 3차원 유동 및 압력손실)

  • Kim, Seon-Ung;Lee, Sang-Woo
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.1
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    • pp.48-54
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    • 2011
  • The effect of channel cutback on three-dimensional flow fields and aerodynamic losses downstream of a cavity squealer tip has been investigated in a turbine rotor cascade for the squealer rim height-to-chord ratio and tip gap height-to-chord ratio of $h_{st}/c$ = 5.51% and h/c = 2.0% respectively. The cutback length-to-camber ratio is changed to be $CB/c_c$ = 0.0, 0.1, 0.2 and 0.3. The results show that longer cutback delivers not only stronger secondary flow but also higher aerodynamic loss in the tip leakage vortex region, meanwhile it leads to lower aerodynamic loss in the passage vortex region. The discharge of cavity fluid through the cutback opening provides a beneficial effect in the reduction of aerodynamic loss, whereas there also exists a side effect of aerodynamic loss increase due to local wider tip gap near the trailing edge. With increasing $CB/c_c$ from 0.0 to 0.3, the aerodynamic loss coefficient mass-averaged all over the measurement plane tends to increase slightly.