• 보존과학연구
• /
• s.13
• /
• pp.81-95
• /
• 1992

The old books which have been colored to brown spots were analyzed chemically to compare with white part. The original raw materials were paper mulberry (Broussonetia Kazine) and woodpulp. White part contained58.8%($\alpha$-37.2%,$\beta$-8.6%, $\gamma$-12.7%)cellulose, 21.7% hemicellulose, 19.8% lignin,4.4% pentosan and brown sopt part contained 49.1%($\alpha$-19.8%, $\beta$-14.5%,$\gamma$-14.8%) cellulose, 27.1% hemicellulose, 23.8% lignin, 4.8% pentosan. Both of brown spot and white parts contained starch without protein. The pH was 4.9 in brown and 5.0 in white part respecitively. The brown spot parts were more solidified than white parts according to SEM observation. Difference of organiccompinent in brown part came from white part were 2-hydroxy-benzaldehydeand phenol.

• Journal of Korean Society of Forest Science
• /
• v.50 no.1
• /
• pp.1-4
• /
• 1980

The Chemical components of Abies koreana Wilson grown in Korea were analized. The results obtained were summarized as follows. 1. The ash content is ca 0.56% on the average, and of the range is 0.33 to 0.76%. 2. The cold water extractive content is ca 8.76% on the average and of the range is 5.55 to 12.5%. 3. The hot water extractive content is ca 10.16% on the average and of the range is 4.80 to 13.65%. 4. Basic extractive content is ca 14.60% on the average and of the range is 5.51 to 25.44%. 5. The alcohol benzol soluble fraction is ca 4. 23% and of the range is 2.94 to 5.44%. 6. The holocellulose content is ca 76.49% on the average and of the range is 73.68% to 79.10%. 7. The cellulose content is ca 56.30% on the average and of the range is 46.02% to 61. 33%. The cellulose contains 78.54% ${\alpha}$-cellulose, 7.66% ${\beta}$-cellulose and 14.04% ${\gamma}$-cellulose respectively. 8. The Klason lignin content is ca 25.03% on the average and of the range is 22.5 to 27.0%. In conclusion, ash content is comparable to the other needle leaf trees. It has 76.49% in holocellulose content which is comparable value to the Pinus densiflora's. It has lower value than the Pinus densiffora in pentosan and lignin content. Having not resin cannal in xylem and long tracheid, this wood could be usable industrial material.

• Applied Chemistry for Engineering
• /
• v.8 no.6
• /
• pp.934-938
• /
• 1997

Acrylic acid was grafted onto the peroxidized cellulose which was stored at room temperature for 20 days after ${\gamma}$-ray irradiation in air. The effect of acids and metallic salts on the grafting yields was determined. The addition of both the acid and metallic salt was found to accelerate the grafting yield much more than the only metallic salt, and the addition of $FeSO_4{\cdot}7H_2O$ led to much higher grafting yield than that of $CuSO_4{\cdot}5H_2O$. The effect of acid on the grafting yield increased by the order $H_2>SO_4>HCl>HNO_3>CH_3COOH$. With the addition of $H_2SO_4$, the grafting yield rapidly increased up to $7{\times}10^{-2}$M, and then levelled off.

• Nuclear Engineering and Technology
• /
• v.15 no.1
• /
• pp.1-10
• /
• 1983

By controlling both the means of grafting and the cast-solution components, no degradation and dimensional change of radiation-induced graft polymerization were found. The electric resistance of styrene-cellulose acetate grafts increases with increasing styrene content, while those for the hydrophilic monomers show no marked effect. In comparison with the grafted cellulose acetate membrane by simultaneous irradiation method, the appearance of the grafted membrane by post-polymerization method was not markedly changed irrespective of the percent of grafting and radiation dose of electron beam or ${\gamma}$-ray. The combination of crosslinking agents such as divinyl benzene (OB) or trimethyl propane triacrylate (TMPT) in the VP:St:BPO system leads to gradual increase of the percent of grafting. The activation energy for grafting of St:VP:BPO solution onto cellulose acetate membrane was determined to be about 21.8 Kcal/mole over the range of 55$^{\circ}$-8$0^{\circ}C$. The initial rate of grafting (in %/hr) is proportional to the power 0.76 for dose intensities.

• Korean Journal of Veterinary Research
• /
• v.31 no.1
• /
• pp.99-108
• /
• 1991

To observe the changes of serum proteins according to the process of Babesia gibsoni(B gibsoni) infection, the babesia protozoa($10^8/kg$) were inoculated into the cephalic vein of healthy dogs. The serum proteins of experimentally infected dogs were separated by using cellulose acetate electrophoresis. The results obtained were as follows; 1. Cellulose acetate electrophoresis was fractionated to total 6 of bands such as, albumin, ${\alpha}_1$, ${\alpha}_2$, ${\beta}_1$, ${\beta}_2$ and $\gamma$-globulin. 2. The concentration of total protein was shown a decreasing tendency after B gibsoni infection. Albumin and A/G ratio were lowered through all periods of the infection, but they were not significant changes. 3. The level of ${\alpha}_1$-globulin was significantly(p<0.05) incresed in early stage of the infection. 4. The levels of ${\alpha}_2$ and total $\alpha$-globulin were shown highly significant decreases (p<0.01) through all periods of the infection. 5. The levels of ${\beta}_1$ and total $\beta$-globulin had highly significant changes (p<0.01) that was increased in early stage of infection and decreased later. 6. The level of $\gamma$-globulin was seen to be constantly increased through all periods of infection. It was a highly significant change (p<0.01). 7. Plasma protein: fibrinogen (PP:F) ratio was shown a temporally significant increase (p<0.05) following the decrease in early infection.

• Korean Chemical Engineering Research
• /
• v.55 no.1
• /
• pp.34-39
• /
• 2017

In this study, intermolecular crosslinked carboxymethyl cellulose sodium salt (CMC) and porcine Cartilage Acellular Matrix (PCAM) blended hydrogel films for anti-adhesive barriers were prepared by gamma-ray radiation. The effects of the CMC/PCAM concentration and blending ratio on the morphology, gel fraction, gel strength, and degree of swelling were determined. The results indicated that crosslinked CMC/PCAM films show significantly lower the gel-fraction than CMC films. The degree of attachment and proliferation of human vascular endothelial cells on CMC/PCAM films was lower than the CMC films. We show the capacity of the CMC and PCAM to be hydrogel films, and the ability to reduce cell adhesion and proliferation on these films by modification with cell anti-adhesion molecules of PCAM. In conclusion, this study suggests that radiation cross-linked CMC/PCAM hydrogel films endowed with anti-adhesion ligands may allow for improved regulation of cell anti-adhesion behavior for prevent peritoneal adhesions.

• Korean Journal of Food Science and Technology
• /
• v.46 no.2
• /
• pp.256-261
• /
• 2014

This study was conducted to determine the effect of gamma-ray and electron-beam irradiation on dried spices (black pepper, red pepper, parsley, and basil) using the photostimulated luminescence (PSL), thermoluminescence (TL) and electron spin resonance (ESR) methods. The spices were irradiated at 0, 1, 5, and 10 kGy. All non-irradiated spices had photon counts (PCs) less than 700 PCs. The PCs of three irradiated spices (red pepper, parsley, and basil) were clearly distinguishable from those of non-irradiated ones, exhibiting PSL signals higher than 5000 PCs. However, negative PSL counts (<700 PCs) were obtained for most irradiated black pepper, except those irradiated with 5 kGy gamma rays and 10 kGy electron-beams. TL glow curves of the irradiated spices showed a higher peak at $150-250^{\circ}C$. TL ratios were found to be less than 0.1 for non-irradiated spices and higher than 0.1 for irradiated ones. No ESR signal was observed for any irradiated spice except red pepper, which displayed cellulose-based ESR spectra. Therefore, the results suggest that the PSL, TL, and ESR methods are effective detection techniques for dried spices irradiated with electron beams as well as gamma rays.

• Polymer(Korea)
• /
• v.33 no.6
• /
• pp.551-554
• /
• 2009

Poly (vinyl alcohol) (PVA) and carboxymethyl cellulose (CMC) have received increasing attention in biomedical and biochemical applications because of their properties such as being water-soluble and biocompatible. In this study, a PVA/CMC hydrogel applicable to artificial cartilage was prepared by a freezing-thawing technique and a gamma-ray irradiation. The solid concentration of PVA was 7 wt% and the concentration of CMC was 4 wt%. The freezing/thawing process was repeated twice and the dose of gamma-ray irradiated was 30 kGy. Results of gelation before and after gamma-ray irradiation were similar, but the swelling degree decreased and compressive strength increased. The cytotoxicity was investigated with CCK-8 assay.

• Korean Chemical Engineering Research
• /
• v.50 no.3
• /
• pp.435-441
• /
• 2012

The direct conversion of cellulose into polyols in $H_2$ was examined over Pt catalysts supported on various zeolites, viz., mordenite, Y, ferrierite, and ${\beta}$. For comparison, Pt catalysts supported on ${\gamma}-Al_2O_3$, $SiO_2-Al_2O_3$, and $SiO_2$ were also tested. The physical properties of the catalysts were probed with $N_2$ physisorption. The surface acidity was measured with temperature programmed desorption of ammonia ($NH_3$-TPD). The Pt content was quantified with inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The Pt dispersion was determined with CO chemisorptions and transmission electron microscopy (TEM). The conversion of cellulose appeared to be mainly dependent on the reaction temperature and reaction time because it depends on the concentration of $H^+$ ions reversibly formed in hot water. Pt/H-mordenite (20) showed the highest yield to polyols among the tested catalysts. Pt/H-zeolite was superior to Pt/Na-zeolite for this reaction. The polyol yield was dependent on the surface acid density and the external surface area.

• Journal of Nutrition and Health
• /
• v.7 no.4
• /
• pp.33-37
• /
• 1974

Changes in the concentration of total protein, albumin, ${\alpha}_1-,{\alpha}_2-,{\beta}-,$ and ${\gamma}-globulin$ in Serum from 138 healthy, normal pregnant woman were studied by the method of cellulose-acetate electrophoresis. 1. The concentration of total serum protein decreased gradually during the first 7 month, and showed a tendency to increase thereafter. 2. The concentration of serum albumin showed a steady continuous fall untill term. 3. During pregnancy,${\alpha}_1$ and ${\beta}-globulin$ value rose, ${\gamma}-globulin$ value fell and ${\alpha}_2-globulin$ value showed no significant change.