• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2004년도 춘계학술대회 논문집
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• pp.76-81
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• 2004

Injection molding is the most widely used process fir the industrial forming of plastic articles. During an injection molding process of composites, the fiber-matrix separation and fiber orientation are caused by the flow of molten polymer/fiber mixture. As a result. the product tends to be nonhomogeneous and anisotropic. Hence, it is very important to clarify the relations between separation orientation and injection molding conditions. So far, there is no research on the measurement of fiber orientation using image processing. In this study, the effects of fiber content ratio and molding condition on the fiber orientation-angle distributions are studied experientially. Using the image processing method, the fiber orientation distribution of welding pars in injection-molded products is assessed. And the effects of fiber content and injection mold shapes on the fiber orientation in case of fiber reinforced polymeric composites are studied experimentally.

• Advanced Composite Materials
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• 제18권2호
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• pp.153-166
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• 2009

A matrix method for evaluating effective electro-magneto-thermo-elastic properties of a generally anisotropic multilayered composite is presented. Physical variables are categorized into two groups: one that satisfies the continuity across the interface between layers and another that satisfies an average inter-layer compatibility (which is also exact). The coupled electro-magneto-thermo-elastic constitutive equation is accordingly reassembled into submatrices, which leads to the derivation of concise and exact matrix expressions for effective properties of a multilayered composite having the coupled physical effects. Comparing the results for a purely elastic multiplayer with those from other theoretical approaches validates the developed method. Examples are given for a PZT-graphite/epoxy composite and a $BaTiO_3-CoFe_2O_4$ multiplayer which exhibit piezo-thermoelastic and magnetoelectric properties, respectively. The result shows how a strong magnetoelectric effect can be achieved by combining piezoelectric and piezomagnetic materials in a multilayered structure. The magnetoelectric coefficient of the $BaTiO_3-CoFe_2O_4$ multiplayer is compared with those for fibrous and particulate composites fabricated with the same constituents.

• EDISON SW 활용 경진대회 논문집
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• 제4회(2015년)
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• pp.304-307
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• 2015

Carbon nanotubes (CNTs) have been widely accepted and used as the enhancer for polymer nano-composites due to their remarkable mechanical properties. Understandably, the CNT fiber-polymer matrix interface plays a major role in determining the properties of the CNT-polymer nano-composites. Here, using the LCAODFT Lab tool available on the EDISON Nano-Physics site, we performed first-principles density-functional theory calculations to determine the atomic configurations and binding energies of the CNTs in contact with polymers. For the polymer matrixes, we chose poly(acrylonitrile) (PAN), which is one of the most well-known polymer matrixes for the carbon nanofiber nanocomposites. Different chiralities and diameters of pristine CNTs were considered, and several PAN-CNT configurations were prepared based on the atomistic positions and directions of cyano group in PAN. The most favorable configuration of PAN was obtained when the PAN bound parallel to the surface of CNT. Our finding indicates the binding configurations are determined by the direction of the cyano group dominantly rather than the atomistic position of PAN, or the symmetry of CNTs. The result of increasing the length of CNT diameter suggests that PAN is inclinable to align evenly on the surface of relatively large size of CNT with the configuration parallel to the surface. These results obtained in this study will provide the starting point for the design of improved PAN-CNT composites for the next-generation ultra-strong and ultra-light carbon nanofibers.

• 한국분말재료학회지
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• 제26권5호
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• pp.383-388
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• 2019

To improve the mechanical properties of aluminum, graphene has been used as a reinforcing material, yielding graphene-reinforced aluminum matrix composites (GRAMCs). Dispersion of graphene materials is an important factor that affects the properties of GRAMCs, which are mainly manufactured by mechanical mixing methods such as ball milling. However, the use of only mechanical mixing process is limited to achieve homogeneous dispersion of graphene. To overcome this problem, in this study, we have prepared composite materials by coating aluminum particles with graphene by a self-assembly reaction using poly vinylalcohol and ethylene diamine as coupling agents. The scanning electron microscopy and Fourier-transform infrared spectroscopy results confirm the coating of graphene on the Al surface. Bulk density of the sintered composites by spark plasma sintering achieved a relative density of over 99% up to 0.5 wt.% graphene oxide content.

• 한국임상수의학회지
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• 제39권2호
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• pp.65-69
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• 2022

A 5 day-old Warmblood foal was presented with a quarter crack due to the dam accidentally stepping on his left hind foot. Physical examination revealed the vertical crack included the coronary band of the medial side of the left hind hoof (quarter crack) with the lower pastern avulsion wound. Different from adult horses, the foot of the 5 day-old foal lacked adequate hoof wall thickness for stainless steel wire insertion and hoof size for a reinforcing fabric to be applied. Therefore, the authors decided to stabilize the edges of the cracked wall only by the polymethyl methacrylate (PMMA) composites without wiring and a reinforcing fabric application; and gluing a plastic shoe that was reshaped to protect the lower pastern and to spread pressure to other parts of the hoof when bearing weight. Disinfection and a supportive bandage were applied daily for 2 weeks. A month after the hoof crack accident, lameness had diminished. The quarter crack in this foal was treated successfully by the application of the composites three times with a reshaped gluing shoe, with approximately a month interval over the 4 months. After 4 months, it presented a successful functional recovery and needed no further treatment. When followed up 8 months after the accident, it revealed successful outcomes without hoof shape distortion and unbalanced hoof/limb growth.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.133.1-133.1
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• 2010

In this work, carbon black(CBs)-embed multi-walled carbon nanotubes (MWNTs) as conductive fillers for activated carbon(ACs)-based electrodes for supercapacitor were prepared by chemical reduction of oxidized MWNTs and CBs. The effect of CBs-MWNT composites on electrochemical performances of ACs-based electrodes were investigated as a function of CB-MWNT ratio. It was found that CBs-MWNTs composites were formed by the reduction reaction of the functional groups of oxidized MWNTs and CBs. It was resulted in the conjugation of CBs onto the MWNT having high surface area and aspect ratio, leading to the enhanced electrical properties of MWNTs. The electrochemical performances, such as current density, charge-discharge, and specific capacitance of the ACs/CBs-MWNT electrodes were higher than that of ACs/MWNTs and conventional ACs/CB electrodes, which was attributed to the synergistic effect of CBs-MWNTs as a conductive filler.

• Carbon letters
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• 제17권1호
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• pp.11-17
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• 2016

Recently, with continuous developments in the field of materials science, graphene oxide (GO) has emerged as a promising material with excellent electrical, thermal, mechanical, and optical properties, which play important roles in most fields. Researchers have achieved considerable progress with graphene. Chitosan (CS) is a natural polymer that has been studied intensively owing to its specific formation, high chemical resistance, and excellent physical properties. These outstanding properties have led to its universal use in applications such as textile fabrics, tissue engineering, medicine and health, coatings, and paints. By combining the advantages of GO and CS, different types of promising materials can be obtained. This review discusses the preparation of GO-CS fibers, hydrogel and aerogel, and the applications of GO-CS nanocomposites. In addition, directions for future research on graphene material composites are discussed.

• Carbon letters
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• 제19권
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• pp.40-46
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• 2016

Nitrogen-atom doped graphene oxide was considered to prevent the dissolution of polysulfide and to guarantee the enhanced redox reaction of sulfur for good cycle performance of lithium sulfur cells. In this study, we used urea as a nitrogen source due to its low cost and easy preparation. To find the optimum urea content, we tested three different ratios of urea to graphene oxide. The morphology of the composites was examined by field emission scanning electron microscope. Functional groups and bonding characterization were measured by X-ray photoelectron spectroscopy. Electrochemical properties were characterized by cyclic voltammetry in an organic electrolyte solution. Compared with thermally reduced graphene/sulfur (S) composite, nitrogen-doped graphene/S composites showed higher electroactivity and more stable capacity retention.

• 소성∙가공
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• 제15권5호
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• pp.360-365
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• 2006

Carbon nanotubes (CNTs) have been the subject of intensive studies for applications in the fields of nano technologies in recent years due to their superior mechanical, electric, optical and electronic properties. Because of their exceptionally small diameters (${\appros}\;several\;nm$) as well as their high Young's modulus (${\appros}1\;TPa$), tensile strength (${\appros}\;200\;GPa$) and high elongation (10-30%) in addition to a high chemical stability, CNTs are attractive reinforcement materials for light weight and high strength metal matrix composites. Although extensive researches have been performed on the electrical, mechanical and functional properties of CNTs, there are not many successful results on the mechanical properties of CNT dispersed nanocomposites. In this paper, we applied equal channel angular pressing for consolidation of CNT/Cu powder mixtures. We also investigated the hardness and microstructures of CNT/Cu nanocomposites used experimental for metal matrix composites.

• Macromolecular Research
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• 제15권4호
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• pp.357-362
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• 2007

Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.