• Title/Summary/Keyword: functional coating

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Hybrid polymer-quantum dot based single active layer structured multi-functional device (Organic Bistable Device, LED and Photovoltaic Cell)

  • Son, Dong-Ick;Kwon, Byoung-Wook;Park, Dong-Hee;Kim, Tae-Whan;Choi, Won-Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.97-97
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    • 2010
  • We demonstrate the hybrid polymer-quantum dot based multi-functional device (Organic bistable devices, Light-emitting diode, and Photovoltaic cell) with a single active-layer structure consisting of CdSe/ZnS semiconductor quantum-dots (QDs) dispersed in a poly N-vinylcarbazole (PVK) and 1,3,5-tirs- (N-phenylbenzimidazol-2-yl) benzene (TPBi) fabricated on indium-tin-oxide (ITO)/glass substrate by using a simple spin coating technique. The multi-functionality of the device as Organic bistable device (OBD), Light Emitting Diode (LED), and Photovoltaic cell can be successfully achieved by adding an electron transport layer (ETL) TPBi to OBD for attaining the functions of LED and Photovoltaic cell in which the lowest unoccupied molecular orbital (LUMO) level of TPBi is positioned at the energy level between the conduction band of CdSe/ZnS and LiF/Al electrode (band-gap engineering). Through transmission electron microscopy (TEM) study, the active layer of the device has a p-i-n structure of a consolidated core-shell structure in which semiconductor QDs are uniformly and isotropically adsorbed on the surface of a p-type polymer core and the n-type small molecular organic materials surround the semiconductor QDs.

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Whey Protein-Based Edible Films and Coatings in Food Industry (식품산업에서 유청 단백질을 이용한 식용 필름과 코팅의 활용)

  • Jayeon Yoo;Sujatha Kandasamy;Hyoun Wook Kim;Hyung-Ho Bae;Jun-Sang Ham
    • Journal of Dairy Science and Biotechnology
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    • v.41 no.4
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    • pp.219-229
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    • 2023
  • Consumer demand for products with health benefits and natural ingredients is significant for the expansion of functional foods. Edible films and coatings are an excellent way to diversify the market for functional foods and as substitutes for the prevailing packaging and products. Incorporation of whey protein (WP) and its active ingredients into edible films and coatings is a promising technique that can be applied to various food products. Numerous combinations can be used on an industrial scale depending on the purpose, product, nature of the film, type of active ingredient, and type of inclusions. In this review, we describe several characteristics of edible WP films and coatings used as novel packaging materials. WP-based packaging can play a beneficial role in sustainability because of the option of recycling materials rather than incinerating, as in synthetic laminates, because of the use of natural byproducts from the food industry as raw materials. However, cost-effectiveness is a driving force against industrial setbacks in current and future WP processing developments. The industrial application of this new technology depends on further scientific research aimed at identifying the mechanism of film formation to improve the performance of both the process and product. Furthermore, research such as consumer studies and long-term toxicity assessments are required to obtain significant market shares.

The Effects of Neuromuscular Electrical Stimulation on Swallowing Function in Acute Stroke Patients with Dysphagia

  • Kim, Myung-Kwon;Lee, Chang-Ryeol;HwangBo, Gak
    • International Journal of Contents
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    • v.7 no.4
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    • pp.98-102
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    • 2011
  • In this study, we investigated the effects of neuromuscular electrical stimulation (NMES) on the treatment of 20 acute stroke patients with dysphagia. For both the treated and control groups, the basic facial stimulation training was conducted for 30 minutes, five times a week, for four weeks. NMES was performed on the treated group only, for 30 minutes each time. Both groups were evaluated according to the functional dysphagia scale (FDS) using a videofluoroscopic swallowing study (VFSS). After the treatment was performed for four weeks, the FDS results of the treated group showed a significance difference in oral transit time in the oral phase and in the triggering of pharyngeal swallow fluid, laryngeal elevation and epiglottic closure, nasal penetration, residue in valleculae, coating of pharyngeal wall after swallow fluid, and pharyngeal transit time in the pharyngeal phase. In addition, the treated group showed a significant difference in laryngeal elevation and epiglottic closure, nasal penetration, and pharyngeal transit time in the pharyngeal phase after the treatment compared to the control group. The results of this study showed that neuromuscular electrical stimulation may be an effective method of treating dysphagia in acute phase stroke patients.

Effect of Surfactant in Electroless Ni-B Plating for Coating on the Diamond Powder (다이아몬드 분말상에 무전해 Ni-B 도금을 위한 계면활성제의 영향)

  • Yang, Changyol;Yu, Si-Young;Moon, Hwan-Gyun;Lee, Jung-Ho;Yoo, Bongyoung
    • Journal of the Korean institute of surface engineering
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    • v.50 no.3
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    • pp.177-182
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    • 2017
  • The properties of electroless Ni-B thin film on diamond powder with different parameters (temperature, pH, surfactant etc.) were studied. The surface morphology, structure and composition distribution of the Ni-B film were observed by field effect scanning electron microscope (FE-SEM), energy-dispersive spectrometer (EDS), X-ray diffraction (XRD) and Auger electron spectroscopy (AES). The growth rate of Ni-B film was increased with increase of bath temperature. The B content in Ni-B film was reduced with increase of bath pH. As a result the structure of Ni-B film was changed from amorphous to crystalline structure. The PVP in solution plays multi-functional roles as a dispersant and a stabilizer. The Ni-B film deposited with adding 0.1 mM-PVP was strongly introduced an amorphous structure with higher B content (25 at.%). Also the crystallite size of Ni-B film was reduced from 12.7 nm to 5.4 nm.

Pinched Flow Fractionation Microchannel to Sort Microring-Containing Immiscible Emulsion Droplets (마이크로 링이 함유된 비혼합성 에멀젼 액적의 분류를 위한 Pinched Flow Fractionation 마이크로 채널)

  • Ye, Woojun;Kim, Hyunggun;Byun, Doyoung
    • Journal of the Korean Society of Visualization
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    • v.15 no.2
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    • pp.41-47
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    • 2017
  • Microring/nanoring structure has high applicability for nano-antenna and biosensor thanks to its superior optical characteristics. Although coiling nanowires manufactured using immiscible emulsion droplets have an advantage in mass production, this process also forms nanowire bundles. In this study, we solved the nanowire bundle problem by size-selective sorting of the emulsion droplets in a pinched flow fractionation microchannel. Utilizing silver nanowires and immiscible emsulsion droplets, we investigated the correlation between the size of ring droplets and bundle droplet. We visualized the sorting process for glass particles and microring-containing emulsion droplets. Droplets were sorted based on their size, and the ratio of bundle droplets in solution decreased. This droplet-sorting strategy has potential to help the printing and coating process for manufacturing of ring structure patterns and developing of functional materials.

Synthesis of Poly(epoxy-imide)-Nano Silica Hybrid Film via CS Sol-gel Process and Their Dielectric Properties (CS졸을 이용한 Poly(epoxy-imide)-나노 Silica 하이브리드 필름의 합성과 유전특성)

  • Han, Se-Won;Han, Dong-Hee;Kang, Dong-Pil;Kang, Young-Taec
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.35-40
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    • 2007
  • The new PEI(poly(epoxy-imide))-nano Silica film has been synthesized via in situ CS sol process, and the chemical bonding and microstructure of nano silica dispersed in resin were examined by FT-IR, TAG and SEM. The dielectric properties of these hybrid films over a given temperature and frequency ranges have been studied in a point of view of stable chemical bonding of nano Silica filler. The results from IR spectra and SEM photograph indicated that PEI-Silica hybrid film prepared with nano CS sol process has been synthesized in uniform and chemical bonding. The decrease property of dielectric constant with CS content, tangent loss consistent of given frequency and temperature has been explained in terms of the chain movement of polymer through chemical bonging and size effect of nano silica. The new PEI-CS sol hybrid film with such stable chemical and dielectric properties was expected to be used as a high functional coating application in ET, IT and electric power products.

Preparation of Functional Textiles by Multilayer Structure - Cotton Fabrics Treated with Chitosan and Alginate Skin - (다층 코팅 처리에 의한 기능성 섬유의 제조 - 키토산과 알지네이트로 피복된 면 -)

  • Son, Tae-Won;Lee, Ju-Hyun;Lee, Min-Gyeong;Cho, Jin-Won
    • Textile Coloration and Finishing
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    • v.23 no.3
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    • pp.201-209
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    • 2011
  • With a new method of applying chitosan and alginate onto cellulose, multi-coated cotton fabrics with chitosan and alginate were prepared and characterized. To coat cotton with chitosan, raw cotton was dipped in chitosan solution, mangled of 1kgf/$cm^2$, neutralized in 2 wt% NaOH soluton, washed, and dried at $60^{\circ}C$ oven. The chitosan-coated fiber was dipped in sodium alginate solution, 1kgf/$cm^2$ mangled, neutralized in 2 wt% $CaCl_2$ solution, washed, and dried at $60^{\circ}C$ oven, resulting in CCAC(coated cotton with chitosan and calcium alginate skin) fiber characteristics. Excellent absorbancy of distilled water and saline solution was observed by the absorption test on cotton fabric treated with CCAC(0.5 wt% calcium alginate) and 0.5 wt% calcium alginate respectively. The SEM photograph confirmed the uniform coating on the cotton fabric surface.

Physical Properties and Flame-Retardant Effects of Polyurethane Coatings Containing Pyrophosphoric Lactone Modified Polyesters (파이로포스포릭 락톤 변성 폴리에스터를 함유한 폴리우레탄 도료의 물성 및 난연 효과)

  • 정동진;김성래;박형진;박홍수;김승진
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.169-175
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    • 2003
  • Pyrophosphoric lactone modified polyester (PATT) containing two phosphorous functional groups in one unit structure was synthesized to prepare a non-toxic reactive flame-retardant coatings. Then the PATT was cured at room temperature with isocyanate, toluene diisocyanate-isocyanurate , to get a two-component polyurethane flame-retardant coatings (PIPUC). Comparing physical properties of the films of PIPUC with those of film of non-flame-retardant coatings, there was no deterioration observed in physical properties by the introduction of a flame-retarding component into the resin. We found that the char lengths measured by 45$^{\circ}$ Meckel burner method were 3.1∼4.4 cm and LOI values recorded 27∼30%. These results indicate that the coating prepared in this study is a good flame-retardant. The surface structure of coatings investigated with SEM does not show any defects and phase separation.

Capillary-driven Rigiflex Lithography for Fabricating High Aspect-Ratio Polymer Nanostructures (모세관 리소그라피를 이용한 고종횡비 나노구조 형성법)

  • Jeong, Hoon-Eui;Lee, Sung-Hoon;Kim, Pil-Nam;Suh, Kahp-Y.
    • Journal of the Korean Society of Visualization
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    • v.5 no.1
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    • pp.3-8
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    • 2007
  • We present simple methods for fabricating high aspect-ratio polymer nanostructures on a solid substrate by rigiflex lithography with tailored capillarity and adhesive force. In the first method, a thin, thermoplastic polymer film was prepared by spin coating on a substrate and the temperature was raised above the polymer's glass transition temperature ($T_g$) while in conformal contact with a poly(urethane acrylate) (PUA) mold having nano-cavities. Consequently, capillarity forces the polymer film to rise into the void space of the mold, resulting in nanostructures with an aspect ratio of ${\sim}4$. In the second method, very high aspect-ratio (>20) nanohairs were fabricated by elongating the pre-formed nanostructures upon removal of the mold with the aid of tailored capillarity and adhesive force at the mold/polymer interface. Finally, these two methods were further used to fabricate micro/nano hierarchical structures by sequential application of the molding process for mimicking nature's functional surfaces such as a lotus leaf and gecko foot hairs.

Studies on Preparation of Functional Powder and Anti-Microbacterial Properties by Vapor-Phase Surface Modification method (기상 표면개질법에 의한 제지용 복합분체 제조 및 항균특성에 관한 연구)

  • 조준형;민동진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.214-214
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    • 2003
  • 제지산업에 경쟁력을 부여할 수 있는 방법의 일환으로 제지용 도공안료의 표면개질을 시도하였다 은(Ag)이 항균력이 있다는 것이 여러 사람에 의해 증명된바 있으므로 이 은의 항균력을 제지용 무기안료에 이산화티탄과 함께 표면개질하고 다기능성 복합 항균분체를 설계하였다. 표면개질장치에 설치한 기상분사장치를 통해 은 용액을 고압기상분사로 TiO$_2$입자 표면에 Coating 하였다 이때의 분무각도는 60$^{\circ}$이고 오리피스 직경은 0.6mm, 분사 압력은 14kgf/$\textrm{cm}^2$ 이다. TiO$_2$에 은 용액을 기상분사하여 코팅시킨 후 표면개질 계산식에 의한 배합비로 모입자(clay, CaCO$_3$, PE)와 자입자(TiO$_2$)를 혼합하였고, 분체의 대전현상을 이용하여 모입자 주위에 자입자를 부착시킨 후, 고속기류중 충격력으로 표면개질처리를 하였다 표면개질 장치를 사용하여 제지용 무기안료 표면에 은용액이 코팅된 TiO$_2$를 개질 시켰다. 각종 물성(항균성, 백색도, 산란도)과 XRD, SEM 측정을 통해 기능성 항균분체의 실용방안 가능성에 대하여 조사하였다.

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